全文获取类型
收费全文 | 467篇 |
免费 | 112篇 |
国内免费 | 87篇 |
专业分类
化学 | 317篇 |
晶体学 | 4篇 |
力学 | 31篇 |
综合类 | 8篇 |
数学 | 33篇 |
物理学 | 273篇 |
出版年
2024年 | 1篇 |
2023年 | 9篇 |
2022年 | 24篇 |
2021年 | 16篇 |
2020年 | 25篇 |
2019年 | 17篇 |
2018年 | 11篇 |
2017年 | 11篇 |
2016年 | 23篇 |
2015年 | 24篇 |
2014年 | 19篇 |
2013年 | 41篇 |
2012年 | 31篇 |
2011年 | 31篇 |
2010年 | 27篇 |
2009年 | 30篇 |
2008年 | 28篇 |
2007年 | 40篇 |
2006年 | 24篇 |
2005年 | 21篇 |
2004年 | 17篇 |
2003年 | 17篇 |
2002年 | 15篇 |
2001年 | 13篇 |
2000年 | 11篇 |
1999年 | 25篇 |
1998年 | 13篇 |
1997年 | 10篇 |
1996年 | 12篇 |
1995年 | 17篇 |
1994年 | 11篇 |
1993年 | 6篇 |
1992年 | 14篇 |
1991年 | 13篇 |
1990年 | 4篇 |
1989年 | 8篇 |
1988年 | 1篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1980年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有666条查询结果,搜索用时 15 毫秒
31.
通过将系统参数定义为参数变量, 构成参数空间,研究齿轮传动系统在参数空间和状态空间耦合下的非线性全局动力学特性,以及多参数、多初值和多稳态行为之间的关联特性.首先设计了一个两空间耦合下非线性系统多稳态行为的计算和辨识方法.其次,基于该方法并结合相图、Poincaré映射图、分岔图、最大Lyapunov指数、吸引域等,研究齿轮传动系统在不同参数平面上多稳态行为的存在区域和分布特性,以及多稳态行为在状态平面上的分布特性,揭示了参数平面和状态平面上系统可能隐藏的多稳态行为和分岔,并分析了多稳态行为的形成机理. 结果发现,两空间耦合下系统在参数平面上存在大量多稳态行为并呈"带状"分布, 状态平面上多稳态行为出现两种不同的侵蚀现象, 即内部侵蚀和边界侵蚀.分岔点或分岔曲线对初值的敏感性导致多稳态行为的出现.当齿侧间隙和误差波动在较小的范围内变化时,系统全局动力学特性受间隙和误差扰动的影响较小,受啮合频率的影响较大.两空间耦合下系统全局动力学特性变得丰富和复杂. 相似文献
32.
Zhang HJ Gou RH Yan L Yang RD 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2007,66(2):289-294
A new ligand, N,N'-di(pyridine N-oxide-2-yl)pyridine-2,6-dicarboxamide (LH2) and its several lanthanide (III) complexes (La, Eu, Gd, Tb, Y) were synthesized and characterized in detail based on elemental analysis, conductivity measurements, IR, 1H NMR, MS (FAB) and UV spectra and TG-DTA studies. The results indicated that the composition of these binary complexes is [Ln(LH2)(NO3)2.H2O]NO3.nH2O (n=0-1); while the ligand has a good planar structure with strong hydrogen bonds. The fluorescence spectra exhibits that the Tb (III) complex and the Eu (III) complex display characteristic metal-centered fluorescence in solid state while ligand fluorescence is completely quenched. However, the Tb (III) complex displays more effective luminescence than the Eu (III) complex, which is attributed to especial effectivity in transferring energy from the lowest triplet energy level of the ligands (T) onto the excited state (5D4) of Tb (III) than that (5D1) of Eu (III). 相似文献
33.
层状复合氢氧化物对乙酰苯甲酸的负载与体外释放 总被引:2,自引:0,他引:2
共沉淀-微波晶化法合成层状复合氢氧化物(LDH)后, 用不同方式将乙酰苯甲酸(ASP)组装到LDH层间制成载药体LDH-ASP, 通过对合成及药物释放前后的液相分析与固相表征数据研究了LDH对ASP的负载及载药体LDH-ASP在磷酸盐介质的溶释现象. 结果表明: LDH层间通道是负载、贮存及控制药物释放的微观基础; 载体选择、药物配比、反应能量供给方式及搅拌强度是决定并影响LDH-ASP载药效率的基本因素, LDH-ASP结构参数可以反映药物负载情况、并与其释放性能明确相关; LDH对ASP的负载与释放均致晶胞参数改变、结晶度下降; 载药体与前体的晶态属性、热力学行为及表面特性相似, 而释放药物后固相的晶态性征减弱、无定形性增强、通道吸附活性降低, 有利于使命后载体在体内降解消除. 相似文献
34.
A nondestructive desulfurization microorganism has been isolated. The metabolism product analyses show that the strain can be a kind of biocatalyst to oxidize dibenzothiophene (DBT) into 2-hydroxydiphenyl (HBP), therefore the sulfur in DBT is removed selectively. The 16SrRNA information, cell wall analysis, physical, biochemical properties and morphological properties suggest that the isolated strain is Rhodococcus erythropolis. The strain can grow in the basal salts medium (BSM) that DBT concentration is no more than 10 mmol/L, and the optimal DBT concentration for growth is 1 mmol/L, however, the optimal DBT concentration for desulfurization is 0.5 mmol/L. The further research shows that the strain can also desulfur some other or-ganosulfur-containing compounds such as thianaphthene, phenyl sulfide and 4,6-dimethyldiben-zothiophene (4,6-DMDBT). 相似文献
35.
Carnation‐like CuO Hierarchical Nanostructures Assembled by Porous Nanosheets for Nonenzymatic Glucose Sensing 下载免费PDF全文
Carnation‐like CuO hierarchical nanostructures assembled by ultrathin porous nanosheets were successfully fabricated via a facile solvothermal route followed with heat treatment. As‐prepared CuO nanostructures exhibited excellent catalytic activity toward glucose oxidation in the absence of any enzymes. Under the optimized conditions, the CuO‐based enzymeless glucose sensor showed high sensitivity of 3.15 mA mM?1 cm?2, low limit of detection (98 nM, S/N=3), good reproducibility, excellent selectivity and long‐time stability. The superb nonenzymatic glucose sensing performance of the CuO hierarchical nanostructures was attributed to the highly catalytically active sites at the edges and basal planes of the CuO nanosheets, facile transportation of analytes through the abundant mesopores and macropores, robust and stable hierarchical structure. Moreover, the CuO‐based enzymeless glucose sensor showed high accuracy and reliability in comparison with clinical glucometer for quantitative determination of glucose in human blood serum samples. 相似文献
36.
IntroductionThemotionoftheinviscid,irrotationalandincompressiblefluidinacylindricalcontainerwithradiusaisgovernedbyFig.1Sloshofaliquidinacylindricalcontainer2=0 (inV),(1)r=0 (onr=a),(2)z=0 (onz=-h),(3)ηt+·η=z (onz=η),(4)t+12|… 相似文献
37.
A photon echo experiment in Tm(3+):YAG is reported that shows, for the first time to the authors' knowledge, the time-domain equivalent of the transition from near- to far-field diffraction, including Talbot self-imaging effects. The experiment demonstrates the huge dispersion capability of photon echoes and opens the way to further exploration of space-time duality. 相似文献
38.
对重氢原子进入钯或钛晶体中可能引起常温核聚变的机理探讨与实验研究结果,已在文献[1]中作了报导。后来又对钛阴极材料,在使用前后进行了X射线结构分析。发现在电解过程中发生过“过热”现象的钛阴极材料的晶体结构由原来的密排六方结构转变为立方结构,而没有发生“过热”现象的钛阴极材料的晶体仍然保持电解前的密排六方结构 相似文献
39.
Z.-W.?He W.-X.?Sun X.-Q.?Liu D.-Y.?Xu J.?Gou Y.-Y.?WangEmail author 《The European Physical Journal B - Condensed Matter and Complex Systems》2005,48(4):463-468
Nanoporous SiO2 thin films with ultra-low
dielectric constants were synthesized using a molecular template method.
Uniform films with pore size between 10 and 20 nm were obtained as observed
by N2 adsorption/desorption isotherms and transmission electron
microscopy. Fourier transform infrared spectroscopy (FTIR) and differential
thermal analysis were carried out to investigate the effect of n-hexane
washing on structural properties before and after the surface modification
process. The results showed that –OH bonds were substituted with –CH3 bonds in the films as a result of modification of trimethylchlorosilane
(TMCS)/n-hexane solution. Four kinds of model were used to analyze the
relationship between porosity and dielectric constant of the films, where
the dielectric constant was determined from capacitance-voltage
measurements. The investigation indicated that the corresponding
relationship was in accord with that estimated by the Rayleigh model. 相似文献
40.
Murphy CJ Sau TK Gole AM Orendorff CJ Gao J Gou L Hunyadi SE Li T 《The journal of physical chemistry. B》2005,109(29):13857-13870
This feature article highlights work from the authors' laboratories on the synthesis, assembly, reactivity, and optical applications of metallic nanoparticles of nonspherical shape, especially nanorods. The synthesis is a seed-mediated growth procedure, in which metal salts are reduced initially with a strong reducing agent, in water, to produce approximately 4 nm seed particles. Subsequent reduction of more metal salt with a weak reducing agent, in the presence of structure-directing additives, leads to the controlled formation of nanorods of specified aspect ratio and can also yield other shapes of nanoparticles (stars, tetrapods, blocks, cubes, etc.). Variations in reaction conditions and crystallographic analysis of gold nanorods have led to insight into the growth mechanism of these materials. Assembly of nanorods can be driven by simple evaporation from solution or by rational design with molecular-scale connectors. Short nanorods appear to be more chemically reactive than long nanorods. Finally, optical applications in sensing and imaging, which take advantage of the visible light absorption and scattering properties of the nanorods, are discussed. 相似文献