全文获取类型
收费全文 | 209篇 |
免费 | 1篇 |
国内免费 | 2篇 |
专业分类
化学 | 169篇 |
晶体学 | 2篇 |
数学 | 18篇 |
物理学 | 23篇 |
出版年
2023年 | 1篇 |
2022年 | 3篇 |
2021年 | 6篇 |
2020年 | 6篇 |
2019年 | 5篇 |
2018年 | 6篇 |
2017年 | 5篇 |
2016年 | 4篇 |
2015年 | 5篇 |
2014年 | 11篇 |
2013年 | 10篇 |
2012年 | 15篇 |
2011年 | 16篇 |
2010年 | 11篇 |
2009年 | 10篇 |
2008年 | 15篇 |
2007年 | 20篇 |
2006年 | 12篇 |
2005年 | 7篇 |
2004年 | 13篇 |
2003年 | 5篇 |
2002年 | 3篇 |
2001年 | 2篇 |
2000年 | 8篇 |
1999年 | 1篇 |
1998年 | 3篇 |
1994年 | 1篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1983年 | 1篇 |
1981年 | 1篇 |
1979年 | 1篇 |
1977年 | 2篇 |
排序方式: 共有212条查询结果,搜索用时 750 毫秒
81.
Niko Radulović Gordana Stojanović Rastko Vukićević Vidoslav Dekić Biljana Dekić Radosav Palić 《Monatshefte für Chemie / Chemical Monthly》2006,137(11):1477-1486
Summary. The one pot reaction preparation, spectral analysis, and molecular modeling experiments on the new 3,4-annelated coumarin
systems with bioactivity associated structural features are described. These provided the insight into the equilibrium of
the respective tautomeric forms making possible the reconciliation of previously published spectral data with the structure
assignments as well as the correction of erroneously established structures. The synthesized compounds were tested in a standard
disk diffusion assay and displayed strong to moderate antimicrobial activity, with a promising new lead prototype compound
(7-amino-9-hydroxy-5-oxa-7a,8,11-triazacyclopenta[b]phenanthren-6-one (5)) possessing greater activity that the antibiotics Ampicillin and Nystatin. Antioxidant capacities of the compounds, determined
spectrophotometrically using a phosphomolybdenum method, were greater, and in the case of compound 5 four times the activity of α-tocopherol acetate. 相似文献
82.
Zora Popovi Gordana Pavlovi Boris‐Marko Kukovec 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(5):m181-m183
The title compound, [Cu(C9H5N2O3)2(C2H6OS)2], consists of octahedrally coordinated CuII ions, with the 3‐oxo‐3,4‐dihydroquinoxaline‐2‐carboxylate ligands acting in a bidentate manner [Cu—O = 1.9116 (14) Å and Cu—N = 2.1191 (16) Å] and a dimethyl sulfoxide (DMSO) molecule coordinated axially via the O atom [Cu—O = 2.336 (5) and 2.418 (7) Å for the major and minor disorder components, respectively]. The whole DMSO molecule exhibits positional disorder [0.62 (1):0.38 (1)]. The octahedron around the CuII atom, which lies on an inversion centre, is elongated in the axial direction, exhibiting a Jahn–Teller effect. The ligand exhibits tautomerization by H‐atom transfer from the hydroxyl group at position 3 to the N atom at position 4 of the quinoxaline ring of the ligand. The complex molecules are linked through an intermolecular N—H...O hydrogen bond [N...O = 2.838 (2) Å] formed between the quinoxaline NH group and a carboxylate O atom, and by a weak intermolecular C—H...O hydrogen bond [3.392 (11) Å] formed between a carboxylate O atom and a methyl C atom of the DMSO ligand. There is a weak intramolecular C—H...O hydrogen bond [3.065 (3) Å] formed between a benzene CH group and a carboxylate O atom. 相似文献
83.
Violeta D. Mitić Marija D. Ilić Vesna P. Stankov Jovanović Aleksandra S. Djordjevic Marija S. Marković Gordana S. Stojanović 《Natural product research》2020,34(18):2698-2701
AbstractThe chemical composition of the essential oil and the volatiles obtained by static headspace (HS) of Inula oculus-christi L. is presented. The GC-MS analysis of the hydrodistilled oil resulted in the identification of 90 components, representing 92.7% of the oil. The most abundant compounds were: caryophyllene oxide (9.8%), trans-longipinocarveol (9.2%), eucalyptol (7.3%) and intermedeol (6.2%). The major constituent of I. oculus-christi L. HS volatiles was eucalyptol (87.4%). The antioxidant activity was evaluated by four different methods: 2,2-diphenyl-1-picryl-hydrazylhydrate free radical assay (DPPH), 2,2-azino-bis-3-ethylbenzothiazoline-6-sulfonic acid (ABTS) method, total reducing power (TRP), ferric reducing antioxidant power (FRAP), and cupric reducing antioxidant capacity (CUPRAC). Total phenolic content in (TPC) examined oil was 177.95?µg GAE/mg oil. Radical scavenging potential of the oil was promising RSC-DPPH was 57.4% and RSC-ABTS was 82.7%. 相似文献
84.
Felicíssimo VC Guimarães FF Gel'mukhanov F Cesar A Agren H 《The Journal of chemical physics》2005,122(9):094319
In this paper we derive the basic physics underlying infrared-x-ray pump-probe spectroscopy (IR, infrared). Particular features of the spectroscopy are highlighted and discussed, such as dependence on phase of the infrared pulse, duration and delay time of the x-ray pulse, and molecular orientation. Numerical applications are carried out for the water dimer using wave packet techniques. It is shown that core ionization of the donor oxygen of the water dimer results in a drastic change of the potential with the global minimum placed in the proton transfer region. The results of the modeling indicate that IR-x-ray pump-probe spectroscopy can be used to study the dynamics of proton transfer in this core-ionized state, and that, contrary to conventional core level photoelectron spectroscopy, x-ray core-ionization driven by an IR field is a proper method to explore the proton transfer in a system like the water dimer. We observe that the trajectory of the nuclear wave packet in the ground state potential well is strongly affected by the absolute phase of the IR pulse. 相似文献
85.
Novak P Tomisić ZB Tepes P Lazarevski G Plavec J Turkalj G 《Organic & biomolecular chemistry》2005,3(1):39-47
Conformations of the 14-membered macrolide antibiotic oleandomycin and its 8-methylene-9-oxime derivative were determined in various solvents. The experimental NMR data--coupling constants and NOE contacts--were compared with the results of molecular modelling--molecular mechanics calculations and molecular dynamics simulations. The conformational changes, on the right-hand side of the 14-membered ring, affected mostly the 3JH2,H3 values and NOE crosspeaks H3 or H4 to H11. Oleandomycin was found to be present predominantly in the C3-C5 folded-in conformations in DMSO-d6 solution, whereas in buffered D2O, acetone-d6 and CDCl3, there was a mixture of folded-in and folded-out conformational families. The predominant conformation of the 8-methylene-oleandomycin-9-oxime derivative in solution was a folded-out one although different amounts of folded-in conformation were also present depending on the solvent. Oleandrose and desosamine sugar moieties adopted the usual and expected chair conformation. The conformation around the glycosidic bonds, governing the relative orientation of sugars vs. the lactone ring, showed a certain flexibility within two conformationally close families. We believe that by combining the experimental NMR data and the molecular modelling techniques, as reported in this paper, we have made significant progress in understanding the conformational behaviour and properties of macrolides. Our belief is based on our own current studies on oleandomycins as well as on the previously reported results and best practices concerning other macrolides. A rational for macrolide conformational studies and advances in methodology has been suggested accordingly. 相似文献
86.
Igor A. Pašti Aleksandra Janošević Ležaić Gordana Ćirić-Marjanović Vladimir M. Mirsky 《Journal of Solid State Electrochemistry》2016,20(11):3061-3069
Due to constant necessity to have reliable and sensitive gas sensors in many contemporary technologies, there is a permanent need for development of new sensing platforms with good sensing properties. Here, we demonstrate a novel type of resistive gas sensors based on carbonized polyaniline/Nafion composites. The sensing mechanism of such sensors is based on the sorption of gases by the composites which induce Nafion swelling and decreasing of conductivity. Chemosensitive properties can be tuned by the (i) choice of carbon materials with different conductivities, (ii) Nafion content in the composite, and (iii) thickness of the composite layer. We have shown that the sensors respond to water, acetone, ethanol, and methanol vapors. For the last two cases, we have achieved high sensitivity, fast response, wide concentration range, and good recovery. The use of simultaneous two- and four-point techniques for these sensors provides an internal control of the sensor integrity. 相似文献
87.
Miseljić B Popović G Agbaba D Marković S Simonovska B Vovk I 《Journal of AOAC International》2008,91(2):332-338
A gradient reversed-phase column high-performance liquid chromatographic method was developed for the detection and quantification of norfloxacin and its major impurities in norfloxacin-containing pharmaceuticals. Chromatographic separations were performed under the following experimental conditions: column, Zorbax SB RP-18 (5 microm, 250 x 4.6 mm); injection volume, 20 microL; mobile phase, 0.05 M NaH2PO4 (pH 2.5)-acetonitrile (87 + 13) for 16 min and (58 + 42) for 9 min (stepwise gradient); and flow rate, 1.3 mL/min. All analyses were performed at 25 degrees C, and the eluate was monitored at 275 nm using a diode array detector. Linearity (correlation coefficient = 0.999), recovery (99.3-101.8%), relative standard deviation (0.2-0.7%), and quantitation limit (0.12-0.47 microg/mL) were evaluated and found to be satisfactory. The method is simple, rapid, and convenient for purity control of norfloxacin in both raw materials and dosage forms. 相似文献
88.
Stanković Milena Antić Gordana Blagojević M. Petrović S. 《Journal of Thermal Analysis and Calorimetry》1998,52(2):581-585
The method of microcalorimetric compatibility testing of the constituents of combustible materials and casting composite explosives
is based on the change in power when separately measuring the different materials involved, and their mixture, during isothermal
treatment. The experimental power-time curve for the mixture was compared to the hypothetical curve constructed from the results
of the measurements of individual materials.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
89.
Activity coefficients of acetamide in acetamide-calcium nitrate melt solutions were determined from cryoscopic data in the concentration range O to 0.151 mole fraction of calcium nitrate. Enthalpies of melting and melting point depressions were obtained from DSC measurements. Melt solutions were obtained from two crystalline forms of acetamide. Eutectic formation was observed in both crystalline forms. Heat capacity of pure acetamide in the two forms was measured in the temperature range 20 to 100°C. Activity coefficients obtained for molten acetamide from two sets of cryoscopic data were in good agreement. Change of activity coefficients with calcium nitrate concentration indicate strong association between solvent and solute and water-like acting of molten acetamide. 相似文献
90.