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41.
W. V. Gehrlein B. Gopinath J. C. Lagarias P. C. Fishburn 《Applied Mathematics and Optimization》1982,8(1):309-324
Letw=(w
1,,w
m
) andv=(v
1,,v
m-1
) be nonincreasing real vectors withw
1>w
m
andv
1>v
m-1
. With respect to a lista
1,,a
n of linear orders on a setA ofm3 elements, thew-score ofaA is the sum overi from 1 tom ofw
i
times the number of orders in the list that ranka inith place; thev-score ofaA{b} is defined in a similar manner after a designated elementb is removed from everya
j
.We are concerned with pairs (w, v) which maximize the probability that anaA with the greatestw-score also has the greatestv-score inA{b} whenb is randomly selected fromA{a}. Our model assumes that linear ordersa
j
onA are independently selected according to the uniform distribution over them linear orders onA. It considers the limit probabilityP
m
(w, v) forn that the element inA with the greatestw-score also has the greatestv-score inA{b}.It is shown thatP
m
(m,v) takes on its maximum value if and only if bothw andv are linear, so thatw
i
–w
i+1=w
i+1–w
i+2 forim–2, andv
i
–v
i+1
=v
i+1
–v
i+2
forim–3. This general result for allm3 supplements related results for linear score vectors obtained previously form{3,4}. 相似文献
42.
Gopinath Subash C. B. Perumal Veeradasan Balakrishnan S.R. Md Arshad M. K. Lakshmipriya Thangavel Haarindraprasad R. Hashim Uda 《Mikrochimica acta》2017,184(11):4425-4431
Microchimica Acta - The authors describe an impedimetric nanosensor for aptamer-mediated detection of ATP. A triangular junction of polysilicon substrate is used as a transducer. The aptamer was... 相似文献
43.
Kalaiyarasi J. Meenakshi S. Pandian K. Gopinath Subash C. B. 《Mikrochimica acta》2017,184(7):2131-2140
Microchimica Acta - Simple and robustic mediator free graphene nanoflake modified glassy carbon electrode (GNF/GCE) was used for the simultaneous determination of vanillin (VAN) and... 相似文献
44.
In this paper,we present a stable,reliable and robust method for reconstructing a three dimensional density function from a set of two dimensional electric tomo... 相似文献
45.
Samir M. Osman Ahmed M. Abdel‐Megied Mohammed H. Zain Eldain Simimole Haleema Chithra Gopinath Sarojini Amma Sumalekshmy Hassan Y. Aboul‐Enein 《Biomedical chromatography : BMC》2019,33(11)
The commercial value of cashew nut shell liquid (CNSL) has become a cornerstone of the agrowaste industry. It is the by‐product of the cashew industry and has an 1/8 inch thickness of soft honeycomb structure. CNSL contains phenolic lipids with aliphatic chains such as anacardic acid, cardanol, cardol and methyl cardol, and their derivatives. The developed GC–MS method is rapid, accurate and selective using a selected derivatizing reagent, namely N‐methyl‐N‐(trimethylsilyl)‐trifluoroacetamide that was previously diluted 1:1% with anhydrous pyridine. The proposed GC–MS method was applied for the analysis of different CNSL samples. The results showed that all classes of CNSL compounds were detected. The four alkyl phenols were detected with their different alkyl sidechains without any interference. This method is also specified for the detection of fatty acids of saturated and unsaturated chains. Silylation did not cause any alteration in the chemical structure of CNSL compounds regardless of esterification action. Silylation is considered a safe derivatizing agent compatible with GC chromatography and specific for all volatile and nonvolatile polar and nonpolar CNSL compounds that could be detected in CNSL samples. 相似文献
46.
Dr. Tata Gopinath Dr. Veliparambil S. Manu Dr. Daniel K. Weber Prof. Gianluigi Veglia 《Chemphyschem》2022,23(13):e202200127
Solid-state NMR (ssNMR) spectroscopy has emerged as the method of choice to analyze the structural dynamics of fibrillar, membrane-bound, and crystalline proteins that are recalcitrant to other structural techniques. Recently, 1H detection under fast magic angle spinning and multiple acquisition ssNMR techniques have propelled the structural analysis of complex biomacromolecules. However, data acquisition and resonance-specific assignments remain a bottleneck for this technique. Here, we present a comprehensive multi-acquisition experiment (PHRONESIS) that simultaneously generates up to ten 3D 1H-detected ssNMR spectra. PHRONESIS utilizes broadband transfer and selective pulses to drive multiple independent polarization pathways. High selectivity excitation and de-excitation of specific resonances were achieved by high-fidelity selective pulses that were designed using a combination of an evolutionary algorithm and artificial intelligence. We demonstrated the power of this approach with microcrystalline U-13C,15N GB1 protein, reaching 100 % of the resonance assignments using one data set of ten 3D experiments. The strategy outlined in this work opens up new avenues for implementing novel 1H-detected multi-acquisition ssNMR experiments to speed up and expand the application to larger biomolecular systems. 相似文献
47.
An evanescent-field-coupled waveguide-mode sensor of the Kretschmann configuration with a silica waveguide having nanoscale holes is an ideal tool for detection of bimolecular reactions. In the present research, an optimized surface of the sensor with cylindrical nanoscale holes was modified with sodium (1-{[6-(2,5-dioxo-2,5-dihydro-1H-pyrrol-1-yl)hexanoyl]oxy}-2,5-dioxopyrrolidine-3-sulfonate) (Sulfo-EMCS) to facilitate the attachment of biomolecules; the resulting surface could be cleaned for reuse simply by changing the pH of the buffering solution. The modification is expected to be useful for wide range of molecular detection. 相似文献
48.
Green fluorescent protein-expressing Escherichia coli as a model system for investigating the antimicrobial activities of silver nanoparticles 总被引:1,自引:0,他引:1
Gogoi SK Gopinath P Paul A Ramesh A Ghosh SS Chattopadhyay A 《Langmuir : the ACS journal of surfaces and colloids》2006,22(22):9322-9328
Recombinant Escherichia coli (E. coli) bacteria expressing green fluorescent protein (GFP) was used as a model system to investigate the antimicrobial activities of Ag nanoparticles (NPs). A convenient in situ method of Ag NP synthesis using sodium borohydride, in the bacterial growth medium, was developed to produce preformed NPs for the study. Fluorescence spectroscopic and microscopic techniques allowed rapid detection of time-dependent changes in bacterial growth as well as fluorescence characteristics in the presence of Ag NPs. In addition, X-ray diffraction, UV-vis spectroscopic, and transmission electron microscopic measurements were carried out to understand the effect of Ag NPs on the bacteria. Our observations indicated that Ag NPs, above a certain concentration, not only were bactericidal but also were found to reduce the sizes of treated bacteria in comparison to untreated ones. Cell lysis of Ag NP-treated bacteria was suggested by the increased GFP fluorescence obtained in the medium. In vitro DNA-Ag NP interaction was detected by spectrophotometric analysis. However, electrophoresis studies indicated no direct effect of Ag NPs on DNA or protein profiles. 相似文献
49.
Benzyl ethers, ketals and orthoformates were cleaved with Pd(OH)2/C in methanol, to generate the corresponding alcohol; carboxylic acid esters were stable under these reaction conditions. Pd(OH)2/C in methanol was used for the deprotection of hydroxyl groups during the preparation of sequoyitol via myo-inositol orthobenzoate. This method of deprotection has the potential to be useful in the synthesis of different classes of organic compounds since the reaction conditions do not involve strong acids, bases or hydrogen. 相似文献
50.
在一系列H模放电条件下,建立了一个旨在研究等离子体温度分布剖面不变性的数据库。介绍了数据库建立过程中要解决的关键问题和所用软件,对等离子体温度分布剖面不变性及芯部约束与边缘参数的关系进行了研究。 相似文献