首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   29175篇
  免费   3645篇
  国内免费   3178篇
化学   21078篇
晶体学   363篇
力学   1431篇
综合类   234篇
数学   3544篇
物理学   9348篇
  2024年   77篇
  2023年   453篇
  2022年   795篇
  2021年   863篇
  2020年   926篇
  2019年   940篇
  2018年   807篇
  2017年   772篇
  2016年   1150篇
  2015年   1179篇
  2014年   1397篇
  2013年   1957篇
  2012年   2308篇
  2011年   2509篇
  2010年   1763篇
  2009年   1734篇
  2008年   1934篇
  2007年   1760篇
  2006年   1579篇
  2005年   1392篇
  2004年   1109篇
  2003年   904篇
  2002年   882篇
  2001年   740篇
  2000年   627篇
  1999年   581篇
  1998年   504篇
  1997年   444篇
  1996年   474篇
  1995年   388篇
  1994年   371篇
  1993年   342篇
  1992年   323篇
  1991年   277篇
  1990年   232篇
  1989年   191篇
  1988年   167篇
  1987年   129篇
  1986年   142篇
  1985年   155篇
  1984年   101篇
  1983年   64篇
  1982年   71篇
  1981年   53篇
  1980年   52篇
  1979年   58篇
  1978年   40篇
  1976年   37篇
  1974年   40篇
  1973年   45篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
81.
The present study is concerned with the determination of the optimal shape for a package containing multiple heating elements. The optimization tool has been developed based on the inverse heat transfer (IHT) approach, incorporating a direct problem solver, a numerical grid generator, a direct-differentiation sensitivity analyzer, and the conjugate gradient method. Shape design that leads to a specified outer surface temperature distribution is predicted by the approach. In this study, the effects of internal heat generation on optimal shapes of the packagings have also been evaluated. Several practical cases with various imbedded heating elements and thermal conditions are studied. Results show that the approach provides an efficient computer-aided design scheme for the shape profile determination.  相似文献   
82.
83.
We report on electron g-factor in an InAs-inserted In0.53Ga0.47As/In0.52Al0.48As heterostructure. The gate voltage dependence of g-factor is obtained from the coincidence method. The obtained g-factor values are surprisingly smaller than the g-factor value of bulk InAs, and it is close to the bare g-factor value of In0.53Ga0.47As. The large change in g-factor is observed by applying the gate voltage. The obtained gate voltage dependence is not simply explained by the energy dependence of g-factor.  相似文献   
84.
By using microlocal analysis, the propagation of weak singularities in Cauchy problems for quasilinear thermoelastic systems in three space variables are investigated. First, paradifferential operators are employed to decouple the quasilinear thermoelastic systems. Second, by investigating the decoupled hyperbolic-parabolic systems and using the classical bootstrap argument, the property of finite propagation speeds of singularities in Cauchy problems for the quasilinear thermoelastic systems is obtained. Finally, it is shown that the microlocal weak singularities for Cauchy problems of the thermoelastic systems are propagated along the null bicharacteristics of the hyperbolic operators.  相似文献   
85.
Great attention is currently paid to the synthesis of polynuclear transition metal complexes as well as their photochemical, photophysical, and electrochemical properties. The design of multicomponent systems capable of performing useful light- and/or redox-induced function is of special interest1. The oxo-centered carboxylate-bridge trinuclear ruthenium clusters have been investigated extensively during recent decades because they have remarkable electron-transfer properties, intense visibl…  相似文献   
86.
The main object of this paper is to investigate several general families of hypergeometric polynomials and their associated single-, double-, and triple-integral representations. Some known or new consequences of the general results presented here, involving such classical orthogonal polynomials as the Jacobi, Laguerre, Hermite, and Bessel polynomials, and various other relatively less familiar hypergeometric polynomials, are also considered. Each of the integral representations, which are derived in this paper, may be viewed also as a linearization relationship for the product of two different members of the associated family of hypergeometric polynomials.  相似文献   
87.
本文介绍概率抽样法在钢球生产过程中的应用,通过此法确定钢球生产中各工序质量监测的最佳抽检方案,以确保产品被接受的概率最大。  相似文献   
88.
Certain 1‐ethyl‐ and 1‐aryl‐6‐fluoro‐1,4‐dihydroquinol‐4‐one derivatives were synthesized and evaluated for antimycobacterial and cytotoxic activities. Preliminary results indicated that, for 1‐aryl‐6‐fluoroquinolones, both 7‐(piperazin‐1‐yl)‐ and 7‐(4‐methylpiperazin‐1‐yl) derivatives, 9b and 11a , are able to completely inhibit the growth of M. tuberculosis at a concentration of 6.25 μg/ml, while the 7‐[4‐(2‐oxo‐2‐phenylethyl)piperazin‐1‐yl] derivative 13 exhibits only 31% growth inhibition at the same concentration. For 1‐ethyl‐6‐fluoroquinolones, both 7‐[4‐(2‐oxopropyl)piperazin‐1‐yl]‐ and 7‐[4‐(2‐oxo‐2‐phenylethyl)piperazin‐1‐yl]‐derivatives, 2a and 2b , respectively, show complete inhibition, while their 2‐iminoethyl and substituted phenyl counterparts 3a and 2c are less active. In addition, the 6,8‐difluoro derivative was a more‐favorable inhibitor than its 6‐fluoro counterpart ( 2b vs. 2d ). These results deserve full attention especially because 2a, 2b, 9b , and 11a are non‐cytotoxic at a concentration of 100 μM . Furthermore, compound 9b proved to be a potent anti‐TB agent with selective index (SI)>40 and an EC90 value of 5.75 μg/ml.  相似文献   
89.
90.
N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine was synthesized from N‐(4‐nitrophenyl)‐diphenylamine by the Vilsmeier‐Haack reaction. Soluble aromatic poly(azomethine)s (PAMs) were prepared by the solution polycondensation of N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine and aromatic diamine in N‐methyl‐2‐pyrrolidone (NMP) at room temperature under reduced pressure. All the PAMs are highly soluble in various organic solvents, such as N,N‐dimethylacetamide (DMAc), chloroform (CHCl3), and tetrahydrofuran (THF). Differential scanning calorimetry (DSC) indicated that these PAMs had glass‐transition temperatures (Tgs) in the range of 170–230 °C, and a 10% weight‐loss temperatures in excess of 490 °C with char yield at 800 °C in nitrogen higher than 60%. These PAMs in NMP solution showed UV‐Vis charge‐transfer (CT) absorption at 405–421 nm and photoluminescence peaks around 462–466 nm with fluorescence quantum efficiency (ΦF) 0.10–0.99%. The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energy levels of these PAMs can be determined from cyclic voltammograms as 4.86–5.43 and 3.31–3.34 eV, respectively. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4921–4932, 2007  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号