Direct chemical ionization mass silylated iridoid glucosides

The direct chemical ionization mass spectra with isobutane of 14 silylated iridoid glucosides of different structural types were studied. The dependence of the intensity of different peaks on the structure and stereochemistry of the investigated compounds is discussed.     

A mechanism for generation of strong energy fluctuations in one-dimensional systems

A mechanism for the generation of strong energy fluctuations in a chain of harmonically and anharmonically coupled atoms in a state of thermodynamic equilibrium has been investigated by a molecular dynamics method. Energy fluctuations multiply exceeding the mean value were localized in a group of three to five atoms with lifetime on the order of an atomic vibrational period. They arise as a consequence of collisions of density waves propagating along the chain. A collision of waves of the same density sign leads to a fluctuation of the potential energy, while for differing signs a fluctuation in the kinetic energy occurs. In particular, collision of dilitatin waves leads to thermal breaking of the chain. The energy concentration at the moment of collision is 30% greater in a harmonic chain than in an anharmonic one.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 47–52, May, 1991.     

Synthesis of Phosphocapped Derivatives of β-Cyclodextrin

Russian Journal of General Chemistry -     

DICSI station at KCSR and NT: Determination of optimal requirements to the formation of an SR beam using cylindrical x-ray optical zoom lenses

To modernize the DICSI station, new hardware and software have been created according to the conditions of the operating storage ring “Sibir’-2” beam channel. The recording system has been successfully tested on the operating channel of the storage ring VEPP-3 (Budker Institute of Nuclear Physics Siberian Branch, Russian Academy of Sciences, Novosibirsk) using the time-resolved “diffraction cinema” technique in studying real biological objects in the static and dynamic modes of data accumulation. At the DICSI station, structural changes in medical and biological objects are permanently investigated. The specific structure dimensions of these objects are in the nanometric range.     

The influence of crystalline grain size on the thermal stability of the Er<Subscript>0.45</Subscript>Ho<Subscript>0.55</Subscript>Fe<Subscript>2</Subscript> compound

The phase composition and the temperature dependence of the magnetization of the Er_0.45Ho_0.55Fe₂ compound in coarse-grained, microcrystalline, and submicrocrystalline states are investigated experimentally. It is found that, upon heating under vacuum, the Er_0.45Ho_0.55Fe₂ microcrystalline powder with a crystalline grain size of ∼1 μm undergoes decomposition into pure iron and rare-earth (erbium and holmium) oxides and nitrides at a temperature of 500 K. The changes observed in the phase composition of the microcrystalline powder due to annealing are confirmed by x-ray diffraction analysis. Heating of the Er_0.45Ho_0.55Fe₂ submicrocrystalline sample leads to a partial change in the phase composition. The phase composition of a large crystal (∼1 mm in size) remains unchanged upon heating to 1080 K. It is shown that the thermal stability of the Er_0.45Ho_0.55Fe₂ compound depends on the crystalline grain size. __________ Translated from Fizika Tverdogo Tela, Vol. 44, No. 6, 2002, pp. 1060–1063. Original Russian Text Copyright ? 2002 by Mulyukov, Sharipov, Korznikova.     

Muonium states in semiconductor crystals: Quantum-chemical calculations

The electronic structure of muonium (Mu) located at the bond-centered sites of the silicon and diamond crystals is calculated by the intermediate neglect of differential overlap method. Calculations of the electronicg- and hyperfine interaction tensors of the impurity atom are performed. The results obtained are compared to the experimental properties of “anomalous” muonium Mu^*. It is shown that the properties of Mu located at the bond-centered sites of the Si and C lattices are in qualitative agreement with the observed properties of Mu^*.     

Gas-liquid chromatography of perfluorocarboxylic thioesters

Perfluorocarboxylic thioesters R_FC(O)SR (R_F=CF₃(CF₂)_j, R=CH₃(CH₂)_i, i andj=0–5) were studied for the first time by GLC on packed columns using SE-30, SKTFT-50X, and XE-60 as the stationary phase. The values of thermodynamics functions of sorption were calculated. The correlations between these functions and the molecular structures as well as the conditions of analysis were established. The insertion of the S atom into the molecules of derivatives of perfluorocarboxylic acids causes a decrease in the contribution of the orientation interaction and an increase in the dispersion interaction of thioesters with the stationary phases compared to esters and amides of perfluorocarboxylic acids studied previously. For Part 1, see Ref. 1. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1165–1168, June, 1997.     

Inhomogeneities in silicon p-n-junctions

Latent macroscopic defects in silicon are detected by electrical and electron microscope measurements. They lead to anomalous temperature dependence of the Fermi level position and growth in the hole capture coefficient. A level with energy of 0.55 eV measured from the conduction zone controls the recombination process. It is proposed that macroscopic defects develop upon association of oxygen-silicon vacancy complexes. Action of an electron beam leads to reversible changes which increase upon multiple scanning, affecting the value of the diffusion length.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 4, pp. 71–75, April, 1991.     

Optical quenching of the magnetoplastic effect in NaCl crystals

Observations indicate that illuminating NaCl crystals by ultraviolet light (λ=350 nm) suppresses the magnetoplastic effect. The processes induced by illumination take place in a subsystem of point defects and are related to a change in the state of magnetically sensitive dislocation pinning sites. Fiz. Tverd. Tela (St. Petersburg) 39, 1389–1391 (1996)