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71.
Silva BV Violante FA Pinto AC Santos LS 《Rapid communications in mass spectrometry : RCM》2011,25(3):423-428
Using electrospray ionization (tandem) mass spectrometry (ESI-MS(/MS)) spectrometric experiments, the Sandmeyer reaction was monitored on-line, and key intermediates were intercepted and characterized for the first time. The mechanistic information provided by on-line ESI-MS(/MS) is in accordance with Sandmeyer's proposal, and was made possible by coupling a microreactor on-line to the ESI ion source, which allowed reactions to be screened from 0.7-2.0 s, identifying and characterizing all intermediates that were formed and consumed during the reaction. 相似文献
72.
Leonardo I. Farfan-Cabrera Mariana Franco-Morgado Armando Gonzlez-Snchez Jos Prez-Gonzlez Benjamín M. Marín-Santibez 《Molecules (Basel, Switzerland)》2022,27(4)
Lubricants are materials able to reduce friction and/or wear of any type of moving surfaces facilitating smooth operations, maintaining reliable machine functions, and reducing risks of failures while contributing to energy savings. At present, most worldwide used lubricants are derived from crude oil. However, production, usage and disposal of these lubricants have significant impact on environment and health. Hence, there is a growing pressure to reduce demand of this sort of lubricants, which has fostered development and use of green lubricants, as vegetable oil-based lubricants (biolubricants). Despite the ecological benefits of producing/using biolubricants, availability of the required raw materials and agricultural land to create a reliable chain supply is still far from being established. Recently, biomass from some microalgae species has attracted attention due to their capacity to produce high-value lipids/oils for potential lubricants production. Thus, this multidisciplinary work reviews the main chemical-physical characteristics of lubricants and the main attempts and progress on microalgae biomass production for developing oils with pertinent lubricating properties. In addition, potential microalgae strains and chemical modifications to their oils to produce lubricants for different industrial applications are identified. Finally, a guide for microalgae oil selection based on its chemical composition for specific lubricant applications is provided. 相似文献
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Richard De la cruz Juan Galvis Juan Carlos Juajibioy Leonardo Rendón 《Bulletin of the Brazilian Mathematical Society》2016,47(1):277-290
We study the one-dimensional Riemann problem for a hyperbolic system of three conservation laws of Temple class. The system is a simplification of a recently proposed system of five conservations laws by Bouchut and Boyaval that models viscoelastic fluids. An important issue is that the considered 3×3 system is such that every characteristic field is linearly degenerate. We study theRiemann problemfor this system and under suitable generalized Rankine-Hugoniot relation and entropy condition, both existence and uniqueness of particular delta shock type solutions are established. 相似文献
75.
We developed a constituent quark-diquark model for the nucleon and its resonances using a harmonic oscillator potential for
the interaction. The effects due to relativistic kinetic energy correction are studied. Finally, charge form factor of the
model is calculated and compared with experimental data.
相似文献
76.
Optics and Spectroscopy - Fifth generation ethylendiamine-core poly(amidoamine) (PAMAM G5)-capped-gold-nanoparticles were prepared by ps laser ablation in water, by using the third harmonic of a ps... 相似文献
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79.
Lizarraga L Andrade EM Florit MI Molina FV 《The journal of physical chemistry. B》2005,109(40):18815-18821
The quasi-equilibrium electrochemomechanical behavior of relatively thick polyaniline films in sulfuric acid is investigated through experimental measurements and theoretical modeling. The leucoemeraldine (LE)-emeraldine (EM) conversion, or redox switching, is studied. The dependence of film volume and electrochemical charge is determined as a function of applied potential. It is observed that the film volume follows the charge, showing an expansion during the second half of the LE-EM oxidation. The model postulates the existence of a stable intermediate, protoemeraldine (PE), with a formal potential distribution for the PE-EM reaction. The volume change is modeled statistically considering contributions from mixing, polymer deformation, and electrostatic charge. The model shows very good agreement with the experiments, indicating that, in the conditions studied, the deformation contribution dominates the volume changes as a result of the conformational modifications undergone by the polymer in the PE-EM oxidation. 相似文献
80.
We devise a technique for defining and computing -point functions in the context of a background-independent gravitational quantum field theory. We construct a tentative implementation of this technique in a perturbatively finite model defined using spin foam techniques in the context of loop quantum gravity. 相似文献