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81.
Fork/join stations are commonly used to model the synchronization constraints in queuing models of computer networks, fabrication/assembly systems and material control strategies for manufacturing systems. This paper presents an exact analysis of a fork/join station in a closed queuing network with inputs from servers with two-phase Coxian service distributions, which models a wide range of variability in the input processes. The underlying queue length and departure processes are analyzed to determine performance measures such as throughput, distributions of the queue length and inter-departure times from the fork/join station. The results show that, for certain parameter settings, variability in the arrival processes has a significant impact on system performance. The model is also used to study the sensitivity of performance measures such as throughput, mean queue lengths, and variability of inter-departure times for a wide range of input parameters and network populations. 相似文献
82.
This paper addresses the finite size 1-center placement problem on a rectangular plane in the presence of barriers. Barriers are regions in which both facility location and travel through are prohibited. The feasible region for facility placement is subdivided into cells along the lines of Larson and Sadiq [R.C. Larson, G. Sadiq, Facility locations with the Manhattan metric in the presence of barriers to travel, Operations Research 31 (4) (1983) 652–669]. To overcome complications induced by the center (minimax) objective, we analyze the resultant cells based on the cell corners. We study the problem when the facility orientation is known a priori. We obtain domination results when the facility is fully contained inside 1, 2 and 3-cornered cells. For full containment in a 4-cornered cell, we formulate the problem as a linear program. However, when the facility intersects gridlines, analytical representation of the distance functions becomes challenging. We study the difficulties of this case and formulate our problem as a linear or nonlinear program, depending on whether the feasible region is convex or nonconvex. An analysis of the solution complexity is presented along with an illustrative numerical example. 相似文献
83.
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85.
The interaction of the antidepressant drug nortriptyline hydrochloride (NOT) with the surface-active ionic liquid (SAIL), 1-decyl-3-methylimidazolium chloride, [C10mim][Cl], has been studied using multiple techniques, including conductometric titration, tensiometric, fluorometric, dynamic light scattering and UV–visible spectrophotometric measurements. There is a significant decrease in the cmc of SAIL on the addition of the drug NOT, indicating adsorption of drug molecules in the outer portion of the micelle. In the present study, the values of the packing parameter, P, lie in the range of 0–0.3, which suggests that the micelles formed are spherical in nature. More negative values of the standard Gibbs energy of adsorption, \( \Delta G_{\text{ad}}^{ \circ } \), compared to \( \Delta G_{\text{m}}^{ \circ } \) support our contention that adsorption of SAIL on the air-solution interface is relatively more favorable than its micellization in the presence of NOT. Fluorescence and DLS studies indicate that the aggregation number, Nagg, and hydrodynamic radius of SAIL increase with increase in concentration of NOT. The UV–visible spectroscopic study confirms the formation of a new complex between SAIL and NOT; this is also supported by the negative Gibbs energy of complexation. 相似文献
86.
Several papers have appeared in the literature describing the determination of antimony, where antimony(V) is extracted into the organic phase and the organic solutions directly analyzed by atomic absorption spectrometry (AAS). This paper describes a procedure where antimony from the organic solution is reductively stripped into an aqueous phase and analyzed for antimony by AAS. The advantage of the method for a routine process control laboratory is highlighted. 相似文献
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88.
A. B. Deshpande C. R. Rajan S. L. Kapur 《Journal of polymer science. Part A, Polymer chemistry》1973,11(6):1317-1320
Vanadium-based catalyst complexes prepared in the presence of monomers have been used for the copolymerization of styrene and acrylonitrile. VOCl3–Al(i-C4H9)3 catalyst system seems to yield an alternating copolymer. The copolymers are easily soluble in DMF and have low softening points. 相似文献
89.
B. S. Uphade P. S. Patil S. B. Pandit C. R. Rajan V. M. Nadkarni 《Journal of polymer science. Part A, Polymer chemistry》1994,32(11):2003-2010
Kinetics of polyesterification of maleic anhydride with polyethylene glycol (PEG) of varying molecular weights have been evaluated. The investigations have been carried out by employing heating cycles comparable to those employed in industrial processes and under nonisothermal conditions. The rate of reaction was found to decrease with increase in the chain length of the polyether. The energy of activation was estimated as 26.91, 40.25, and 47.30 Kcal/mol for PEG of molecular weights 200, 300, and 400, respectively. © 1994 John Wiley & Sons, Inc. 相似文献
90.
R. Harikrishna S. Ponrathnam C. R. Rajan S. S. Tambe 《Journal of Thermal Analysis and Calorimetry》2013,112(2):805-813
A solid urethane acrylate macromonomer with bis-aromatic as well as alicyclic moieties was synthesized and the kinetics of photopolymerization reactions were studied in the presence of varying concentration of photoinitiator and large excess of reactive diluent using photo DSC. The studies show that the rate of maximum polymerization was found to increase with increase in concentration of photoinitiator while a decrease was observed by an increase in temperature. The final conversion showed a decrease at highest isothermal condition due to vitrification. Estimation of kinetic parameters including applicability of autocatalytic and modified autocatalytic models were investigated by nonlinear regression. It was observed that the modified models gave a better fit with the experimental data and kinetic parameters showed a decrease with increase in temperature and an increase with increase in concentration of photoinitiator. 相似文献