Bulk Viscous Cosmological Model with Interacting Dark Fluids

We study a cosmological model for a spatially flat Universe whose constituents are a dark energy field and a matter field comprising baryons and dark matter. The constituents are assumed to interact with each other, and a non-equilibrium pressure is introduced to account for irreversible processes. We take the non-equilibrium pressure to be proportional to the Hubble parameter within the framework of a first-order thermodynamic theory. The dark energy and matter fields are coupled by their barotropic indexes, which depend on the ratio between their energy densities. We adjust the free parameters of the model to optimize the fits to the Hubble parameter data. We compare the viscous model with the non-viscous one, and show that the irreversible processes cause the dark-energy and matter-density parameters to become equal and the decelerated–accelerated transition to occur at earlier times. Furthermore, the density and deceleration parameters and the distance modulus have the correct behavior, consistent with a viable scenario of the present status of the Universe.     

An electroactive nickel containing polymeric film obtained by electrochemical reduction of an aryl-nickel derivative

The electrochemical reduction of [Ni(PPh₃)₂(p-C₆H₄Br)Br] in acetonitrile results in a polymeric coating of a nickel-containing poly-p-phenylene, formulated as [-Ni(p-C₆H₄)_n-] (n=6?7) on the basis of elemental analysis, IR, UV, MS and ESCA measurements. This coating is found to undergo a two-electron reversible reduction and a one-electron reversible oxidation with a large potential window (3.6 V), without the polymeric film being destroyed. Moreover, the polymer obtained is shown to be electroactive towards dissolved reactants via permeation or mediated electron transfer, depending on the molecular size of the electroactive species employed.     

On the physical interpretation of asymptotically flat gravitational fields

A problem in general relativity is how to extract physical information from solutions to the Einstein equations. Most often information is found from special conditions, e.g., special vector fields, symmetries or approximate symmetries. Our concern is with asymptotically flat space–times with approximate symmetry: the BMS group. For these spaces the Bondi four-momentum vector and its evolution, found at infinity, describes the total energy–momentum and the energy–momentum radiated. By generalizing the simple idea of the transformation of (electromagnetic) dipoles under a translation, we define (analogous to center of charge) the center of mass for asymptotically flat Einstein–Maxwell fields. This gives kinematical meaning to the Bondi four-momentum, i.e., the four-momentum and its evolution which is described in terms of a center of mass position vector, its velocity and spin-vector. From dynamical arguments, a unique (for our approximation) total angular momentum and evolution equation in the form of a conservation law is found. Third Award in the 2008 Essay Competition of the Gravity Research Foundation.     

Reflectance and ultraviolet spectroscopy: predicting the relative growth of Saccharomyces cerevisiae in pine biomass

Ultrasound treatment favors enzymatic attack on vegetal materials and influences biological activity. The objective of this study was to develop substrates for Saccharomyces cerevisiae based on the hydrothermal treatment and ultrasound treatment of pine needle biomass. The samples subjected to ultrasound treatment at 550?°C and 650?°C showed higher reflectance bands at around 200?nm after 80?min of ultrasound treatment and lower band gap energies associated with lower IC₃₀ values. The hydrothermal treatment with 100?min of ultrasound treatment generated more promising materials for the use of the substrates with the eukaryotic model S. cerevisiae.     

Cathodically deposited polypyridine films: A novel electroactive polyconjugated polymer

Poly-2,5- and poly-2,6-pyridine coatings have been produced on glassy-carbon electrodes by nickelcatalysed reduction of the corresponding dibromopyridine in acetonitrile. Poly-2,5-pyridine films display two reversible cathodic cycles, one of which is due to nickel ions coordinated to pyridine moieties and the other to the polymeric backbone. Both reductions lead to the polymer changing from the insulating to the conductive state. Conversely, Poly-2,6-pyridine films are not reversibly electroactive and the differences are discussed in terms of conjugation along the polymeric chain.     

Heat conduction through a rarefied gas between two rotating cylinders at small temperature difference

Summary Numerical calculations of heat transfer between two coaxial rotating cylinders at a small temperature difference are carried out over wide ranges of the Knudsen number and the angular velocity. The calculations have been performed based on the S-model of the Boltzmann equation by the discrete velocity method. It has been confirmed that in a rotating gas a radial temperature gradient causes both radial and tangential heat fluxes. Also, it has been found that the radial heat flux is affected by the rotation.On temporary leave from Department of Physics, Urals State University, 620083 Ekaterinburg, Russia.     

Synthesis and luminescent properties of Eu-complexes with 2-acyl-1,3-indandionates (ACIND) and TPPO ligands: The first X-ray structure of Eu–ACIND complex

Europium complexes presenting general formulas [Eu(ACIND)₃(H₂O)₂] and [Eu(ACIND)₃(TPPO)₂] have been synthesized and characterized. In these formulas ACIND is stands for the ligands 2-acetyl-1,3-indandionate (AIND), 2-isovaleryl-1,3-indandionate (ISOVIND) or 2-benzyl-1,3-indandionate (BIND). The [Eu(ISOVIND)₃(H₂O)(EtOH)] complex was also prepared and its structure determined by single crystal X-ray analysis, showing that this complex crystallize in a monoclinic space group P2₁/n with the water molecules bridging through the hydrogen bond. The Eu(III) ion is eight-coordinate in a bicapped trigonal prismatic geometry defined by the oxygen donor atoms with a site of symmetry close to C_2ν. Isovaleryl groups in the ISOVIND molecules in the structure are disordered over two positions of the europium complex. Carbon atoms in ethanol molecule are disordered by the thermal vibration. Photoluminescence properties of these complexes in solid state were investigated both experimentally and theoretically, suggesting an efficient ligand-to-metal intramolecular energy transfer process.