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排序方式: 共有331条查询结果,搜索用时 78 毫秒
11.
Marek Mooste Elo Kibena Ave Sarapuu Uno Mäeorg Gilberto Maia Kaido Tammeveski 《Journal of Solid State Electrochemistry》2014,18(6):1725-1733
Anthraquinone groups were electrochemically grafted to glassy carbon (GC) electrodes via methylene linker to study the oxygen reduction reaction (ORR) in alkaline medium. Two different anthraquinone derivatives, 2-bromomethyl-anthraquinone or 2-chloromethyl-anthraquinone, were used to modify the GC electrode surface. Several modification conditions encompassing potential cycling and electrolysis at a fixed potential were employed in order to vary the surface concentration of MAQ groups (Γ MAQ) and to study the dependence of the O2 reduction behaviour on electrografting procedure. Cyclic voltammetry confirmed the presence of anthraquinone moieties attached to the GC electrode and Γ MAQ varied in the range of (0.5–2.4)?×?10?10 mol cm?2. Oxygen reduction was studied on MAQ-modified GC electrodes of various surface coverage using the rotating disc electrode (RDE) and rotating ring-disc electrode (RRDE) methods. The RDE and RRDE results of O2 reduction reveal that GC/MAQ electrodes show rather similar electrocatalytic behaviour towards the ORR yielding hydrogen peroxide as the final product. 相似文献
12.
Amanda L. Santos Gilberto O. Chierice Kenneth S. Alexander Alan Riga Ellen Matthews 《Journal of Thermal Analysis and Calorimetry》2009,96(3):821-825
Eugenol is the main volatile compound extracted oil from clove bud, Syzygium aromaticum L., and used in traditional medicine, as a bactericide, fungicide, anesthetic, and others. Its extraction was performed using
hydrodistillation which is the most common extraction technique. Its components and thermal behavior were evaluated using
gas chromatography (GC) and differential scanning calorimetry (DSC), which provide a better characterization of these natural
compounds. This extracted product was compared to the standard eugenol results. The GC results suggested ~90% eugenol was
found in the total extracted oil, and some of its boiling characteristics were 270.1 °C for peak temperature and 244.1 J g−1 for the enthalpy variation.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
13.
Diego Alberto Lomelí-Rosales Adalberto Zamudio-Ojeda Oscar Kevin Reyes-Maldonado Morelia Eunice Lpez-Reyes Georgina Cristina Basulto-Padilla Edgar Jos Lopez-Naranjo Víctor Manuel Zuiga-Mayo Gilberto Velzquez-Jurez 《Molecules (Basel, Switzerland)》2022,27(5)
So far, several studies have focused on the synthesis of metallic nanoparticles making use of extracts from the fruit of the plants from the genus Capsicum. However, as the fruit is the edible, and highly commercial, part of the plant, in this work we focused on the leaves, a part of the plant that is considered agro-industrial waste. The biological synthesis of gold (AuNPs) and silver (AgNPs) nanoparticles using aqueous extracts of root, stem and leaf of Capsicum chinense was evaluated, obtaining the best results with the leaf extract. Gold and silver nanoparticles synthesized using leaf extract (AuNPs-leaf and AgNPs-leaf, respectively) were characterized by UV-visible spectrophotometry (UV-Vis), Fourier Transform Infrared Spectroscopy with Attenuated Total Reflection (FTIR-ATR), X-ray Photoelectron Spectroscopy (XPS), Ultra Hight Resolution Scanning Electron Microscopy coupled to Energy-Dispersive X-ray spectroscopy (UHR-SEM-EDX) and Transmission Electron Microscopy (TEM), and tested for their antioxidant and antimicrobial activities. In addition, different metabolites involved in the synthesis of nanoparticles were analyzed. We found that by the use of extracts derived from the leaf, we could generate stable and easy to synthesize AuNPs and AgNPs. The AuNPs-leaf were synthesized using microwave radiation, while the AgNPs-leaf were synthesized using UV light radiation. The antioxidant activity of the extract, determined by ABTS, showed a decrease of 44.7% and 60.7% after the synthesis of the AuNPs-leaf and AgNPs-leaf, respectively. After the AgNPs-leaf synthesis, the concentration of polyphenols, reducing sugars and amino acids decreased by 15.4%, 38.7% and 46.8% in the leaf extract, respectively, while after the AuNPs-leaf synthesis only reducing sugars decreased by 67.7%. These results suggest that these groups of molecules are implicated in the reduction/stabilization of the nanoparticles. Although the contribution of these compounds in the synthesis of the AuNPs-leaf and the AgNPs-leaf was different. Finally, the AgNPs-leaf inhibited the growth of S. aureus, E. coli, S. marcescens and E. faecalis. All of them are bacterial strains of clinical importance due to their fast antibiotic resistance development. 相似文献
14.
We introduce a thermal conductance by using the fluctuation-dissipation theorem to analyze the heat transfer between two nanoparticles separated by a submicron distance. Using either a molecular dynamics technique or a model based on the Coulomb interaction between fluctuating dipoles, we derive the thermal conductance. Both models agree for distances larger than a few diameters. For separation distances smaller than the particle diameter, we find a transition regime characterized by a thermal conductance larger than the contact conductance. 相似文献
15.
Pérez EM Dryden DT Leigh DA Teobaldi G Zerbetto F 《Journal of the American Chemical Society》2004,126(39):12210-12211
A novel type of mechanical switch is described in which light-induced translation of a macrocycle in a [2]rotaxane quenches anthracene fluorescence. Features of the system include the remarkable 200:1 difference in fluorescence intensity between the two positional states of the molecule ( approximately 85:1 between one isomer and the photostationary state). In principle the same concept could be used for mechanically switching virtually any property that can be influenced by functional group proximity effects. 相似文献
16.
Gilberto Siqueira Sandra Tapin-Lingua Julien Bras Denilson da Silva Perez Alain Dufresne 《Cellulose (London, England)》2011,18(1):57-65
In a previous work (Siqueira et al. 2010b) the preparation of cellulosic nanoparticles from sisal fibers using different processing routes, viz. a combination of
mechanical shearing, acid and enzymatic hydrolysis was reported. It was shown that the pre-enzymatic hydrolysis treatment
of bleached sisal pulp helps the preparation of well individualized rod-like nanocrystals. An amorphous polymer (natural rubber—NR)
was chosen as model matrix to investigate the effect of these nanoparticles on the thermo-mechanical properties of nanocomposites.
Both tensile tests and dynamic mechanical analyses showed improved stiffness for all nanocomposites. The enzymatic treatment
allowed production of a huge range of cellulosic nanoparticles which provided completely different mechanical properties to
NR matrix. 相似文献
17.
Gilberto Muñoz Moreno Noé Alcalá Ochoa 《Optics and Lasers in Engineering》2011,49(6):663-667
An analysis of phase modifications introduced by laser jitter in frequency-domain optical coherence tomography (OCT) is described. It is shown that a 1D spurious phase function is introduced as a consequence of this phenomenon. This phase function is added to any other introduced by the object under analysis causing a superposition of both. The result may impose some limitations for unambiguous determination of phase changes of objects. Experimental and theoretical results are presented. 相似文献
18.
The traditional way of employing operational research in organisational interventions has been the expert mode. In this mode, the problem situation faced by the client is given to the operational research consultant, who then builds a model of the situation, solves the model to arrive at an optimal (or quasi-optimal) solution, and then provides a recommendation to the client based on the obtained solution. An alternative mode of engagement is to conduct the whole intervention together with the client: from structuring and defining the nature of the problem situation of interest, to supporting the evaluation of priorities and development of plans for subsequent implementation. In this latter mode, the operational researcher works throughout the intervention not only as an analyst, but also as a facilitator to the client. This paper discusses this latter mode of engagement with clients, with particular emphasis on the use of facilitated modelling as the intervention tool. Drawing on research scattered across a range of publications and domains, the review presented here provides a formal definition of facilitated modelling, together with a general framework that allows the conceptualisation of a wide variety of facilitated modelling approaches to organisational intervention. Design issues in facilitated modelling and their practical implication are discussed, and directions for future research identified. 相似文献
19.
Carlos Kozameh Ezra T. Newman Gilberto Silva-Ortigoza 《General Relativity and Gravitation》2008,40(10):2043-2050
A problem in general relativity is how to extract physical information from solutions to the Einstein equations. Most often
information is found from special conditions, e.g., special vector fields, symmetries or approximate symmetries. Our concern
is with asymptotically flat space–times with approximate symmetry: the BMS group. For these spaces the Bondi four-momentum
vector and its evolution, found at infinity, describes the total energy–momentum and the energy–momentum radiated. By generalizing
the simple idea of the transformation of (electromagnetic) dipoles under a translation, we define (analogous to center of
charge) the center of mass for asymptotically flat Einstein–Maxwell fields. This gives kinematical meaning to the Bondi four-momentum,
i.e., the four-momentum and its evolution which is described in terms of a center of mass position vector, its velocity and
spin-vector. From dynamical arguments, a unique (for our approximation) total angular momentum and evolution equation in the
form of a conservation law is found.
Third Award in the 2008 Essay Competition of the Gravity Research Foundation. 相似文献
20.