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101.
Sanguineti A Monguzzi A Vaccaro G Meinardi F Ronchi E Moret M Cosentino U Moro G Simonutti R Mauri M Tubino R Beverina L 《Physical chemistry chemical physics : PCCP》2012,14(18):6452-6455
A new oxyiminopyrazole-based ytterbium chelate enables NIR emission upon UV excitation in colorless single layer luminescent solar concentrators for building integrated photovoltaics. 相似文献
102.
Kordatos Konstantinos Prato Maurizio Menna Enzo Scorrano Gianfranco Maggini Michele 《Journal of Sol-Gel Science and Technology》2001,22(3):237-244
We report on the synthesis of fullerene derivatives containing a trialkoxysilane moiety that exhibit enhanced solubility in solvents commonly used for sol-gel processing. These derivatives have been successfully embedded in glassy bulk samples and thin films that show very promising optical limiting properties. 相似文献
103.
Gianfranco Romanazzi Yann Oronneau Marwa Moumni Yann Davillerd Patrice Andr Marchand 《Molecules (Basel, Switzerland)》2022,27(11)
Synthetic pesticides are widely used to protect crops from pathogens and pests, especially for fruits and vegetables, and this may lead to the presence of residues on fresh produce. Improving the sustainability of agriculture and, at the same time, reducing the adverse effects of synthetic pesticides on human health requires effective alternatives that improve the productivity while maintaining the food quality and safety. Moreover, retailers increasingly request fresh produce with the amounts of pesticides largely below the official maximum residue levels. Basic substances are relatively novel compounds that can be used in plant protection without neurotoxic or immune-toxic effects and are still poorly known by phytosanitary consultants (plant doctors), researchers, growers, consumers, and decision makers. The focus of this review is to provide updated information about 24 basic substances currently approved in the EU and to summarize in a single document their properties and instructions for users. Most of these substances have a fungicidal activity (calcium hydroxide, chitosan, chitosan hydrochloride, Equisetum arvense L., hydrogen peroxide, lecithins, cow milk, mustard seed powder, Salix spp., sunflower oil, sodium chloride, sodium hydrogen carbonate, Urtica spp., vinegar, and whey). Considering the increasing requests from consumers of fruits and vegetables for high quality with no or a reduced amount of pesticide residues, basic substances can complement and, at times, replace the application of synthetic pesticides with benefits for users and for consumers. Large-scale trials are important to design the best dosage and strategies for the application of basic substances against pathogens and pests in different growing environments and contexts. 相似文献
104.
The electronic structure of linear RhC0 and PdCO molecules has been studied by means of effective core potential calculations including configuration interaction. The study of the 4Δ and 2Σ+ states of RhCO and the 3Σ+ and 1Σ+ states of PdCO has shown that their low-spin states are bound and their high-spin states are repulsive. The binding energies of RhCO and PdCO are 4.0 and 7.2 kcal/mol, for the equilibrium bond lengths of 3.87 and 4.03 au, respectively. The interaction between the diffuse 5s metal orbital and the carbon lone pair produces a repulsion in the α-space, as depicted by the negative region along the metal-carbon axis in the electron density difference contour maps. The bonding in low-spin states of RhCO and PdCO is due to the metal-CO π “backdonation”. The present investigation on RhCO and PdCO, preliminary results on ScCO, as well as published results on FeCO, NiCO, CuCO and PtCO allows us to make a general conjecture that a low occupancy of the outer s atomic orbital of the transition metal atom in the complex favours the bonding interaction with the CO moiety. The analogy with properties of LiCO and NaCO systems is pointed out. 相似文献
105.
Gianfranco Chiocchia 《Meccanica》1994,29(1):43-60
The initial aim of this work was the estimation of the lift acting on a flat plate performing small oscillations in a plane uniform stream by means of a simplified model based on one or at the most two lumped vortices, and the assessment of its results by comparison to those that were exact. The model was found to work well up to a reduced frequency of about 1 or 2, above which the results diverged from those that were correct. In order to improve the model, its behaviour at very high frequencies was then investigated, discovering: (i) that if the number of lumped vortices is greater than one the possibility to impose all boundary conditions is subject to certain geometrical constraints; (ii) that the asymptotical behaviour is not the right one. A straightforward extension of this conclusion to the exact case of a continuous, vorticity distribution simulating the motion of the plate and to the classical equation describing it leads apparently to an incorrect result. The reason for the discrepancy is found in the singularity displayed by the integral equation which cannot be reproduced by the discrete model. It this therefore concluded that the latter can be trusted at low and middle frequencies but its extension to higher ones is fundamentally uncorrect.
Sommario Lo scopo iniziale di questo lavoro era il calcolo approssimato della portanza agente su una lamina piana soggetta a piccole oscillazioni in una corrente bidimensionale uniforme per mezzo di un modello semplificato basato su uno o al più due vortici concentrati, e il confronto dei risultati con quelli esatti. Il modello risulta funzionare bene per frequenze ridotte inferiori ad 1 o 2, sopra le quali, tuttavia, i risultati si allontanano da quelli corretti. Per migliorarlo si è allora studiato il suo comportamento alle frequenze molto alte, scoprendo che: (i) la possibilità di imporre tutte le condizioni al contorno quando il numero dei vortici concentrati è superiore a uno è soggetta a certe limitazioni sulla configurazione geometrica; (ii) che il comportamento asindotico non è quello corretto. Un'estensione automatica di questa conclusione al caso esatto in cui il moto della lamina è simulato da una distribuzione continua di vorticità e alla classica equazione che lo descrive sembra condurre ad un risultato errato. La ragione di questa discrepanza viene individuata nella singolarità contenuta nell'equazione integrale, che non può essere riprodotta dal modello discreto. Se ne conclude perciò che esso è utilizzabile alle basse e medie frequenze ma che una sua estensione alle alte è fondamentalmente errata.相似文献
106.
Summary We introduce a class of second order elliptic operators from H
0
1
() to his dual space H–1(), where is an open set in Rn that we allow to be unbounded. We prove that such operators are continuously invertible and that the constant majoryzing the norm of their inverses depends only on the parameters of the class. We prove moreover that if T H–1() is given then the set of the L–1T, where L belongs to the mentioned class is relatively compact in L2(). Next we study the relationships between several kinds of convergence (one of them is the G-convergence) and we study in what cases the spectrum function is semicontinuous or continuous on certain subsets of our class of operators. 相似文献
107.
A series of new chiral diselenides with a N-atom in the side chain was prepared by a short synthetic sequence (Scheme 1). Only 1 mol-% of these diselenides catalyzed very effectively the diethylzinc addition to various aromatic and α,β-unsaturated aldehydes yielding the secondary alcohols in up to 98% ee (Scheme 2 and Tables 1 and 2). An asymmetric amplification was observed with these catalysts. Detailed NMR studies were performed to characterize the catalytically active species. 相似文献
108.
Ercolani G 《Journal of the American Chemical Society》2003,125(51):16097-16103
A method has been proposed to assess cooperativity in self-assembly processes. The method is based on a clear distinction between intermolecular and intramolecular processes which are compared with the corresponding reference reactions. It has been applied to two classical cases, namely the self-assembly of helicates and of porphyrin ladders, by using data previously published by the groups of Lehn and Anderson, respectively. Contrarily to the conclusions of the authors, pointing out self-assembly processes driven by positive cooperativity, the method here presented indicates in both cases the absence of cooperative effects. The methods previously used to assess cooperativity, in particular Scatchard plot and/or Hill plot, are criticized as being inappropriate for self-assembly, because they are pertinent to a specific case only, namely the intermolecular binding of a monovalent ligand L to a multivalent receptor M, a case very different from self-assembly which involves both inter- and intramolecular interactions. The present method underscores the fact that positive cooperativity in artificial self-assembling systems is probably much more rare than it was previously thought. 相似文献
109.
Giacomo Saielli Gianfranco Scorrano Alessandro Bagno Akihiro Wakisaka 《Chemphyschem》2005,6(7):1307-1315
The solvation of tetramethylammonium chloride (Me4NCl) and tetra-n-butylammonium chloride (Bu4NCl) in water-acetonitrile mixtures was investigated by mass spectrometry of clusters isolated from the solution. As far as the positive ions are concerned, clusters composed of alkylammonium ions and acetonitrile molecules only were observed, even for mixtures with high water content. In contrast, for the negative ions, clusters composed of chloride with both water and/or acetonitrile molecules were observed. For the smaller system (Me4NCl) we performed quantum chemical calculations and molecular dynamics simulations. It was found that even though water is present in the solvation shell of Me4N+, only acetonitrile has a strong electrostatic interaction with the cation. Water molecules around Me4N+ form hydrogen bonds with other water molecules, and they interact with Me4N+ mainly via dispersive interactions. These results indicate that Me4N+ behaves like a hydrophobic solute. On the other hand, the interaction of Cl- with water and acetonitrile is of comparable strength and, in both cases, the electrostatic interaction dominates. Herein we demonstrate experimentally and theoretically that positive and negative ions give rise to characteristic solvation structures in mixed solvents: even a relatively small organic cation, such as Me4N+, exhibits a hydrophobic-like solvation shell. 相似文献
110.
Gianfranco CainelliDaria Giacomini Massimo GazzanoPaola Galletti Arianna Quintavalla 《Tetrahedron letters》2003,44(33):6269-6272
This paper describes the different reactivity of E- and Z-4-alkylidene-β-lactams in acylation reactions under basic conditions. The E isomer is readily acylated, whereas the Z reacted sluggishly rearranging to the corresponding oxazin-6-one. The N-acylation of Z isomers was successfully obtained with oxalyl- or malonyl chlorides in benzene at reflux. 相似文献