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51.
Rocco Angelone Dr. Francesco Ciardelli Prof. Arturo Colligiani Prof. Francesco Greco Dr. Paolo Masi Prof. Annalisa Romano Dr. Giacomo Ruggeri Prof. 《Chemphyschem》2010,11(2):460-465
A derivative of 2‐methylindole, 3‐[2‐(4‐nitrophenyl)ethenyl]‐1‐allyl‐2‐methylindole, NPEMI‐A, is studied for its photoconductivity and photorefractivity behaviour. Its blends with the organic polymer poly‐(2,3‐dimethyl‐N‐vinylindole), PVDMI, are also investigated. Due to the expected and devised mutual solubility of the two components of the blends, it is possible to carry out measurements with the weight percent of the chromophore NPEMI‐A changing from zero to 100. Films were produced by a squeezing process between two ITO‐covered glass sheets. No opacity phenomena, that are so common for many other organic blends due to the segregation of the dissolved chromophore, are observed. The photorefractive optical gain Γ2 is obtained as a function of the chromophore content. Differential scanning calorimetry measurements (DSC) are also carried out to obtain the whole change of the glass transition temperature Tg as a function of the amount of chromophore contained in the blends. From the experimental trend of Tg a meaningful quantitative estimate of the value of the electrostatic interactions acting in the studied blends, is obtained. The importance of the value of Tg, and of the electrostatic interactions, in determining the extent of the photorefractivity is clearly evident. The results are compared for NPEMI‐A (Γ2=210 cm?1) and for NPEMI‐E (Γ2 ≈ 2000 cm?1) that has a N‐2‐ethylhexyl group instead of a N‐allyl group. The Pockels and Kerr contributions and—for the first time—a “collaborative effect” of the photorefractivity of NPEMI‐A are distinguished and quantitatively evaluated. 相似文献
52.
Livraghi S Corazzari I Paganini MC Ceccone G Giamello E Fubini B Fenoglio I 《Chemical communications (Cambridge, England)》2010,46(44):8478-8480
A safe UV filter may be obtained by inhibiting the photo-generation of free radicals through modification of the surface of TiO(2) nanoparticles with carbon. 相似文献
53.
Leo Liberti Nenad Mladenović Giacomo Nannicini 《Mathematical Programming Computation》2011,3(4):349-390
Finding good (or even just feasible) solutions for Mixed-Integer Nonlinear Programming problems independently of the specific
problem structure is a very hard but practically important task, especially when the objective and/or the constraints are
nonconvex. With this goal in mind, we present a general-purpose heuristic based on Variable Neighborhood Search, Local Branching,
a local Nonlinear Programming algorithm and Branch-and-Bound. We test the proposed approach on MINLPLib, comparing with several
existing heuristic and exact methods. An implementation of the proposed heuristic is freely available and can employ all NLP/MINLP
solvers with an AMPL interface as the main search tools. 相似文献
54.
In this paper we propose practical strategies for generating split cuts, by considering integer linear combinations of the
rows of the optimal simplex tableau, and deriving the corresponding Gomory mixed-integer cuts; potentially, we can generate
a huge number of cuts. A key idea is to select subsets of variables, and cut deeply in the space of these variables. We show
that variables with small reduced cost are good candidates for this purpose, yielding cuts that close a larger integrality
gap. An extensive computational evaluation of these cuts points to the following two conclusions. The first is that our rank-1
cuts improve significantly on existing split cut generators (Gomory cuts from single tableau rows, MIR, Reduce-and-Split,
Lift-and-Project, Flow and Knapsack cover): on MIPLIB instances, these generators close 24% of the integrality gap on average;
adding our cuts yields an additional 5%. The second conclusion is that, when incorporated in a Branch-and-Cut framework, these
new cuts can improve computing time on difficult instances. 相似文献
55.
We study quantum learning algorithms for quantum measurements. The optimal learning algorithm is derived for arbitrary von Neumann measurements in the case of training with one or two examples. The analysis of the case of three examples reveals that, differently from the learning of unitary gates, the optimal algorithm for learning of quantum measurements cannot be parallelized, and requires quantum memories for the storage of information. 相似文献
56.
G. Cristoforetti A. De Giacomo M. Dell'Aglio S. Legnaioli E. Tognoni V. Palleschi N. Omenetto 《Spectrochimica Acta Part B: Atomic Spectroscopy》2010
In the Laser-Induced Breakdown Spectroscopy (LIBS) technique, the existence of Local Thermodynamic Equilibrium (LTE) is the essential requisite for meaningful application of theoretical Boltzmann–Maxwell and Saha–Eggert expressions that relate fundamental plasma parameters and concentration of analyte species. The most popular criterion reported in the literature dealing with plasma diagnostics, and usually invoked as a proof of the existence of LTE in the plasma, is the McWhirter criterion [R.W.P. McWhirter, in: Eds. R.H. Huddlestone, S.L. Leonard, Plasma Diagnostic Techniques, Academic Press, New York, 1965, pp. 201–264]. However, as pointed out in several papers, this criterion is known to be a necessary but not a sufficient condition to insure LTE. The considerations reported here are meant to briefly review the theoretical analysis underlying the concept of thermodynamic equilibrium and the derivation of the McWhirter criterion, and to critically discuss its application to a transient and non-homogeneous plasma, like that created by a laser pulse on solid targets. Specific examples are given of theoretical expressions involving relaxation times and diffusion coefficients, as well as a discussion of different experimental approaches involving space and time-resolved measurements that could be used to complement a positive result of the calculation of the minimum electron number density required for LTE using the McWhirter formula. It is argued that these approaches will allow a more complete assessment of the existence of LTE and therefore permit a better quantitative result. It is suggested that the mere use of the McWhirter criterion to assess the existence of LTE in laser-induced plasmas should be discontinued. 相似文献
57.
M. Campostrini A. Di Giacomo Ŝ. Olejník 《Zeitschrift fur Physik C Particles and Fields》1986,31(4):577-582
We compute the effect of the gluon condensate on the spectra of heavy quarkonia, taking into account the condensate correlation length. We compare the results obtained for the hydrogen-like model with a more realistic model. The effects are shown to be very small both in bottomonium and toponium. 相似文献
58.
59.
A. De Giacomo M. Dell’Aglio O. De Pascale 《Applied Physics A: Materials Science & Processing》2004,79(4-6):1035-1038
In this paper the flexibility of Laser Induced Breakdown Spectroscopy (LIBS) has been proved for the analysis of water solutions. The plasma is generated directly in the bulk of a water solution by a Q-switched Nd:YAG laser (1064). The emission signal of four different solutions has been studied: AlCl3, NaCl, CaCO3 and LiF. The basic mechanisms influencing the emission signal and the experimental tricks for the optimization of the detection mode have been pointed out. PACS 52.70.Kz; 52.80.Wq; 39.30.+p 相似文献
60.
We show that local and semilocal strings in Abelian and non-Abelian gauge theories with critical couplings always reconnect classically in collision, by using moduli space approximation. The moduli matrix formalism explicitly identifies a well-defined set of the vortex moduli parameters. Our analysis of generic geodesic motion in terms of those shows right-angle scattering in head-on collision of two vortices, which is known to give the reconnection of the strings. 相似文献