Pyridine-cored V-shaped π-conjugated oligomers: synthesis and optical properties

A new series of V-shaped pyridine-cored π-conjugated oligomers are synthesized utilizing two-fold Heck/Suzuki coupling reactions. Optical properties of these compounds (λ_max=390–449 nm, Φ_fl=79–5%, in solutions) are discussed. They are shown to be thermally stable and soluble in common organic solvents. Stilbenoid oligomers exhibited much higher fluorescence quantum yields than tri- and tetra-phenylethylene substituted oligomers in solutions.     

Phase retrieval in optical fiber modal interference for structural health monitoring

A method based on data dependent system (DDS) for extraction of phase in fiber modal interference is presented. The interference patterns of LP₀₁ & LP₁₁, LP₀₁ & LP₀₂ and LP₀₆ &LP₀₇ within the fiber have been recorded under different launching conditions. The patterns were characterized by means of autoregressive model and the self coherence functions of the corresponding interferogram were determined. It would provide the phase distribution of the pattern and the modulation of group delay due to the measurand. An application has been made for measuring strain in a simply supported beam under different loading conditions. Results are presented for the applied strain in the range of 270-1500 μ strain.     

Versatile, fragrant, convertible isonitriles

The metalation of oxazoles leads to ring opening to the isocyanoenolate that can be O-acylated to give the unsaturated isonitriles. These substances undergo conventional multicomponent reactions. The products of their reactions are readily converted to acyl substitution products by treatment with acid and a nucleophile. These unsaturated isonitriles are notable by their simple preparations and, unusually, their nonoffensive odors.     

Existence of a size-dependent diffusivity maximum for uncharged solutes in water and its implications

Recent studies suggest that there exists a size-dependent diffusivity maximum in binary mixtures interacting via Lennard-Jones potential when the size of one of the two components is varied (Ghorai, P. K.; Yashonath, S. J. Phys. Chem., 2005, 109, 5824). We discuss in the present paper the importance of the existence of a size-dependent maximum for an uncharged solute in liquid or amorphous solid water and its relation to the ionic conductivity maximum in water. We report molecular dynamics investigations into the size dependence of the self-diffusivity, D, of the uncharged solutes in water at low temperatures (30 K) with immobile as well as mobile water. We find that a maximum in self-diffusivity exists as a function of the size of solute diffusing within water at low temperatures but not at high temperatures. This is due to the relatively weak interactions between the solute and the water compared to the kinetic energy at room temperature. Previously, we have shown that a similar maximum exists for guests sorbed in zeolites and is known as the levitation effect (LE). Thus, it appears that the existence of a size-dependent maximum is universal and extends from zeolites to simple liquids to solvents of polyatomic species. We examine the implications of this for the size-dependent maximum in ionic conductivity in polar solvents known for over a hundred years. These results support the view that the size-dependent maximum seen for ions in water has its origin in the LE (see Ghorai, P. Kr.; Yashonath, S.; Lynden-Bell, R. M. J. Phys. Chem. 2005, 109, 8120).     

Tunable infrared generation in KTA and applications

Noncollinear difference frequency mixing of dye laser and Nd:YAG second harmonic (fundamental) radiation from a commercial laser system is employed for the generation of 2.7–5.3 μm (1.6–1.7 μm) radiations in a flux-grown KTiOAsO₁ crystal. The generated radiation is used to scan the methane absorption in the fundamental (v ₃) and its first overtone (2v ₃) band at pressure 90 torr in a laboratory made single pass gas cell of length 33 cm.     

关于K个复相关矩阵相等的检验

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Study of theS-matrix near bound states in the continuum

The behaviour ofS-matrix for potentials generating bound states in continuum in the neighbourhood of the positive bound state energies is studied. It is shown that unlike the case of usual negative energy bound states, theS-matrix does not have a pole at the positive bound state energy but becomes unity at the energy corresponding to bound states in continuum. Calculations ofS-waveS-matrix for a local potential constructed by Stillinger and Herrick and a separable nonlocal potential constructed by the present authors verify these results. Our results indicate that the bound states embedded in continuum constructedvia the von Neumann and Wigner procedure cannot be interpreted as resonances with zero width.     

Inversion of the direction of stereoinduction in the coupling of chiral gamma,delta-unsaturated Fischer carbene complexes with o-ethynylbenzaldehyde

[reaction: see text] A variety of gamma,delta-unsaturated carbene complexes that feature a stereogenic center at the beta-carbon couple with 2-ethynylbenzaldehyde to afford hydrophenanthrene derivatives with a high degree of stereoinduction. The direction of stereoinduction is opposite for examples where the stereogenic center is acyclic vs examples where it is within a ring.     

Tandem one pot synthesis of 1,5-benzodiazocine-2-one by isocyanide based Ugi multicomponent reaction

We have developed an efficient one-pot, two-step reaction protocol for the synthesis of eight-membered 1,5-benzodiazocine-2-ones by Ugi four-center three-component coupling reaction (U-4C-3CR) and subsequent reductive cyclization using Fe/NH₄Cl in protic solvent.