Synthesis and properties of <Emphasis Type="Italic">N</Emphasis>-[2,2-bis(2,4-dihydroxyaryl)ethyl]-<Emphasis Type="Italic">N</Emphasis>-methylamines and their hydrohalides

Condensation of one molecule of α-methylaminoacetaldehyde dimethyl acetal with two molecules of resorcinol or methylresorcinol in hydrohalogen acid solutions led to substituted N-(2,2-diarylethyl)-N-methylamine hydrohalides. Reactions of the corresponding amines with acetic anhydride, mono-and diisocyanates, and formaldehyde were studied. Conditions for formation of calixarene from resorcinol and α-methylaminoacetaldehyde dimethyl acetal were invented. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 319–324, February, 2007.     

Limit Theorems for Stopped Functionals of Markov Renewal Processes

Some results for stopped random walks are extended to the Markov renewal setup where the random walk is driven by a Harris recurrent Markov chain. Some interesting applications are given; for example, a generalization of the alternating renewal process.     

Hall effect plateaus and giant Shubnikov-de Haas oscillations in (BiSb)Telayered single crystals near the quantum limit

On bulk layered single crystals (Bi_0.25Sb_0.75)₂Te₃ with a hole concentration cm^-3 and a mobility cm²/Vs magnetoresistance and Hall effect investigations were performed in the temperature range T = 1.4 K ... 20 K in magnetic fields up to 18 T. For the magnetic field perpendicular to the layered structure giant Shubnikov-de Haas oscillations are measured; the positions of the maxima are triplets in the reciprocally scaled magnetic field. From the damping of the amplitudes with increasing temperature the cyclotron mass m _c = 0.12m ₀ is evaluated. Correlated with the SdH oscillations doublets of Hall effect plateaus (or kinks in low fields) are found. The weak well known Shubnikov-de Haas oscillations from the generally accepted multivallied highest valence band can be detected as a modulation on the giant oscillation. The high anisotropy of the SdH oscillations and their triplet structure in connection with the layered crystal structure lead us to suggest that the effects are caused by hole carrier pairing (mediated by the bipolaron mechanism) in quasi 2D sheets parallel to the crystal layer stacks. The measured Hall plateau resistances coincide with the quantum Hall effect values considering the number of layer stacks and the valley degeneracy of the 3D hole carrier reservoir. The ratio of spin splitting to Landau (cyclotron) splitting is observed to be . Received: 12 September 1997 / Revised: 8 January 1998 / Accepted: 22 January 1998     

An Elementary Approach to the Twin Primes Problem

Hardy-Littlewood [4] conjectured an asymptotic formula for the number of prime pairs (twin primes) (p, p+2d) with p+2dy, where d N is fixed and y . Up to now, no one has been able to prove this conjecture, but employing Hardy-Littlewoods circle method, Lavrik [5] showed that in a certain sense this formula holds true for almost-all dy/2.In the present paper, we use a completely different method to prove Lavriks almost-all result. Our method is based on an elementary approach developed by Pan Chengdong [7] to the twin primes problem. By a slight modification of our method, we get a corresponding almost-all result for the binary Goldbach problem. From this, according to [3], we derive Vinogradovs [8] well-known Three-Primes-Theorem.     

On Distributional Properties of Perpetuities

We study probability distributions of convergent random series of a special structure, called perpetuities. By giving a new argument, we prove that such distributions are of pure type: degenerate, absolutely continuous, or continuously singular. We further provide necessary and sufficient criteria for the finiteness of p-moments, p>0, as well as exponential moments. In particular, a formula for the abscissa of convergence of the moment generating function is provided. The results are illustrated with a number of examples at the end of the article.      

Exchange Currents,Isobaric Excitations and the Deuteron

Some recent attempts to take into account exchange currents and isobaric excitations in the electromagnetic and weak interactions of leptons with the deuteron are reviewed. After a presentation of the relevant theoretical framework the crucial experiments supporting strongly the exchange current ideas are discussed in some detail.