全文获取类型
收费全文 | 770篇 |
免费 | 31篇 |
国内免费 | 1篇 |
专业分类
化学 | 675篇 |
晶体学 | 5篇 |
力学 | 3篇 |
数学 | 45篇 |
物理学 | 74篇 |
出版年
2021年 | 11篇 |
2020年 | 15篇 |
2019年 | 13篇 |
2017年 | 4篇 |
2016年 | 21篇 |
2015年 | 19篇 |
2014年 | 18篇 |
2013年 | 36篇 |
2012年 | 32篇 |
2011年 | 49篇 |
2010年 | 16篇 |
2009年 | 27篇 |
2008年 | 44篇 |
2007年 | 35篇 |
2006年 | 36篇 |
2005年 | 29篇 |
2004年 | 19篇 |
2003年 | 23篇 |
2002年 | 19篇 |
2001年 | 16篇 |
2000年 | 15篇 |
1999年 | 13篇 |
1998年 | 10篇 |
1997年 | 14篇 |
1996年 | 7篇 |
1995年 | 21篇 |
1994年 | 15篇 |
1993年 | 14篇 |
1992年 | 25篇 |
1991年 | 16篇 |
1990年 | 7篇 |
1989年 | 18篇 |
1988年 | 10篇 |
1987年 | 10篇 |
1986年 | 16篇 |
1985年 | 7篇 |
1984年 | 10篇 |
1983年 | 5篇 |
1982年 | 9篇 |
1981年 | 10篇 |
1980年 | 7篇 |
1979年 | 5篇 |
1978年 | 14篇 |
1977年 | 5篇 |
1976年 | 4篇 |
1975年 | 5篇 |
1974年 | 4篇 |
1973年 | 4篇 |
1972年 | 4篇 |
1971年 | 5篇 |
排序方式: 共有802条查询结果,搜索用时 109 毫秒
21.
Soliton physics has made considerable progress in solving nonlinear problems. This paper is meant to relate the soliten concept to the stationary axisymmetric vacuum fields in general relativity. We present a functional transformation which, working as a nonlinear creation operator, generates gravitational fields of isolated sources. When applied to flat space-time (gravitational vacuum) this operation leads to a nonlinear superposition of an arbitrary number of Kerr particles. This superposition also includes the Tomimatsu-Sato fields. The functional transformations form an infinite-parameter group which contains the Kinnersley-Geroch group as a subgroup.This essay received the second award from the Gravity Research Foundation for the year 1980.-Ed. 相似文献
22.
Hölscher M Leitner W Holthausen MC Frenking G 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(16):4700-4708
Quantum chemical calculations by using density functional theory at the B3LYP level have been carried out to elucidate the reaction course for the addition of ethylene to [OsO2(CH2)2] (1). The calculations predict that the kinetically most favorable reaction proceeds with an activation barrier of 8.1 kcal mol(-1) via [3+2] addition across the O=Os=CH2 moiety. This reaction is -42.4 kcal mol(-1) exothermic. Alternatively, the [3+2] addition to the H2C=Os=CH2 fragment of 1 leads to the most stable addition product 4 (-72.7 kcal mol(-1)), yet this process has a higher activation barrier (13.0 kcal mol(-1)). The [3+2] addition to the O=Os=O fragment yielding 2 is kinetically (27.5 kcal mol(-1)) and thermodynamically (-7.0 kcal mol(-1)) the least favorable [3+2] reaction. The formal [2+2] addition to the Os=O and Os=CH2 double bonds proceeds by initial rearrangement of 1 to the metallaoxirane 1 a. The rearrangement 1-->1 a and the following [2+2] additions have significantly higher activation barriers (>30 kcal mol(-1)) than the [3+2] reactions. Another isomer of 1 is the dioxoosmacyclopropane 1 b, which is 56.2 kcal mol(-1) lower in energy than 1. The activation barrier for the 1-->1 b isomerization is 15.7 kcal mol(-1). The calculations predict that there are no energetically favorable addition reactions of ethylene with 1 b. The isomeric form 1 c containing a peroxo group is too high in energy to be relevant for the reaction course. The accuracy of the B3LYP results is corroborated by high level post-HF CCSD(T) calculations for a subset of species. 相似文献
23.
24.
25.
26.
27.
Back Cover: Constrained Peptides with Target‐Adapted Cross‐Links as Inhibitors of a Pathogenic Protein–Protein Interaction (Angew. Chem. Int. Ed. 9/2014)
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
28.
29.
Dr. Mark Feyand Milan Köppen Prof. Dr. Gernot Friedrichs Prof. Dr. Norbert Stock 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(37):12537-12546
A systematic investigation of the systems Bi3+/carboxylic acid/HNO3 for the tri‐ and tetracarboxylic acids pyromellitic acid (H4Pyr), trimellitic acid (H3Tri) and trimesic acid (H3BTC) acid led to the discovery of five new bismuth carboxylates. Structural characterisation allowed the influence of the linker geometry and the Bi3+:linker molar ratio in the starting solution on the crystal structure to be determined. The crystallisation of three selected compounds was investigated by in situ energy‐dispersive X‐ray diffraction. Three new crystalline intermediates were observed within minutes, and two of them could be isolated by quenching of the reaction mixture. Their crystal structures were determined from laboratory and synchrotron X‐ray powder diffraction data and allowed a possible reaction pathway to be established. In depth characterisation of the luminescence properties of the three bismuth pyromellate compounds was carried out. Fluorescence and phosphorescence could be assigned to (mainly) ligand‐ and metal‐based transitions. The polymorphs of Bi(HPyr) exhibit different luminescence properties, although their structures are very similar. Surprisingly, doping of the three host structures with Eu3+ and Tb3+ ions was only successful for one of the polymorphs. 相似文献
30.
Jacob RE Laicher G Minard KR 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2007,188(2):357-366
In (3)He magnetic resonance images of pulmonary air spaces, the confining architecture of the parenchymal tissue results in a non-Gaussian distribution of signal phase that non-exponentially attenuates image intensity as diffusion weighting is increased. Here, two approaches previously used for the analysis of non-Gaussian effects in the lung are compared and related using diffusion-weighted (3)He MR images of mechanically ventilated rats. One approach is model-based and was presented by Yablonskiy et al., while the other approach utilizes the second order decay contribution that is predicted from the cumulant expansion theorem. Total lung coverage is achieved using a hybrid 3D pulse sequence that combines conventional phase encoding with sparse radial sampling for efficient gas usage. This enables the acquisition of nine 3D images using a total of only approximately 1 L of hyperpolarized (3)He gas. Diffusion weighting ranges from 0 s/cm(2) to 40 s/cm(2). Results show that the non-Gaussian effects of (3)He gas diffusion in healthy rat lungs are directly attributed to the anisotropic geometry of lung microstructure as predicted by the Yablonskiy model, and that quantitative analysis over the entire lung can be reliably repeated in time-course studies of the same animal. 相似文献