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51.
R. I. Vas’kevich P. V. Savitskii Yu. L. Zborovskii V. I. Staninets A. V. Turov A. N. Chernega 《Russian Journal of Organic Chemistry》2006,42(9):1396-1402
Reactions of substituted 1-(thieno[2,3-d]pyrimidin-2-yl)-4-arylthiosemicarbazides with methyl iodide led to the formation of fused triazolothienopyrimidine derivatives. 相似文献
52.
M. V. Otdel’nova J. A. Zakharova E. M. Ivleva V. A. Kasaikin A. B. Zezin V. A. Kabanov 《Polymer Science Series A》2006,48(4):413-421
Supramolecular organization of complexes formed by poly(N-ethyl-4-vinylpyridinium bromide) and sodium dodecylsulfate in aqueous salt solutions was studied as a function of temperature and concentration of the complexes. It was shown that a decrease in temperature and/or concentration of complexes led to their reversible disaggregation into a molecularly dispersed (“unipolymer”) state. The ratio between the components in complex particles remained unchanged in this case. It was first found that phase separation in aqueous solutions of the complexes upon temperature elevation is accompanied by the precipitation of a nonstoichiometric complex. 相似文献
53.
A. P. Yaroshenko M. V. Savos’kin V. I. Shologon R. D. Mysyk A. N. Magazinskii 《Russian Journal of Applied Chemistry》2006,79(1):163-165
The possibility of obtaining residual graphite nitrate by water treatment of graphite nitrate and its subsequent drying was studied. The expansion coefficients were determined in the temperature range 500–900°C with a step of 100°C for the samples obtained. 相似文献
54.
N. A. Davidenko Yu. P. Get’manchuk M. A. Zabolotnyi T. G. Zabolotnaya L. P. Linets E. V. Mokrinskaya V. A. Pavlov S. L. Studzinskii N. G. Chuprina 《High Energy Chemistry》2006,40(6):410-416
The effect of doping with CdS nanoparticles of recording medium films for the thermoplastic holographic recording process, which are based on photosemiconductors (oligomers and cooligomers of glycidylcarbazole) and a dielectric (a styrene copolymer with octyl methacrylate) containing a photoconductivity sensitizer, on their photosensitivity was studied. The enhancement of photosensitivity of films by doping with nanoparticles is associated with the appearance of an additional channel for transport of electrons generated from sensitizer molecules. A difference in informational properties between the oligomer and the polymer films was revealed. 相似文献
55.
A. N. Dmitrievskii A. A. Pribylov N. A. Skibitskaya L. A. Zekel’ A. P. Kubyshkin M. Ya. Shpirt 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2006,80(7):1099-1104
Isotherms of sorption of butane, propane, ethane, methane, and carbon dioxide on an asphaltene sample of known elemental composition were measured. The effect of the pressure and temperature on the shape the sorption isotherms for all the adsorption systems studied was examined. The values of the initial heat of sorption were determined and compared to the energies of interaction of the molecules with asphaltene. The results obtained suggest that asphaltene is a swellable amorphous sorbent. 相似文献
56.
N. S. Shaglaeva O. V. Lebedeva Yu. N. Pozhidaev R. G. Sultangareev S. S. Bochkareva L. A. Es’kova 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2007,81(3):335-338
Hybrid organoinorganic composites insoluble in water and organic solvents were prepared by the hydrolysis of tetraethoxysilane in the presence of poly-1-vinylpyrazole, poly-1-vinylimidazole, and poly-4-vinylpyridine. The composition of the composites was determined by the nature of the polymeric nitrogen base and hydrolysis conditions. The composites synthesized showed high sorption activity in the extraction of the [PdCl4]2?, [PtCl6]2?, and [AuCl4]? ions from hydrochloric acid solutions. 相似文献
57.
A. M. Genaev G. E. Sal’nikov V. G. Shubin 《Russian Journal of Organic Chemistry》2007,43(8):1134-1138
By DFT method energy barriers were calculated for carousel rearrangements of bicyclo[3.1.0]hexenyl, cyclobutenyl, and homotropylium cations. A plausible agreement between calculated and experimental findings was found. 相似文献
58.
59.
I. G. Vasil’eva 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2006,80(11):1842-1847
A new methodology is proposed and the phase equilibrium is investigated in the Ln2S3-LnS2 systems, in which the low-temperature behavior of nonstoichiometric phases is controlled by the kinetics of the ordering of defects. It is shown that, under equilibrium conditions, the phase equilibrium in the systems is represented not only by a polysulfide with a wide homogeneity region, but also by several (or one) phases of constant irrational compositions combined in the homologous series LnnS2n?1 (n = 3, 4, 7, 8, and 10). The formation of sulfur vacancies and isolated [S2]2? ions (which compensate the charge) in the anionic S2? layer is the basic mechanism of changing the composition of the members of the series. On the basis of structural data, the possible mechanisms of the ordering of defective LnS2?x polysulfides are examined and it is shown that the formation of stable or metastable phases is a kinetics-controlled process. The role of p s-T-x diagrams in the interpretations of complex structures of metastable phases from the point of view of attainment of the equilibrium state is discussed. 相似文献
60.
A. N. Vasil’ev A. N. Lyshchikov O. E. Nasakin Ya. S. Kayukov V. A. Tafeenko 《Russian Journal of Organic Chemistry》2005,41(2):279-282
Reduction of alkyl-2-amino-5,6-dialkyl-3-cyanopyridine-4-carboxylates with sodium borohydride in protic solvents gave rise to 4-amino-3-imino-6,7-dialkyl-1,3-dihydrofuro[3,4-c]pyridines that at hydrolysis in acid medium afforded the corresponding lactones.__________Translated from Zhurnal Organicheskoi Khimii, Vol. 41, No. 2, 2005, pp. 288–291.Original Russian Text Copyright © 2005 by Vasil’ev, Lyshchikov, Nasakin, Kayukov, Tafeenko. 相似文献