Use of ultrafine-dispersed nanodiamond for selective deposition of boron-doped diamond films

A suspension of ultrafine-dispersed nanodiamond was used for introducing (in particular, selectively) high-density centers of diamond nucleation on various substrates. High-quality doped diamond films to be used as electrochemistry electrodes were deposited from the gas phase in a microwave discharge on certain substrates treated using ultrafine-dispersed nanodiamond. A uniform distribution of nucleation centers with concentrations greater than 10¹⁰ cm^-2 on silicon substrates was obtained. Electrochemical current-potential curves were measured for continuous films. Diamond meshes of different transparency were grown using selective nucleation. Successful production of high-quality doped diamond meshes gives grounds to consider them the most promising electrodes for use in electrochemistry.     

Chain decay of low-angle tilt boundaries in nanocrystalline materials

In terms of two-dimensional dislocation-disclination dynamics, a theoretical model is developed to describe the decay of a low-angle tilt boundary in a deformed nanocrystalline material under the action of an externally applied elastic stress and of the elastic field of a neighboring decayed boundary. The critical external stresses are calculated at which the boundary decays and the dislocations making up this boundary either are trapped by the boundary that decayed earlier or break away from both boundaries. The decay of a low-angle tilt boundary is shown to result in a substantial decrease in the critical decay stresses for the neighboring boundaries, which can cause an avalanche-like chain decay of low-angle boundaries yielding high-density ensembles of mobile dislocations capable of carrying substantial plastic deformations and of forming shear bands in deformed nanocrystalline materials.     

Investigation of the X-ray radiation produced by a diffusive discharge in the rod-plane geometry under atmospheric pressure

Spatial parameters of the X-ray radiation produced by a high-voltage nanosecond discharge evolving in air under atmospheric pressure in the rod (cathode)-plane electrode system with a 10-cm electrode spacing are studied experimentally. A ∼170-ns voltage pulse with an amplitude of ∼200 kV and 10-ns rise time is applied to the cathode. The photoelectronic method is used to study, under the same conditions, the integrated (over the gap) characteristics of the radiation, in particular, the duration of its generation. It is found that, when the size of the X-ray source is not smaller than that of the discharge region of diffusive luminescence, radiation from the cathode region of the gap is primarily observed (i.e., from the region where the electric field distribution is sharply inhomogeneous). The X-ray generation is usually observed after the bridging of the discharge gap, the X-ray pulse having a rise time of ∼3 ns, a duration of ∼10 ns, and an effective radiation energy of ∼6 keV.     

Perpendicular magnetic anisotropy in single-crystal Co<Subscript>50</Subscript>Pt<Subscript>50</Subscript>/MgO(100) films

The crystal structure and hysteretic magnetic properties of equiatomic single-crystal CoPt films applied on MgO substrates by magnetron sputtering, as well as modification of these properties by thermal annealing, are studied. Heat-treated films of thickness in the range 2<d≤16 nm exhibit perpendicular magnetic anisotropy. A correlation between the crystalline anisotropy constant of the CoPt films and the order parameter of the LI₀ superstructure in these alloys is found. The effect of a single-crystalline MgO substrate on the structure and magnetic properties of equiatomic CoPt films is revealed.     

Numerical simulation of the translational nonequilibrium zone behind a shock-wave front

The translational nonequilibrium zone in a shock wave is considered for a gas consisting of light particles and a small addition of heavy particles. The gas is taken to be two-dimensional, and long-range forces are assumed to be absent. In the framework of this approximation, a program for molecular dynamics simulation of the gas is developed. It is applied to calculate a particle distribution function in the shock wave, to analyze the time evolution of the distribution function, and to study its dependence on the gas composition.     

The total acoustic impedance of a prolate spheroid performing transverse oscillatory movements

Using the theory of spheroidal wave functions, the total acoustic impedance is determined for a prolate spheroid performing transverse translational and rotational oscillatory movements. Expressions for the radiation resistance, the added mass, and the added moment of inertia are derived. It is shown that, in the lowfrequency approximation, this mass and moment of inertia reach limiting values identical to hydrodynamic ones. The components of the total acoustic impedance are calculated for spheroids of different relative thicknesses at an arbitrary frequency.     

Effect of purification on the electron structure and field emission characteristics of a carbonaceous material containing single-wall carbon nanotubes

A carbonaceous material containing single-wall carbon nanotubes (SWNTs) has been synthesized by arc-discharge evaporation of graphite with a catalytic additive of nickel and cobalt powders. The synthesized SWNTs were purified from an amorphous carbon component (soot) and the catalyst particles by boiling in nitric acid. A comparison of the X-ray fluorescence spectra measured before and after this treatment showed that acid etching significantly decreased the content of soot in the material. The material enriched with SWNTs is characterized by a reduced threshold for the appearance of the field emission current, which is explained by a decrease in the screening effect of soot. The current-voltage characteristics of SWNTs exhibit a hysteresis, which is suggested to be due to the adsorption of molecules and radicals on the surface and at the ends of carbon nanotubes.     

Synthesis of ordered Ge-Si heterostructures containing ultrasmall germanium nanoclusters

Different techniques for the fabrication of structures containing ensembles of ultrasmall germanium nanoclusters distributed with a high density over the substrate surface are discussed. How to control the morphology and ordering of these ensembles is also discussed.