Estimates for low-frequency elastic scattering by a rigid body

When a plane elastic wave is scattered by a rigid body the surface integral of the traction, projected along the direction of polarization of the incident wave, provides the leading low-frequency approximation for the scattering amplitudes. Two kinds of lower and upper bounds for the surface traction integral are given. One is based on the geometrical characteristics of the scatterer and is expressed in terms of corresponding values of the best fitting interior and exterior confocal triaxial ellipsoids. The case of best fitting interior and exterior spheres is examined as a special case. These bounds are sharp in the sense that they both become equalities when the scatterer degenerates to an ellipsoid. The other kind of lower and upper bounds involve the capacity of the scatterer. All estimates were obtained by using the generalized Dirichlet and Thomson Principles of Potential Theory in Elastostatics. Furthermore, all constants appearing in the bounds are given in terms of the ratio of the phase velocities for the transverse and the longitudinal wave. An upper bound for scattering by a cube at normal incidence is also included.This work was done while both authors were visiting the Department of Mathematics of The University of Tennessee at Knoxville. The second author wishes to acknowledge partial support from The University of Tennessee Science Alliance.     

Effective Relative Permeabilities and Capillary Pressure for One-Dimensional Heterogeneous Media

The paper presents an analytical construction of effective two-phase parameters for one-dimensional heterogeneous porous media, and studies their properties. We base the computation of effective parameters on analytical solutions for steady-state saturation distributions. Special care has to be taken with respect to saturation and pressure discontinuities at the interface between different rocks. The ensuing effective relative permeabilities and effective capillary pressure will be functions of rate, flow direction, fluid viscosities, and spatial scale of the heterogeneities.The applicability of the effective parameters in dynamic displacement situations is studied by comparing fine-gridded simulations in heterogeneous media with simulations in their homogeneous (effective) counterparts. Performance is quite satisfactory, even with strong fronts present. Also, we report computations studying the applicability of capillary limit parameters outside the strict limit.     

Global attractors for the three-dimensional Navier-Stokes equations

In this paper we show that the weak solutions of the Navier-Stokes equations on any bounded, smooth three-dimensional domain have a global attractor for any positive value of the viscosity. The proof of this result, which bypasses the two issues of the possible nonuniqueness of the weak solutions and the possible lack of global regularity of the strong solutions, is based on a new point of view for the construction of the semiflow generated by these equations. We also show that, under added assumptions, this global attractor consists entirely of strong solutions.     

Experimental Studies of the Flow of Ferrofluid in Porous Media

This paper presents laboratory-scale experimental results of the behavior of ferrofluids in porous media consisting of sands and sediments. Ferrofluids are colloidal suspensions of magnetic particles stabilized in various carrier liquids. In the presence of an external magnetic field, a ferrofluid becomes magnetized as the particles align with the magnetic field. We investigate the potential for controlling fluid emplacement in porous media using magnetic fields. These experiments show that in laboratory-scale porous media experiments (up to 0.25m), with both vertical gravitational forces and lateral magnetic forces acting simultaneously, the magnetic field produces strong attractive forces on the ferrofluid, particularly in the vicinity of the magnet. These holding forces result in a predictable configuration of the fluid in the porous medium which is dependent on the magnetic field and independent of flow pathway or heterogeneity of the porous medium. No significant retention effects due to flow through variably saturated sands are observed. While the proposed field engineering applications of ferrofluids are promising, the observations to date are particularly relevant at the laboratory scale where the decrease in magnetic field strength with distance from a magnet is less of a limitation than in larger scale applications. Ferrofluids may find immediate application in any situation where it is desirable to control the motion or final configuration of fluid in an experimental flow apparatus without direct physical contact.     

Symbolic Image, Hyperbolicity, and Structural Stability

The aim of the paper is substantiation of a constructive method for verification of hyperbolicity and structural stability of discrete dynamical systems. The main tool here is a symbolic image which is a directed graph constructed by a finite covering of the projective bundle. Hyperbolicity is tested by calculation of the Morse spectrum (the limit set of Lyapunov exponents of pseudo trajectories) which can be found for a given accuracy by the symbolic image [24]. If the Morse spectrum does not contain 0, then the chain recurrent set is hyperbolic and the system is Ω-stable. Thus, the symbolic image gives an opportunity to verify these properties. A diffeomorphism f is shown to be structurally stable if and only if the Morse spectrum does not contain 0 and for the complementary differential there is no connection CR ⁺→CR ^? on the protective bundle. These conditions are verified by an algorithm based on the symbolic image of the complementary differential.     

Evolution of fabric tensors in damage mechanics of solids with micro-cracks: Part I – Theory and fundamental concepts

The evolution of fabric tensors based on micro-crack distributions is formulated based on sound thermodynamic principles. In Part I of this work, the exact definition of fabric tensors based on micro-crack distributions is presented. This definition is seen to incorporate both the orientation and length of a micro-crack. In this regard, the micro-crack distribution is assumed to be radially symmetric, i.e. symmetric about a line through the origin.The equations of thermodynamics are employed in order to derive the exact evolution equations of the fabric tensors defined in the first part. In this regard, a thermodynamic force that is associated with the fabric tensor is defined and utilized in the derivation of the evolution equations. The application of the theory to the case of uniaxial tension is derived in Part II (companion paper) of this work.     

Evolution of fabric tensors in damage mechanics of solids with micro-cracks: Part II – Evolution of length and orientation of micro-cracks with an application to uniaxial tension

In Part II of this work, the equations of thermodynamics are employed in order to derive the exact evolution equations of the fabric tensors defined in Part I (companion paper). In this regard, a thermodynamic force that is associated with the fabric tensor is defined and utilized in the derivation of the evolution equations. A special case of uniaxial tension is solved in order to illustrate the theory.We also derive specific uncoupled equations for the evolution of the length and orientation of micro-cracks. In this regard, some interesting results are obtained. It is concluded that the micro-crack length and orientation cannot evolve simultaneously for the same set of micro-cracks. However, two different sets of micro-cracks may be considered in the same RVE where in one set the micro-crack length evolves, while in the second set the micro-crack orientation evolves.     

Theoretical study of the vibrational frequencies of carbon disulfide

A benchmark comparison for different computational methods and basis sets has been presented. In this study, five computational methods (Hartree–Fock (HF), MP2, B3LYP, MPW1MP91, and PBE1PBE) along with 18 basis sets have been applied to optimize the geometry of carbon disulfide (CS₂), and further calculate the vibrational frequencies of the optimized geometries. The differences between the calculated frequencies and corresponding experimental data are used to evaluate the efficiency of each combination of computational method and basis set. The comparison of frequency difference indicates that B3LYP generally gives the best prediction of frequencies for CS₂, whereas the other two density functional theory (DFT) methods, i.e., MPW1PW91 and PBE1PBE, often give parallel results. Although MP2 predicts the frequencies with accuracy almost as good as those from DFT methods, in a particular case, HF calculation outperforms MP2 as well as MPW1PW91 and PBE1PBE for prediction of the frequency of asymmetrical stretching for CS₂. © 2013 Wiley Periodicals, Inc.     

Facile and stereo-controlled synthesis of 2-deoxynojirimycin, Miglustat and Miglitol

A novel and facile synthesis of a series of the biologically significant iminosugar derivatives including 2-deoxynojirimycin, Miglustat and Miglitol is reported. The synthesis features a strategic double inversion mechanism for securing the desired stereochemistry at C5 position of such glucose-type carbohydrate mimetics, representing a practical and remarkable improvement on the previously reported method that suffers from the loss of the stereo-control during the reaction process.     

Synthesis of (±)- and (+)-perovskone

A biomimetic synthesis of the triterpene (±)-perovskone was achieved featuring a remarkable polycyclization process in which three rings, four bonds, and five stereocenters were created in a single operation in 82% yield. This convergent synthesis required 16 steps, starting from vanillin, and proceeded in 9% overall yield. A second route to prepare optically active quinone 2 took 15 steps in 36% overall yield and featured a palladium-catalyzed reductive allylic transposition to establish the C-5 chirality stereospecifically. Quinone (−)-2 was converted to (+)-perovskone (1) via a polycyclization cascade, which created four rings, five bonds, and six stereocenters in a single operation in 50% yield.