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31.
    
PLLA, PCL and PHBV are aliphatic polyesters which have been researched and used in a wide range of medical devices, and all three have advantages and disadvantages for specific applications. Blending of these materials is an attractive way to make a material which overcomes the limitations of the individual polymers. Both PCL and PHBV have been evaluated in polymer blends with PLLA in order to provide enhanced properties for specific applications. This paper explores the use of PCL and PHBV together with PLLA in ternary blends with assessment of the thermal, mechanical and processing properties of the resultant polymer blends, with the aim of producing new biomaterials for orthopaedic applications. DSC characterisation is used to demonstrate that the materials can be effectively blended. Blending PCL and PHBV in concentrations of 5–10% with PLLA produces materials with average modulus improved by up to 25%, average strength improved by up to 50% and average elongation at break improved by 4000%, depending on the concentrations of each polymer used. PHBV impacts most on the modulus and strength of the blends, whilst PCL has a greater impact on creep behaviour and viscosity. Blending PCL and PHBV with PLLA offers an effective approach to the development of new polyester-based biomaterials with combinations of mechanical properties which cannot be provided by any of the materials individually.  相似文献   
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The homolytic decomposition of hydroxylamine-O-sulphonic acid in alcoholic solvents was investigated in the presence or absence of protonated heteroaromatic bases and Fe(II) salt. The addition of the α-hydroxyalkyl radicals to the base and their oxidation by Fe(III) salt to the corresponding alkyl cyanide were competitive processes. A redox chain process involving the amino radical cation, NH3t., is suggested and the factors affecting the yields of the homolytic substitution are discussed.  相似文献   
33.
We discuss the development and characterisation of a new in situ spin exchange optical pumping (SEOP) based 3He neutron spin filter polarisation device. We present results from a recent test of the prototype system developed with the Institut Laue-Langevin. The polariser was installed on the polarised reflectometer CRISP at ISIS in the analyser position. The 3He was pumped continuously in situ on the beamline. The system also integrated a 3He adiabatic fast passage spin flipper that allowed reversal of the 3He and therefore neutron polarisation state, allowing for measurement of all four polarisation cross-sections. The system was run for a number of days reaching a 3He polarisation of 63%.  相似文献   
34.
Agent-based modeling has been well received in the simulation community. Complex systems are simulated by many autonomous agents whose behavior is defined by a conceptual model. However, the model can be improperly implemented or misinterpreted resulting in an implementation that does not reflect the conceptual rules. It is imperative that the implementation’s function be tested against the model’s expected outcome. In this paper, we present certain steady-state techniques that can be used to verify the operation of agent-based simulations. These methods are introduced and then applied to an ecological model which simulates reproductive dynamics of mosquitoes.  相似文献   
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Further examples of O-isopropylidenaldehydosugars in the furanose series Formyl-bearing furanose derivatives 1–3 (α-D -xylo or α-D -erythro configurations) and 5–8 (configurations α-D -ribo, α-D -lyxo, β-L -threo and D -arabino) have been prepared by classical synthetic steps and their properties mainly spectroscopic, reported. The coupling constant between the formyl and the vicinal proton is always small. Like other members of the series, these new aldehydosugars constitute very useful and flexible synthetic intermediates.  相似文献   
37.
Support-graph preconditioners have been shown to be a valuable tool for the iterative solution, via a Preconditioned Conjugate Gradient method, of the KKT systems that must be solved at each iteration of an Interior Point algorithm for the solution of Min Cost Flow problems. These preconditioners extract a proper triangulated subgraph, with “large” weight, of the original graph: in practice, trees and Brother-Connected Trees (BCTs) of depth two have been shown to be the most computationally efficient families of subgraphs. In the literature, approximate versions of the Kruskal algorithm for maximum-weight spanning trees have most often been used for choosing the subgraphs; Prim-based approaches have been used for trees, but no comparison have ever been reported. We propose Prim-based heuristics for BCTs, which require nontrivial modifications w.r.t. the previously proposed Kruskal-based approaches, and present a computational comparison of the different approaches, which shows that Prim-based heuristics are most often preferable to Kruskal-based ones. This paper has been partially supported by the UE Marie Curie Research Training Network no. 504438 ADONET.  相似文献   
38.
A system of fermions on a one-dimensional lattice, subject to a weak periodic potential whose period is incommensurate with the lattice spacing and satisfies a Diophantine condition, is studied. The Schwinger functions are obtained, and their asymptotic decay for large distances is exhibited for values of the Fermi momentum which are multiples of the potential period  相似文献   
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