预电离脉冲群开关技术高功率脉冲CO2激光器

采用独特的电极结构和预电离脉冲群开关放电技术, 实现了5kW 量级平均功率横流CO₂激光器脉冲激光输出. 关键词： 2脉冲激光')" href="#">CO₂脉冲激光 预电离 脉冲群开关     

Some quasi-periodic solutions to the Kadometsev-Petviashvili and modified Kadometsev-Petviashvili equations

The Kadometsev-Petviashvili (KP) and modified KP (mKP) equations are retrieved from the first two soliton equations of coupled Korteweg-de Vries (cKdV) hierarchy. Based on the nonlinearization of Lax pairs, the KP and mKP equations are ultimately reduced to integrable finite-dimensional Hamiltonian systems in view of the r-matrix theory. Finally, the resulting Hamiltonian flows are linearized in Abel-Jacobi coordinates, such that some specially explicit quasi-periodic solutions to the KP and mKP equations are synchronously given in terms of theta functions through the Jacobi inversion.     

A general fuzzy control scheme for nonlinear processes with stability analysis

In this paper we develop a general fuzzy control scheme for nonlinear processes. Assuming little knowledge about the dynamics of the controlled process, the proposed scheme starts by probing the process at different points in its operating region to generate a fuzzy quantisation. A simple local controller is then designed at each fuzzy locality. A fuzzy inference mechanism then links up tje local controllers to form a global controller which can be further refined by the learning algorithm. By employing a newly developed structure-adaptive fuzzy modelling scheme, the appropriate fuzzy rule-base for the inference mechanism can be extracted stably and efficiently. The conditions for the stability of the global controller are rigourously established. Simulation results are presented to illustrate the effectiveness of the scheme.     

Highly selective thiocyanate electrode based on bis-[N-(2-hydroxyethyl)salicylaldimino]copper(II) complex as a neutral carrier.

A novel selective thiocyanate electrode of a PVC membrane based on bis-[N-(2-hydroxyethyl)salicylaldimino]copper(II) [Cu(II)-BNSDM] as a neutral carrier is reported. The selectivity sequence of this electrode is as follows: SCN- > ClO4- > I- > Sal- > Br- > NO2- > Cl- > NO3- > H2PO4- > SO4(2-), which is an anti-Hofmeister selectivity sequence. The electrode exhibits a Nernstian potential linear range to thiocyanate from 1.0 x 10(-1) to 6.0 x 10(-6) mol/L with a detection limit of 2.0 x 10(-6) mol/L and a slope of (-59.0+/-0.2)mV/decade in pH 5.0 of a phosphate buffer solution at 25 degrees C. Electrochemical impedance spectroscopy (EIS) and UV spectroscopy techniques were performed to understand the response mechanism of the electrode. The electrode had the advantage of simplicity, high selectivity, fast response and low detection limit compared with the other electrode, which had been reported before. The electrode had been applied to wastewater analysis, and the obtained results were satisfactory.     

新显色剂1-羟基-2-(5-NO2-2-吡啶偶氮)-8-氨基-3,6-萘二磺酸与钯的显色反应

探讨了新显色剂1-羟基-2-(5-NO2-2-吡啶偶氮 )-8-氨基-3,6-萘二磺酸(简称5-NO2-PAH)与钯离子显色的适宜条件及其共存离子的影响,建立了5-NO2-PAH测定钯的新显色反应体系.结果表明,在pH 2.0～5.5范围内,钯与试剂形成稳定的1∶1配合物,其最大吸收峰位于712 nm, 表观摩尔吸光系数ε Pd=2.84×104 L*mol-1*cm-1,钯的浓度在0～20 μg/10 mL 范围内遵守比尔定律.方法已用于实际样品中钯的测定.     

液相色谱中的一个新的表征参数Z Ⅲ.反相高效液相色谱中的生物大分子分离体系

研究了在反相高效液相色谱中的烷基醇-甲酸-水、烷基醇-三氟醋酸-水和烷基醇-磷酸盐-水三种流动相,9种生物大分子的分离体系中Z的表征。发现当蛋白质完全变性时,Z值与其分子量呈正比,而与置换剂分子大小呈反比。Z值会因流动相中离子对试剂的存在而减小,且浓度愈大,减小程度愈甚。对于在异丙醇-水溶液中的不同种类离子对试剂而言,对蛋白构象变性影响的减小顺序为44％(V/V)甲酸>0.05mol/L磷酸盐缓冲液(pH<2.5)>0.1％(V/V)三氟醋酸。     

分光光度法测定发样中的微量铁

在表面活性剂OP存在下，利用硫氰酸钾和罗丹明B与铁的显色反应，建立了测定发样中微量铁离子含量的分光光度法。在OP溶液浓度为1.0g／L、酸度为4mmol／L的硫酸介质中，于580nm波长处，铁含量在0-0．8μg／mL范围内符合比尔定律，线性回归方程为A=1．403c 0．0114，相关系数r=0．9992，回收率为93．6％-107．1％，该法的分析结果与原子吸收分光光度法基本一致。     

高效液相色谱法测定血清中的鸟氨酸脱羧酶活性

建立了血清中鸟氨酸脱羧酶活性的高效液相色谱测定法。结果表明，腐胺在２．８～４５．５μｍｏｌ／Ｌ范围内线性关系良好。最低检测量为０．０５ｎｍｏｌ，回收率为８５．０６％，ＲＳＤ为８．９１％。本法测定正常人及乳腺癌、宫颈癌患者血清中的鸟氨酸脱羧、酶活性发现，乳腺癌及宫颈癌血清中的酶活性升高（ｐ＜０．０５），说明测定血清的鸟氨酸脱羧酶活性，对诊断肿瘤有一定的临床意义。     

用纤维素黄原酸酯去除硫酸锌浸出液中的重金属杂质

铜;镉;钴;镍;用纤维素黄原酸酯去除硫酸锌浸出液中的重金属杂质