Toroidal hopping of a single hole through the circularly-arrayed naphthyl groups in hexanaphthylbenzene cation radical

Synthesis of a dendritic (soluble) hexanaphthylbenzene derivative is described in which the six naphthyl groups are connected to the central benzene ring in a propeller-shaped arrangement. Observation of multiple oxidation waves in its cyclic voltammogram as well as an intense charge-resonance transition (extending beyond 1600 nm) in its cation radical, generated by laser-flash photolysis using photoexcited chloranil as an oxidant, suggests that a single hole is mobilized via electron transfer (or hopping) over six identical (circularly arrayed) redox centers.     

Multiobjective analog/RF circuit sizing using an improved brain storm optimization algorithm

This paper presents a multiobjective analog/RF circuit sizing tool using an improved brain storm optimization (IMBSO) algorithm with the purpose of analyzing the tradeoffs between competing performance specifications of analog/RF circuit block. A number of improvements are incorporated into IMBSO algorithm at different steps. At first, the clustering step of IMBSO algorithm is augmented with k-means\(++\) seeding technique to select the initial cluster centroids while clustering using k-means clustering technique. As a second improvement, the proposed IMBSO algorithm makes use of random probabilistic decision-making of river formation dynamics scheme to select optimal cluster centroids during population generation step. As a third improvement, an adaptive mutation operator is incorporated inside the IMBSO algorithm to generate new population. Finally, two separate constraint handling techniques are employed to handle both boundary and functional constraints during analog/RF circuit optimization. The performance of the proposed IMBSO algorithm is demonstrated in finding optimal Pareto fronts among different performance specifications of a two-stage operational amplifier circuit, a folded cascode amplifier circuit and a low noise amplifier circuit.     

Formation and dynamics of dark solitons and vortices in quantum electron plasmas

We present simulation studies of the formation and dynamics of dark solitons and vortices in quantum electron plasmas. The electron dynamics in the latter is governed by a pair of equations comprising the nonlinear Schr?dinger and Poisson system of equations, which conserves the number of electrons as well as their momentum and energy. The present governing equations in one spatial dimension admit stationary solutions in the form a dark envelope soliton. The dynamics of the latter reveals its robustness. Furthermore, we numerically demonstrate the existence of cylindrically symmetric two-dimensional quantum electron vortices, which survive during collisions. The nonlinear structures presented here may serve the purpose of transporting information at quantum scales in ultracold micromechanical systems and dense plasmas, such as those created during intense laser-matter interactions.     

Improved Protocols of Secure Quantum Communication Using W States

Recently, Hwang et al. (Eur. Phys. J. D 61:785, 2011) and Yuan et al. (Int. J. Theor. Phys. 50:2403, 2011) have proposed two efficient protocols of secure quantum communication using 3-qubit and 4-qubit symmetric W state respectively. These two dense coding based protocols are generalized and their efficiencies are considerably improved. Simple bounds on the qubit efficiency of deterministic secure quantum communication (DSQC) and quantum secure direct communication (QSDC) protocols are obtained and it is shown that dense coding is not essential for designing of maximally efficient DSQC and QSDC protocols. This fact is used to design maximally efficient protocols of DSQC and QSDC using 3-qubit and 4-qubit W states.     

Bidirectional Controlled Teleportation by Using 5-Qubit States: A Generalized View

Recently bidirectional controlled perfect teleportation using 5-qubit states are reported in Int. J. Theor. Phys. (2013), doi:10.1007/s10773-013-1484-8 and ibid (2012), doi:10.1007/s10773-012-1208-5. In this paper we have shown that there exists a class of 5-qubit quantum states that can be used for bidirectional controlled teleportation. Two out of the three reported cases are the special cases of the proposed class of 5-qubit quantum states and one of them is not strictly a case of controlled bidirectional quantum teleportation. Further, we have shown that one can in principle, construct infinitely many 5-qubit quantum states for this purpose. We have also shown that the idea can be extended to bidirectional controlled probabilistic teleportation. Some potential applications of the proposed scheme and its modified versions are also discussed in relation with the implementation of quantum remote control and quantum cryptography.     

Mechanoluminescence and thermoluminescence of BaFCl:Sm 2+ and BaFBr:Sm 2+ crystals

The alkaline-earth fluorohalide crystals MFX, where M=Ca, Sr, Ba, Pb and X=Cl, Br, I, form an important class of materials crystallizing in the PbFCl-type tetragonal structure which is also called the matlockite structure. These compounds have long been of interest because of the various defect species which can be detected by spin resonance and associated techniques. The crystals were prepared by slow cooling of the melt of a stoichiometric mixture of BaF ₂ and the corresponding chloride or bromide under 0.2 bar of ultrapure argon (5N5), often slightly fluorinated. We have studied the mechanoluminescence (ML) of BaFBr:Sm ²⁺ and BaFCl:Sm ²⁺ crystals. It is seen that after the impact of a moving piston, initially the ML intensity increases with time, attains a maximum value and then it decreases with time up to a particular minimum value, and then it increases again, attaining a peak value and finally disappears. The first peak lies in the deformation region and the second peak lies in the post-deformation region. The ML intensity of the BaFCl:Sm ²⁺ crystal is much higher than the ML intensity of the BaFBr:Sm ²⁺ crystal. For different impact velocities, the ML intensity increases with velocity; and the total ML intensity attains a saturation value for higher impact velocities. The total ML intensity increases with the increase in the applied load. It is suggested that the moving dislocation produced during deformation of crystals captures holes from hole-trapped centers (like H centers), and the subsequent radiative recombination of the dislocation holes with electron gives rise to ML. Thermoluminescence (TL) of BaFBr:Sm ²⁺ and BaFCl:Sm ²⁺ crystals was studied after exposure to ultraviolet rays with the help of a TLD reader. The peak of TL for the BaFBr:Sm ²⁺ crystal is found at ～247°C and for BaFCl:Sm ²⁺ crystals at 283°C. The TL intensity initially increases with increase in the UV radiation and then it attains saturation for higher values of UV exposure. The absorption spectrum was recorded with the help of a UV–visible spectrophotometer (Shimadzu). The band found at 275 nm was attributed to H centers.     

Viscosity Approximation Methods for Generalized Multi-Valued Nonexpansive Mappings with Applications

Abstract

In this article, we study viscosity approximation methods for generalized multi-valued nonexpansive mappings and we present some new results related to strong convergence, variational inequality, convex optimization, split and common split feasibility problems (SFPs). Some numerical computations are also presented to illustrate our results.     

An eco-friendly,sustainable, and greener approach to the synthesis of Dihydroquinazolin-4(1H)-ones using a deep eutectic solvent

A safer, greener, and more effective reaction methodology for the synthesis of dihydroquinazolinones (DHQs) has been developed. The deep eutectic solvent (DES) ZnCl₂/urea employed in this study efficiently accelerated the cyclization of 2-aminobenzamide with different aldehydes (aromatic and heteroaromatic) to afford the target scaffolds without the generation of any oxidized product. This method has exhibited remarkable advantages such as quick reaction time, mild reaction conditions, high yield (82%–98%), operational simplicity, and selectivity. The approach was observed to be tolerant to electron-donating and electron-withdrawing functional groups. Green metric parameters (AEf, OE, AE, RME, CE, etc.) determined further aided this greener chemical approach.     

Detailed electrical measurements on sago starch biopolymer solid electrolyte

The biopolymer solid electrolyte has been synthesized and characterized. Potassium iodide (KI) has been added in polymer matrix to develop solid polymer electrolyte. Relationships between electrical, ionic transport parameter and mechanism have been studied in detail. Impedance spectroscopy reveals the detailed electrical studies and ion transport mechanism. The ion dissociation factor is compared with a measured dielectric constant at a fixed frequency. The dielectric data are calculated which support the ionic conductivity data.