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41.
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G. Lakshminarayana C.G. Mahajan 《Journal of Quantitative Spectroscopy & Radiative Transfer》1976,16(7):549-552
The afterglow emission spectrum of sulphur and argon mixture is found to consist of (a) the main band system of S2(B3Σ-u?X3Σ-g) in the region 3200–6600 Å and (b) the atomic spectrum of argon in the 7500–9000 Å region. Although B?X bands of S2 obtained by ordinary excitation extends from 2829 to 7100 Å, the lower wavelength limit of these bands from the afterglow is only 3200Å. It is proposed that the S2 molecules are formed in the B3Σ-u state through inverse predissociation when two S atoms approach each other along the potential curve of the predissociating electronic state 1u. 相似文献
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We generalize the hybrid magnetofluid model of a charged fluid interacting with an electromagnetic field to the dynamics of a relativistic hot fluid interacting with a non-Abelian field. The fluid itself is endowed with a non-Abelian charge and the consequences of this generalization are worked out. Applications of this formalism to the quark gluon plasma are suggested. 相似文献
47.
Nanocrystalline ZnO thin films were deposited at different temperatures (Ts = 325 °C–500 °C) by intermittent spray pyrolysis technique. The thickness (300 ± 10 nm) independent effect of Ts on physical properties was explored. X-Ray diffraction analysis revealed the growth of wurtzite type polycrystalline ZnO films with dominant c-axis orientation along [002] direction. The crystallite size increased (31 nm–60 nm) and optical band-gap energy decreased (3.272 eV–3.242 eV) due to rise in Ts. Scanning electron microscopic analysis of films deposited at 450 °C confirmed uniform growth of vertically aligned ZnO nanorods. The films deposited at higher Ts demonstrated increased hydrophobic behavior. These films exhibited high transmittance (>91%), low dark resistivity (~10?2 Ω-cm), superior figure of merit (~10?3 Ω?1) and low sheet resistance (~102 Ω/□). The charge carrier concentration (η -/cm3) and mobility (μ – cm2V?1s?1) are primarily governed by crystallinity, grain boundary passivation and oxygen desorption effects. 相似文献
48.
As a polycation with diverse applications in biomedical and environmental engineering, polyethylenimine (PEI) can be synthesized with varying degrees of branching, polymerization, and can exist in different protonation states. There have been some interests in molecular modeling of PEI at all-atom or coarse-grained (CG) levels, but present CG models are limited to linear PEIs. Here we present the methodology to systematically categorize bond lengths, bond angles and dihedral angles, which allows us to model branched PEIs. The CG model was developed under the Martini scheme based on eight ~600 Da PEIs, with four different degree of branching at two different protonation states. Comparison of the CG model with all-atom simulations shows good agreement for both local (distributions for bonded interactions) and global (end-to-end distance, radius of gyration) properties, with and without salt. Compatibility of the PEI model with other CG bio-molecules developed under the Martini scheme will allow for large-scale simulations of many PEI-enabled processes. © 2018 Wiley Periodicals, Inc. 相似文献
49.
B. A. Philips A. G. Norman T. Y. Seong S. Mahajan G. R. Booker M. Skowronski J. P. Harbison V. G. Keramidas 《Journal of Crystal Growth》1994,140(3-4):249-263
A model is proposed to rationalize the occurence of CuPt-type ordering in mixed III–V epitaxial layers grown on (001) substrates. It is invoked that 2× surface reconstruction occuring on group V terminated (001) surfaces produces dilated and compressed regions in sub-surface layers. The presence of these regions biases the occupation of certain sites during the growth of a layer consisting of atoms differing in their tetrahedral radii. By assuming that the reconstruction always occurs at the growing surface, it is possible to explain the evolution of CuPt-type ordering in epitaxial layers. Also, based on the model, experimental observations pertaining to the influence of growth conditions, surface misorientation and steps on ordering can be rationalized. 相似文献
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For a subsetS, let the descent statistic (S) be the number of permutations that have descent setS. We study inequalities between the descent statistics of subsets. Each subset (and its complement) is encoded by a list containing the lengths of the runs. We define two preorders that compare different lists based on the descent statistic. Using these preorders, we obtain a complete order on lists of the form (k
i
,P,k
n–i
, whereP is a palindrome, whose first entry is larger thank. We prove a conjecture due to Gessel, which determines the list that maximizes the descent statistic, among lists of a given size and given length. We also have a generalization of the boustrophedon transform of Millar, Sloane and Young. 相似文献