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31.
The interfacial and bulk properties of mixtures of the anionic surfactant (dioctyl sulphosuccinate sodium salt, AOT) with zwitterionic surfactants 3-(N,N-dimethyldodecylammonio) propane sulfonate (DPS), 3-(N,N-dimethyltetradecylammonio) propane sulfonate (TPS), 3-(N,N-dimethylhexadecylammonio) propane sulfonate (HPS) have been studied employing surface tension, fluorescence, and viscometric techniques in aqueous media at 25 °C. It is observed that these mixtures exhibit synergism and these synergistic interactions increase with the enhancement of the hydrocarbon chain of the zwitterionic surfactant. The various physicochemical properties such as critical micelle concentration (cmc), surface excess concentration (Г(max)), minimum area per molecule (A(min)), aggregation number (N(agg)), interaction parameters (β(σ), β(m)), and thermodynamic parameters such as standard Gibbs free energy of adsorption (ΔG(ads)(o)), excess free energy of micellization (ΔG(ex)), and standard Gibbs free energy of micellization (ΔG(m)(o)) have been evaluated. The negative values of ΔG(m)(o) and ΔG(ads)(o) show that the micelle formation and adsorption of surfactant at the air/solution interface is energetically favorable, while a negative value of ΔG(ex) ensures stability of the mixed micelles formed. The Regular Solution Approximation, Motomura and Rosen's approaches have been used to explain and compare the results. The packing parameter (p) ensures the formation of vesicles or bilayers for AOT+DPS/TPS mixtures, which can potentially be used as delivery agents for industrial applications. 相似文献
32.
A systematic investigation of layered perovskite oxides with general formula Ln0.5Sr1.5Mn0.5Fe0.5O4 (Ln?=?La, Nd, Gd, and Dy) has been undertaken mainly to understand their structural, magnetic, as well as electrical behavior. The materials were prepared by the ceramic method. X-ray data have been analyzed by using program Checkcell and the variations of various parameters are explained. It has been concluded that not only A-site cation radius, <r A>, but also the size variance factor (σ 2) influence electrical and magnetic properties. A systematic study of electrical resistivity of all the four materials was undertaken as a function of temperature to understand the conduction mechanism. On analyzing the electrical resistivity data, it has been concluded that variable range hopping model is found to fit well. The magnetic studies suggest that the phases are antiferromagnetic and this behavior could arise from Mn4+–O–Mn4+, and Fe3+–O–Fe3+ superexchange interaction. 相似文献
33.
The dissociation energy of twelve diatomic molecules has been determined by fitting four-parameter potential functionU(r)=D
e[[1−exp{−b(r−r
e)}]/ [1−Cexp{−b(r−r
e)}]]2 to the true Rydberg-Klein-Rees (RKR) curves for their fifteen electronic states using the mean square deviation as the criterion
for the selection of the best fit. Average deviation ofD
e has been found to be 2.7% as compared to 20.5% obtained with Lippincott’s potential function for these molecules. In addition
the anharmonocity constantω
exe has also been calculated for the same electronic states yielding average mean deviation 8.9%. 相似文献
34.
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36.
JPC – Journal of Planar Chromatography – Modern TLC - A sensitive and accurate high-performance thin-layer chromatographic method has been developed, validated, and used for... 相似文献
37.
Effects of a finite ion temperature on the Hall magnetohydrodynamics (MHD), which breaks down for a finite ion temperature, are clarified in terms of a rigorous three-field kinetic dispersion relation. The MHD mode equation becomes anisotropic with respect to the ion pressure because of the double adiabaticity in ion dynamics. 相似文献
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Sandeep Mishra Sarvpreet Kaur S. K. Tripathi C. G. Mahajan G. S. S. Saini 《Journal of Chemical Sciences》2006,118(4):361-369
We present here infrared absorption spectra of dithia tetraphenylporphine and its cation in the 450–1600 and 2900–3400 cm−1 regions. Most of the allowed IR bands are observed in pairs due to overallD
2h
point group symmetry of the molecule. The observed bands have been assigned to the porphyrin skeleton and phenyl ring modes.
Some weak bands, which are forbidden underD
2h
, also appear in the spectra due to the distortion of the molecule from planarity-caused by the out-of-plane positioned N
and S atoms. Increased intensity of some phenyl ring bands compared to free-base tetraphenylporphine is explained on the basis
of rotation of phenyl rings towards the mean molecular plane. Contrary to the point group symmetry of cation of dithia tetraphenylporphine,
certain bands are observed to be degenerate due to identical bonding arrangements in pyrrole rings of the cation 相似文献