相对论平均场理论对Pb同位素位移的研究

运用变形的相对论平均场理论研究了Pb同位素链的基态性质. 对关联的处理采用了BCS方法, 不成对核子的处理运用了“阻塞”法. 计算的结果很好地符合了实验上Pb的平均结合能, 中子分离能, 同位素位移. 接着从原子核的微观结构出发, 比较详细地研究了Pb链同位素位移出现反常扭折这一重要性质的物理机制.     

Non-Gibbsian stochastic light-mode dynamics of passive mode locking

We study a stochastic light-mode system with non-Gibbsian steady state statistics, unravelling global nonequilibrium phase transition properties. It relates to the onset of passive mode-locking in the general case of lasers with arbitrary dispersion and Kerr nonlinearity that includes the nonsolitonic regime. The solution is facilitated by a special stationarity criterion imposed by the system gain balance. We show that the mode-locking phase transition is generic, and give exact expressions for the pulse power and its stability map. We find that at the boundary of the mode-locking stability the pulse power is exactly one half of the total intracavity power, and that the parameter region for the most resistant pulses against noise destabilization is not at the soliton condition.     

Direct contact heat transfer from an immiscible liquid jet

Temperature distribution and transfer of heat in a vertical, immiscible, liquid jet in direct contact with a liquid matrix are analyzed. A theoretical model for plug and parabolic flow is adopted from the literature, the treatment of a special V-shaped velocity distribution expected in the experiment and suitable for reactor application is calculated. Two common surface conditions, i.e. constant heat flux or constant temperature are considered. An experiment was performed in which a high Prandtl number fluid (oil) formed the jet and a low Prandtl number fluid (water) formed the matrix. The experimental results fall within theoretical results obtained for a V-type velocity distribution and plug flow. It was determined that the heat transfer characteristics of a direct contact jet flow in most cases have definite advantages over those of flow in a pipe beyond the obvious advantage of removal of the pipe wall's thermal resistance. These advantages result from the more flat velocity distribution encountered in jet flow as compared to a corresponding Laminar pipe flow. The likeliness of having a particular flow shape is discussed. Advantages of a central wire, leading to the V-type flow, are the enhancement of heat transfer and the stabilisation of the jet for any desired length. The jet flow is laminar.     

Alkyne creation in aliphatic polymers: influence of side groups

In this article, we focus on the influence of side groups on terminal alkyne creation, in aliphatic polymers submitted to swift heavy ions, under vacuum. Terminal alkyne creation was compared in polyethylene and in substituted polymers. We selected two classes of side groups: alkyl groups, which differed in their length (polypropylene and polybutene) and allyl groups, which were linear (EPDMh) or cyclic (EPDMn). Irradiated samples were analyzed using Fourier transform IR spectroscopy, in the transmission mode, at room temperature. Alkynes are created when the electronic stopping power, (dE/dx)e, exceeds a threshold value. This threshold value was moderately influenced by the presence of an alkyl side chain but was clearly reduced in the presence of C=C bonds on the side chain. Nevertheless, in all-saturated polymers, below the (dE/dx)e threshold, terminal alkyne formation is observed after a latent dose, rather independently of the side-chain length and directly related to the formation of radiation-induced double bonds prior to alkyne formation. Under S ion irradiation, the radiation chemical yield G0 value obtained in EPDMh was 4 times the value of G0 in PE. This effect is understandable only if important energy transfers, from the backbone to C=C double bonds, are considered.     

Reversed phase UHPLC/ESI-MS determination of oxylipins in human plasma: a case study of female breast cancer

The ultrahigh-performance liquid chromatography-mass spectrometry (UHPLC/MS) method was optimized and validated for the determination of oxylipins in human plasma using the targeted approach with selected reaction monitoring (SRM) in the negative-ion electrospray ionization (ESI) mode. Reversed phase UHPLC separation on an octadecylsilica column enabled the analysis of 63 oxylipins including numerous isomeric species within 12-min run time. The method was validated (calibration curve, linearity, limit of detection, limit of quantification, carry-over, precision, accuracy, recovery rate, and matrix effect) and applied to 40 human female plasma samples from breast cancer patients and age-matched healthy volunteers (control). Thirty-six oxylipins were detected in human plasma with concentrations above the limit of detection, and 21 of them were quantified with concentrations above the limit of quantitation. The concentrations determined in healthy controls are in a good agreement with previously reported data on human plasma. Quantitative data were statistically evaluated by multivariate data analysis (MDA) methods including principal component analysis (PCA) and orthogonal partial least square discriminant analysis (OPLS-DA). S-plot and box plots showed that 13-HODE, 9-HODE, 13-HOTrE, 9-HOTrE, and 12-HHTrE were the most upregulated oxylipin species in plasma of breast cancer patients.

     

The isotopic composition of evaporating waters - review of the historical evolution leading up to the Craig-Gordon model

Attempts to explain the variations in the abundance of heavy isotopic species of water throughout the hydrologic cycle solely by means of the classical equilibrium-fractionation processes could not be reconciled with measured abundances of the isotopic species in residues of "evaporation systems". Focusing on the evaporation of surface waters, the paper follows the evolution of the concepts during the 1950-ties and early 1960-ties leading up to the formulation of the Craig-Gordan Evaporation Model in 1965.     

Formation and annihilation of laser light pulse quanta in a thermodynamic-like pathway

We present a theoretical and experimental study of multiple pulse formation in passively mode-locked lasers. Following a statistical-mechanics approach, the study yields a thermodynamic-like "phase diagram" with boundaries representing cascaded first order phase transitions. They correspond to abrupt creation or annihilation of pulses and a quantized rf power behavior, as system parameters (noise and/or pumping levels) are varied, in excellent accordance with the experiments. Remarkably, individual pulses carry an almost constant quantum of energy.