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Nathan L. Bauld Dennis J. Bellville Steven A. Gardner Yoelit Migron Garrett Cogswell 《Tetrahedron letters》1982,23(8):825-828
Cation radical polymers which have cation radical functions at up to 5% of the poly(styrene) monomer sites have been prepared, and their effectiveness in catalyzing the cation radical Diels-Alder reaction is demonstrated. 相似文献
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Lin C Chen C Sharkawy A Schneider GJ Venkataraman S Prather DW 《Optics letters》2005,30(11):1330-1332
We present a promising coupling device, namely, a terahertz (THz) planar photonic crystal (PhC) lens based on the effective refractive-index contrast between the PhC and the surrounding unpatterned area. Three-dimensional finite-difference time-domain calculations show a 90% power transfer from a 100-microm silicon waveguide to a 10-microm waveguide, and 45% coupling efficiency is confirmed experimentally. These results demonstrate the utility of the PhC lens as an effective approach to coupling into PhC THz circuits. 相似文献
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G. M. Luke L. P. Le B. J. Sternlieb Y. J. Uemura J. H. Brewer R. Kadono R. F. Kiefl S. R. Kreitzman T. M. Riseman C. L. Seaman Y. Dalichaouch M. B. Maple J. D. Garrett 《Hyperfine Interactions》1991,64(1-4):517-522
We have performed both zero field and high transverse field measurements at dilution refrigerator temperatures on a number of heavy electron systems, examining the superconducting and magnetic properties of these interesting materials. Among the materials studied to date are UBe13, URu2Si2 and U6Fe. The magnetic field penetration depth in the superconducting state of UBe13 is greater than 10000 Å, as no increase in the transverse field relaxation rate is observed belowT c . A sharp increase in the precession frequency is seen, starting atT c . This frequency shift shows little temperature dependence at low temperature; we found no clear evidence for unconventional superconductivity in this material. Zero field measurements in URu2Si2 show the weak antiferromagnetic transition at 17.5 K. Finally, we we found no clear evidence for unconventional superconductivity in this material. Zero field measurements in URu2Si2 show the weak antiferromagnetic transition at 17.5 K. Finally, we have observed relaxation in high transverse field due to the formation of a flux lattice in U6Fe, a material where the electron effective mass is rather lighter than in other heavy fermion systems. The relaxation exhibits a sharp onset atT c=3.9 K, and is flat at low temperatures as expected for a conventional superconductor. 相似文献
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Anthony JM Garrett 《Contemporary Physics》2013,54(2):163-165
The dynamic electronic structure of atoms and molecules can be directly observed by means of the (e, 2e) reaction, which measures the distribution of energies and momenta of two electrons in coincidence after a knockout reaction initiated by an electron beam of known momentum incident on a molecular gas target. The molecular state for each event is identified by the electron separation energy. The recoil momentum for each event is known from the difference of measured initial and final momenta. It has been verified that values of this momentum are equal under suitable conditions to the momentum of the electron in the target immediately before knockout. Thus the spherically-averaged electron momentum distribution for each molecular orbital is measured. This is directly related to molecular orbitals calculated by the methods of quantum chemistry. Properties obtained by this method for different types of molecules are discussed. 相似文献
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Abstract A hydrophone consisting of a hollow cylinder whose flexible, circular end plates are bonded to pairs of pat, spiral wound coils of optical fiber is described. When the end plate/disk is deformed due to a pressure difference, the outer and inner fiber coils experience opposite strains resulting in a “push—pull” optical path length difference which is detected in an all-fiber Michelson interferometer. The close proximity of the interferometric fiber coils, separated by the thin thermally conducting end plate, rejects thermal gradient-induced signals. The addition of a second identical end plate and fiber coil pair at the opposite end of the cylinder will double the acoustic sensitivity while canceling acceleration induced signals. The calculated and measured optical strain of a single simply supported plate, single-coil sensor (8.0 cm diameter, 3.0 mm thickness) using static pressure, acoustic pressure, and acceleration are in good agreement and yield a sensitivity of 0.21 rad/Pa (ΔΦ/ΦΔP = -301 dB re I μPa-1) below its resonance frequency of 3 kHz. The calculated and measured strain for a dual clamped disk (4.5 cm diameter, 1.0 mm thickness) acceleration-canceling sensor with four 8-m coils are in good agreement also and yield a sensitivity of 1.0 rad/Pa (ΔΦ/ΦpΔP = -291 dB re 1 μPa?1) below the disk resonance frequency of 4.5 kHz. These are the highest fiber-optic, omnidirectional hydrophone sensitivities reported to date. 相似文献
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The angular dependence of the EPR linewidth in the paramagnetic region for CsMnCl3 is accurately represented by A(1+cos2θ) + B in accord with conventional exchange narrowing theory but the spin fluctuations in this material are not in the short correlation time limit. 相似文献
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