全文获取类型
收费全文 | 231篇 |
免费 | 3篇 |
专业分类
化学 | 135篇 |
晶体学 | 1篇 |
力学 | 14篇 |
数学 | 16篇 |
物理学 | 68篇 |
出版年
2021年 | 2篇 |
2020年 | 3篇 |
2019年 | 2篇 |
2018年 | 4篇 |
2017年 | 4篇 |
2016年 | 5篇 |
2015年 | 6篇 |
2014年 | 7篇 |
2013年 | 11篇 |
2012年 | 20篇 |
2011年 | 8篇 |
2010年 | 6篇 |
2009年 | 6篇 |
2008年 | 9篇 |
2007年 | 8篇 |
2006年 | 13篇 |
2005年 | 4篇 |
2004年 | 11篇 |
2003年 | 8篇 |
2002年 | 5篇 |
2001年 | 6篇 |
2000年 | 7篇 |
1999年 | 3篇 |
1998年 | 2篇 |
1995年 | 5篇 |
1994年 | 6篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1989年 | 4篇 |
1987年 | 3篇 |
1985年 | 2篇 |
1984年 | 7篇 |
1979年 | 3篇 |
1978年 | 7篇 |
1975年 | 3篇 |
1974年 | 4篇 |
1973年 | 2篇 |
1937年 | 2篇 |
1936年 | 2篇 |
1923年 | 1篇 |
1919年 | 1篇 |
1912年 | 1篇 |
1910年 | 2篇 |
1901年 | 2篇 |
1900年 | 1篇 |
1895年 | 2篇 |
1894年 | 1篇 |
1891年 | 1篇 |
1888年 | 1篇 |
1886年 | 1篇 |
排序方式: 共有234条查询结果,搜索用时 17 毫秒
11.
Gamblin DP Garnier P Ward SJ Oldham NJ Fairbanks AJ Davis BG 《Organic & biomolecular chemistry》2003,1(21):3642-3644
Controlled site-selective glycosylation can be achieved by combining site-directed cysteine mutagenesis with chemical modification of the introduced thiol; a new class of more efficient chemoselective reagents, glycosyl phenylthiosulfonates, allow rapid glycosylations of representative simple thiols, peptides and proteins. 相似文献
12.
Dr. Siddhartha De Dr. Alexandrine Flambard Dr. Delphine Garnier Patrick Herson Dr. Frank H. Köhler Dr. Abhishake Mondal Dr. Karine Costuas Dr. Béatrice Gillon Prof. Rodrigue Lescouëzec Dr. Boris Le Guennic Dr. Frédéric Gendron 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(52):12120-12136
The local magnetic structure in the [FeIII(Tp)(CN)3]− building block was investigated by combining paramagnetic Nuclear Magnetic Resonance (pNMR) spectroscopy and polarized neutron diffraction (PND) with first-principle calculations. The use of the pNMR and PND experimental techniques revealed the extension of spin-density from the metal to the ligands, as well as the different spin mechanisms that take place in the cyanido ligands: Spin-polarization on the carbon atoms and spin-delocalization on the nitrogen atoms. The results of our combined density functional theory (DFT) and multireference calculations were found in good agreement with the PND results and the experimental NMR chemical shifts. Moreover, the ab-initio calculations allowed us to connect the experimental spin-density map characterized by PND and the suggested distribution of the spin-density on the ligands observed by NMR spectroscopy. Interestingly, significant differences were observed between the pseudo-contact contributions of the chemical shifts obtained by theoretical calculations and the values derived from NMR spectroscopy using a simple point-dipole model. These discrepancies underline the limitation of the point-dipole model and the need for more elaborate approaches to break down the experimental pNMR chemical shifts into contact and pseudo-contact contributions. 相似文献
13.
14.
15.
Habib Ammari Junqing Chen Zhiming Chen Josselin Garnier Darko Volkov 《Journal de Mathématiques Pures et Appliquées》2014
The goal of this paper is to contribute to the field of nondestructive testing by eddy currents. We provide a mathematical analysis and a numerical framework for simulating the imaging of arbitrarily shaped small-volume conductive inclusions from electromagnetic induction data. We derive, with proof, a small-volume expansion of the eddy current data measured away from the conductive inclusion. The formula involves two polarization tensors: one associated with the magnetic contrast and the second with the conductivity of the inclusion. Based on this new formula, we design a location search algorithm. We include in this paper a discussion on data sampling, noise reduction, and probability of detection. We provide numerical examples that support our findings. 相似文献
16.
Sanchez-sanz M; Blyth MG 《The Quarterly Journal of Mechanics and Applied Mathematics》2007,60(2):125-138
Unsteady, axisymmetric stagnation flow about a circular cylinderis examined when the far-field flow is a periodic function oftime with a fixed time average and an oscillatory part of prescribedamplitude and frequency. Solutions are computed for arbitraryvalues of the Reynolds number, quantifying the effects of surfacecurvature, and a frequency parameter based on the period ofthe far-field flow. It is found that solutions remain regularand periodic provided that the far-field amplitude lies belowa critical value. Above this value, solutions terminate in afinite-time singularity. The blow-up time is delayed by increasingthe curvature of the surface. These results are corroboratedby asymptotic predictions valid in the limits of small and largeamplitude and frequency. For large Reynolds number, the problemreduces to the two-dimensional stagnation-point flow againsta plane wall studied by previous authors. 相似文献
17.
E. F. Schwier C. Monney N. Mariotti Z. Vydrovà M. García-Fernández C. Didiot M. G. Garnier P. Aebi 《The European Physical Journal B - Condensed Matter and Complex Systems》2011,81(4):399-403
We explore the interplay between the elastic scattering of photoelectrons and the surface core level shifts with regard to the determination of core level binding energies in Au(111) and Cu3Au(100). We find that an artificial shift is created in the binding energies of the Au 4f core levels, that exhibits a dependence on the emission angle, as well as on the spectral intensity of the core level emission itself. Using a simple model, we are able to reproduce the angular dependence of the shift and relate it to the anisotropy in the electron emission from the bulk layers. Our results demonstrate that interpretation of variation of the binding energy of core-levels should be conducted with great care and must take into account the possible influence of artificial shifts induced by elastic scattering. 相似文献
18.
J Garnier 《Waves in Random and Complex Media》2013,23(3):149-162
Abstract A statistical approach of the propagation of solitons in media with a spatially random potential is developed. Applying the inverse scattering transform several regimes are demonstrated which are determined by the mass and the velocity of the incoming soliton as well as by the correlation length of the random potential. Namely, the mass of the soliton is conserved if its initial amplitude is large enough. If the initial mass is small, then the mass decays with the length of the system. The decay rate is exponential in the case of a white noise perturbation, but it obeys a power law if the carrier wavenumber of the soliton lies in the tail of the spectrum of the potential. Furthermore, the scattered radiation propagates in a backward direction in the case of a white noise perturbation, while it propagates in a forward direction (with the same carrier wavenumber as the soliton) in the case of a coloured noise with long-range correlation. 相似文献
19.
M. Hengsberger P. Segovia M. Garnier D. Purdie Y. Baer 《The European Physical Journal B - Condensed Matter and Complex Systems》2000,17(4):603-608
We present high-resolution photoemission data from the Bi(111)-surface. The electronic structure of the semimetal close to
the Fermi level has been found to change dramatically with respect to the well established bulk band structure. The Fermi
surfaces observed for the electron and hole bands resemble those of the next group-V element, antimony, probably as a consequence
of surface relaxation. This results in a relatively high surface charge density. The observed temperature dependence of the
electron Fermi energy confirms this result.
Received 8 June 2000 相似文献
20.
René Garnier 《Annali di Matematica Pura ed Applicata》1962,58(1):1-34
Résumé Soit Γ un quadrilatère variable, dont deux c?tés opposés A2A3, A1A4 sont dans les plans x3=c, x3=−c. Quand c tend vers0, Γ tend vers un quadrilatèreΓ
0 présentant un point double, A0. Le travail étudie la représentation conforme sur le demi-plan R(ix)<0 (ou sur le cercle - unité) de la surface minimale
∑ passant par Γ. Il montre (§ I) que si les affixes x de A1, A2, A4 sont 0, 1, ∞, l'affixe de A3 sera ɛ−2, où ɛ tend vers 0 avec c. Il étudie (§ II) l'allure pour ɛ tendant vers 0 des intégrales canoniques de l'équation linéaire
du problème. La forme de la relation entre ɛ et c est indiquée au no 19; on montre que dans la région de striction ɛ |x| reste borné et que la surface ∑ y est assimilable à une surface minimale
simple: la surface de vis à filet carré. La représentation conforme de l'une des deux régions de ∑ qui tendent à se séparer
l'une de l'autre tend à envahir tout le demi-plan (ou tout le cercle-unité). Les représentations conformes de ∑ pour c>0 et
c<0 ne sont pas analytiquement distinctes (n0 20). A titre d'exemple, on étudie (n0 21) le cas où ∑ possède un axe de symétrie.
A M. Enrico Bompiani pour son Jubilé scientifique 相似文献