全文获取类型
收费全文 | 444篇 |
免费 | 29篇 |
专业分类
化学 | 266篇 |
晶体学 | 2篇 |
力学 | 11篇 |
数学 | 91篇 |
物理学 | 103篇 |
出版年
2023年 | 7篇 |
2022年 | 20篇 |
2021年 | 18篇 |
2020年 | 9篇 |
2019年 | 18篇 |
2018年 | 19篇 |
2017年 | 23篇 |
2016年 | 19篇 |
2015年 | 15篇 |
2014年 | 21篇 |
2013年 | 28篇 |
2012年 | 41篇 |
2011年 | 36篇 |
2010年 | 21篇 |
2009年 | 10篇 |
2008年 | 11篇 |
2007年 | 18篇 |
2006年 | 9篇 |
2005年 | 15篇 |
2004年 | 8篇 |
2003年 | 11篇 |
2002年 | 10篇 |
2001年 | 7篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1998年 | 4篇 |
1997年 | 3篇 |
1996年 | 2篇 |
1995年 | 5篇 |
1994年 | 2篇 |
1993年 | 4篇 |
1992年 | 2篇 |
1991年 | 4篇 |
1990年 | 1篇 |
1989年 | 5篇 |
1988年 | 3篇 |
1987年 | 4篇 |
1986年 | 5篇 |
1985年 | 1篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1980年 | 5篇 |
1979年 | 3篇 |
1978年 | 5篇 |
1977年 | 5篇 |
1976年 | 4篇 |
1975年 | 1篇 |
1974年 | 2篇 |
1973年 | 2篇 |
排序方式: 共有473条查询结果,搜索用时 31 毫秒
121.
1-Phenyl-, 1-m-tolyl- and 1-p-tolyl-1,2-dihydro-2-quinolone have been prepared by treating the potassium derivative of 1,2-dihydro-2-quinolone with the corresponding aryl bromide in the presence of finely divided copper. The use of o-bromotoluene in this reaction gave trace amounts of a crystalline material which upon the basis of mass spectrum analysis was assigned 2-o-tolyloxyquinoline as a structure. The 1-aryl groups caused an unusual chemical shift of the 8-proton to the Δ 6.64–6.70 region. This behavior paralleled that observed for the 7-proton of 6-phenyl-6H-indeno[1,2-c]isoquinoline-5,11-dione in earlier studies. 相似文献
122.
André C Thomassin M Truong TT Robert JF Guillaume YC 《Journal of chromatographic science》2003,41(6):311-316
The retention mechanism for a series of D,L-dansyl amino acids in high-performance liquid chromatography is investigated using a teicoplanin stationary phase and hydroxypropyl-beta-cyclodextrin (HP-beta-CD) as the mobile phase additive (0-16mM). A theoretical treatment is developed to determine the HP-beta-CD influence on the equilibrium between the teicoplanin phase and the aqueous medium, respectively. From the experimental data, the association constants of the D,L-dansyl amino acids-HP-beta-CD inclusion complexes are determined and discussed in relation to the enantiomer structure. A thermodynamic study confirms that both the retention and complexation mechanisms are independent of the dansyl amino acid molecular structure and its absolute carbon configuration. 相似文献
123.
This paper reports the results of an analytical study comparing capillary gas chromatography (GC) operated in the normal mode with 2 new GC techniques, comprehensive GC (GC x GC) and targeted (or selective) multidimensional GC, which use a longitudinally modulated cryogenic system (LMCS), recently developed in our laboratory. A high-temperature application of derivatized sterols, of interest in fecal pollution monitoring, was chosen for this work. A directly connected coupled-column ensemble was used, comprising a nonpolar column and a moderately polar column. With LMCS, effluent from the first column is zone-compressed in a cryogenic trap and then pulsed to a short second column, producing narrower peaks with sharp, tall peak responses at the detector. The modulator is operated at a constant frequency, e.g., 0.25 s(-1), to produce the GC x GC result, or is moved in a predefined manner so that whole peaks are selectively trapped and subsequently pulsed through to the second column in the targeted mode. Standard solutions containing a mixture of 7 sterols and 5-alpha-cholestane internal standard were used. Detection sensitivity is increased by a factor of >25 with the use of LMCS. The estimated limit of detection was about 0.1 microg/mL when normal GC with flame ionization detection (GC/FID) and a 1.0 microL splitless injection volume were used, compared with 0.02 and 0.004 microg/mL for the LMCS operated in GC x GC and selective modes, respectively. Calibration curves for GC/FID were linear over the 0.1-2.0 microg/mL range tested. Reproducibilities for the GC x GC and normal GC modes were comparable; generally, relative standard deviations (RSD) were on the order of 3-4%, based on raw peak responses. Improved reproducibility was found for selective LMCS operation, at an RSD of around 2%; with internal standardization, better results were achieved. The coupled-column arrangement allowed complete separation of sterol peaks from overlapping impurity peaks in a number of instances with LMCS modes, and its use should improve data quality over that of normal GC operation, in which the overlapping peaks interfere with measurement of peak response in the normal mode. 相似文献
124.
Huy Truong Nguyen Thanh-Trung Nguyen Thuc-Huy Duong Nguyen-Minh-An Tran Chuong Hoang Nguyen Thi-Hong-Anh Nguyen Jirapast Sichaem 《Molecules (Basel, Switzerland)》2022,27(8)
α-Glucosidase plays a role in hydrolyzing complex carbohydrates into glucose, which is easily absorbed, causing postprandial hyperglycemia. Inhibition of α-glucosidase is therefore an ideal approach to preventing this condition. A novel polyprenylated benzoylphloroglucinol, which we named schomburgkianone I (1), was isolated from the fruit of Garcinia schomburgkiana, along with an already-reported compound, guttiferone K (2). The structures of the two compounds were determined using NMR and HRESIMS analysis, and comparisons were made with previous studies. Compounds 1 and 2 exhibited potent α-glucosidase inhibition (IC50s of 21.2 and 34.8 µM, respectively), outperforming the acarbose positive control. Compound 1 produced wide zones of inhibition against Staphylococcus aureus and Enterococcus faecium (of 21 and 20 mm, respectively), compared with the 19 and 20 mm zones of compound 2, at a concentration of 50 µg/mL. The MIC value of compound 1 against S. aureus was 13.32 µM. An in silico molecular docking model suggested that both compounds are potent inhibitors of enzyme α-glucosidase and are therefore leading candidates as therapies for diabetes mellitus. 相似文献
125.
Fast fractal image compression using spatial correlation 总被引:6,自引:0,他引:6
Fractal image compression is time consuming in the encoding process. The time is essentially spent on the search for the best-match block in a large domain pool. In this paper, the spatial correlations in both the domain pool and the range pool are utilized to reduce the searching space. With this technique, the encoding speed is 2.6 times faster than that of the full search method while the quality of the retrieved image is almost the same. Moreover, since the searching space is limited to the matched blocks of the previous range blocks, fewer bits are required to represent the transform. The bit rate is thus improved by about 20%. 相似文献
126.
S. Lau Truong G. Levi F. Bozon-Verduraz A.V. Petrovskaya A.V. Simakin G.A. Shafeev 《Applied Physics A: Materials Science & Processing》2007,89(2):373-376
The formation of dense arrays of nanospikes occurs under laser ablation of bulk silver immersed in liquids such as water or
ethanol. The average height of spikes is 50 nm and their density on the target amounts to 1010 cm-2. This effect is observed with sufficiently short laser pulses. In particular, either a 350 ps or a 90 ps Nd:YAG lasers are
used operating in their fundamental harmonics. These nanospikes are characterized by UV–visible reflection spectrometry and
atomic force microscopy. The oscillations of electrons within Ag nanospikes results in a permanent coloration of the surface
and a modification of the optical reflection spectra of the metal. Nanospikes show a peak of plasmon resonance around 380 nm,
which shifts to the visible range upon oxidation in air. The initial spectrum may be restored by reduction of the oxidized
Ag surface through processing in an ammonia aqueous solution. Scanning the laser beam along the metal surface allows its nanostructuring
over extended areas (∼1 cm2). The nanostructured Ag surface shows enhanced Raman scattering of acridine molecules at a concentration of 10-5 M/l, whereas initial Ag target do not show any signal within the accuracy of measurements.
PACS 68.65.k; 64.70.Dv; 79.20.Ds; 42.62.Cf 相似文献
127.
A current algebra calculation of e+e-→4π± cross section is carried out using the axial current matrix element obtained from τ→π?ν. Assuming ?′→?+2π(I=0, l=0), the following results are obtained: for the A1 resonance, 1.05?mA ?1.15 GeV; for ?′, Γ?′(total)≈0.23 GeV, M?′≈1.5 GeV, Γ(?′→e+e-)≈0.4 keV×B?1(?′→?′ →?π+π). 相似文献
128.
Absence of particle production, non-vanishing backward scattering and factorization are shown to determine uniquely the S-matrix. 相似文献
129.
130.
We sketch a program for the explicit construction of the sine-Gordon and the massive Thirring-model fields. This construction only works in the phase of the model in which the infinite set of “soliton conservation laws” are valid. The procedure entails two steps of which we only indicate explicitly the first, namely the determination of the S-matrix leading to the sine-Gordon spectrum. 相似文献