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131.
In this paper, we establish an exact asymptotic formula for the finite-time ruin probability of a nonstandard compound renewal risk model with constant force of interest in which claims arrive in groups, their sizes in one group are identically distributed but negatively dependent, and the inter-arrival times between groups are negatively dependent too.  相似文献   
132.
Excitation wavelength dependent (Ex‐De) emission materials have potential applications in anti‐counterfeiting labels and bioimaging. Nevertheless, few purely organic chromophores are used in these areas. In this study, multiple excited states were incorporated into a molecule that was excited state intramolecular proton transfer (ESIPT) active, with the goal of manipulating the relaxation pathways of the excited states. The triazole derivative exhibits Ex‐De photoluminescence (PL), and the maximum PL wavelength is located at 526 nm and 593 nm under a series of excitation wavelengths. Spectral identification indicates that the excimer and ESIPT processes are responsible for the green (526 nm) and orange (593 nm) fluorescence, respectively. Importantly, the quick response code and test strip prepared with this triazole derivative can be used for anti‐counterfeiting and food spoilage detection applications, respectively. This research opens the door for developing novel Ex‐De materials for anti‐counterfeiting purposes.  相似文献   
133.
In TEMPO (2,2,6,6,‐tetramethyl‐1‐piperidinyloxy) controlled styrene radical polymerizations, the thermal self‐initiation reaction of styrene monomer is one of the main sources for the deviations from ideal living polymerization. However, it is also important because it continuously generates radicals to compensate for the loss of radicals caused by the termination reactions and thereby maintains a reasonable reaction rate. In this report, different initial TEMPO concentrations were used in styrene miniemulsion polymerizations without any added initiator. The consumption rate of TEMPO or radical generation rate was calculated from the length of the induction period and the increasing total number of polymer chains. It was found that there is little difference between the miniemulsions and the corresponding bulk systems in terms of the length of the induction period, which increases linearly with initial TEMPO concentration. After the induction period, the consumption rate of TEMPO or radical generation rate was reduced to a lower level, and a faster initial polymerization rate was found in the bulk system compared to the corresponding miniemulsion system. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4921–4932, 2004  相似文献   
134.
改性活性炭纤维吸附二甲胺水溶液的研究   总被引:2,自引:0,他引:2  
采用气相氧化法制备改性ACF,以二甲胺水溶液为吸附对象,在静态吸附条件下研究了吸附时间、温度、ACF用量对吸附效果的影响,获得了吸附等温线;在动态吸附条件下测定了动态穿透曲线,并研究了ACF的再生方法。在ACF优化用量0.6g/100mL溶液条件下,对初始浓度256mg/L二甲胺溶液的吸附率为85%;吸附饱和的ACF用5%盐酸溶液进行再生时,再生率接近100%。  相似文献   
135.
介绍了能量色散X荧光分析方法在含水Fe样品测量中的应用。用ANTG 2000型海底X荧光探测系统对含Fe为10%~60%的Fe样进行测量,建立水分对Fe元素特征Kα射线影响的校正模型。结果表明,通过该模型校正,对含饱和水情况下Fe样品的分析相对误差小于4%,具有良好的分析效果。  相似文献   
136.
分析了光子晶体谐振腔的模式选择功能,实现光子晶体谐振腔回旋管振荡器高阶电磁模与高次电子回旋模的有效耦合,并成功抑制了模式竞争。通过对光子晶体谐振腔禁带特性的分析,定出了工作模式为TE23模,还建立了光子晶体谐振腔回旋管的等效半径的概念,设计了自洽非线性理论和相关的计算机数值模拟程序。研究发现TE23模能有效地与电子的二次回旋谐波相互作用,其耦合频率为206 GHz,并极大地降低了对工作磁场的要求。在考虑诸多物理因素影响的情况下,对该二次谐波光子带隙谐振腔(PBGC)回旋管振荡器进行了参数优化,得到了电压40 kV、电流4.2 A、磁场3.925 T、输出功率35 kW、互作用效率21%的二次谐波TE23模PBGC回旋管振荡器。  相似文献   
137.
A companding method for peak-to-average power ratio (PAPR) reduction in optical orthogonal frequency division multiplexing systems has been proposed and simulated. The proposed scheme is based on the modified hyperbolic tangent transform, which can enlarge the small signals and compress the large signals while keeping the average power invariant. Simulation results verify that the proposed companding scheme can markedly decrease the PAPR, and a good bit error rate performance is obtained.  相似文献   
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