Entangling different degrees of freedom by quadrature squeezing cylindrically polarized modes

Quantum systems such as, for example, photons, atoms, or Bose-Einstein condensates, prepared in complex states where entanglement between distinct degrees of freedom is present, may display several intriguing features. In this Letter we introduce the concept of such complex quantum states for intense beams of light by exploiting the properties of cylindrically polarized modes. We show that already in a classical picture the spatial and polarization field variables of these modes cannot be factorized. Theoretically it is proven that by quadrature squeezing cylindrically polarized modes one generates entanglement between these two different degrees of freedom. Experimentally we demonstrate amplitude squeezing of an azimuthally polarized mode by exploiting the nonlinear Kerr effect in a specially tailored photonic crystal fiber. These results display that such novel continuous-variable entangled systems can, in principle, be realized.     

Long-range dependence in the volatility of commodity futures prices: Wavelet-based evidence

Commodity futures have long been used to facilitate risk management and inventory stabilization. The study of commodity futures prices has attracted much attention in the literature because they are highly volatile and because commodities represent a large proportion of the export value in many developing countries. Previous research has found apparently contradictory findings about the presence of long memory or more generally, long-range dependence. This note investigates the nature of long-range dependence in the volatility of 14 energy and agricultural commodity futures price series using the improved Hurst coefficient (H) estimator of Abry, Teyssière and Veitch. This estimator is motivated by the ability of wavelets to detect self-similarity and also enables a test for the stability of H. The results show evidence of long-range dependence for all 14 commodities and of a non-stationary H for 9 of 14 commodities.     

Kinetics and mechanisms of gas‐phase elimination of 2,2‐diethoxyethyl amine and 2,2‐diethoxy‐N,N‐diethylethanamine

The gas‐phase elimination kinetics of 2,2‐diethoxyethyl amine and 2,2‐diethoxy‐N,N‐diethylethanamine (320–380 °C; 40–150 Torr) in a seasoned reaction vessel are homogeneous, unimolecular and obey a first‐order rate law. These elimination processes involve two parallel reactions. The first gives ethanol and the corresponding 2‐ethoxyethenamine. The latter compound further decomposes to ethylene, CO and the corresponding amine. The second parallel reaction produce ethane and the corresponding ethyl ester of an α‐amino acid. The following Arrhenius expressions are given as: For 2,2‐diethoxyethyl amine For 2,2‐diethoxy‐N,N‐diethylethanamine Comparative kinetic and thermodynamic parameters of the overall, the parallel and the consecutive reactions lead to consider two types of mechanisms in terms of a concerted polar cyclic transition state structures. Copyright © 2008 John Wiley & Sons, Ltd.     

On the number of curves of genus 2 over a finite field

In this paper we compute the number of curves of genus 2 defined over a finite field k of odd characteristic up to isomorphisms defined over k; the even characteristic case is treated in an ongoing work (G. Cardona, E. Nart, J. Pujolàs, Curves of genus 2 over field of even characteristic, 2003, submitted for publication). To this end, we first give a parametrization of all points in , the moduli variety that classifies genus 2 curves up to isomorphism, defined over an arbitrary perfect field (of zero or odd characteristic) and corresponding to curves with non-trivial reduced group of automorphisms; we also give an explicit representative defined over that field for each of these points. Then, we use cohomological methods to compute the number of k-isomorphism classes for each point in .     

Minimal entropy and collapsing with curvature bounded from below

We show that if a closed manifold M admits an ℱ-structure (not necessarily polarized, possibly of rank zero) then its minimal entropy vanishes. In particular, this is the case if M admits a non-trivial S ¹-action. As a corollary we obtain that the simplicial volume of a manifold admitting an ℱ-structure is zero.?We also show that if M admits an ℱ-structure then it collapses with curvature bounded from below. This in turn implies that M collapses with bounded scalar curvature or, equivalently, its Yamabe invariant is non-negative.?We show that ℱ-structures of rank zero appear rather frequently: every compact complex elliptic surface admits one as well as any simply connected closed 5-manifold.?We use these results to study the minimal entropy problem. We show the following two theorems: suppose that M is a closed manifold obtained by taking connected sums of copies of S ⁴, ℂP ², ²,S ²×S ²and the K3 surface. Then M has zero minimal entropy. Moreover, M admits a smooth Riemannian metric with zero topological entropy if and only if M is diffeomorphic to S ⁴,ℂP ²,S ²×S ²,ℂP ²#  ² or ℂP ²# ℂP ². Finally, suppose that M is a closed simply connected 5-manifold. Then M has zero minimal entropy. Moreover, M admits a smooth Riemannian metric with zero topological entropy if and only if M is diffeomorphic to S ⁵,S ³×S ², then on trivial S ³-bundle over S ² or the Wu-manifold SU(3)/SO(3). Oblatum 13-III-2002 & 12-VIII-2002?Published online: 8 November 2002 G.P. Paternain was partially supported by CIMAT, Guanajuato, México.?J. Petean is supported by grant 37558-E of CONACYT.     

The dynamics of excitons and trions in resonant tunneling diodes

The aim of this work is to study the dynamic formation and dissociation of trions and excitons in double barrier resonant tunneling diodes. We propose a system of rate equations that takes into account the formation, dissociation and annihilation of these complexes inside the quantum well. From the solutions of the coupled equations, we are able to study the modulation of excitons and trions formation in the device as a function of the applied bias. The results of our model agree qualitatively with the experiments showing the viability of these rate equations system to study the dynamics of complex systems.     

Sunset decay of the convective turbulence with Large-Eddy Simulation under realistic conditions

Large-Eddy Simulation is performed for a single day from the Cooperative Atmosphere-Surface Exchange Study (CASES-99) field program. This study investigates an observed case of evening transition boundary layer over land. Parameters of the ambient atmosphere in the LES-decay studies conducted so far were typically prescribed in an idealized form. To provide suitable data under the wide range of the PBL weather conditions, the LES should be able to adequately reproduce the PBL turbulence dynamics including–if possible–baroclinicity, radiation, large scale advection and not only be related to a decreasing surface heating. In addition LES-decay studies usually assume that the sensible heat flux decreases instantaneously or with a very short time scale. The main purpose of this investigation is to study the decay of boundary-layer average turbulent kinetic energy at sunset with Large-Eddy Simulation that is forced with realistic environment conditions. This allows investigating the Turbulent Kinetic Energy decay over the realistic time scale that is observed in the atmosphere. During the intermediate and last stage of decay of the boundary-layer average Turbulent Kinetic Energy the exponents of the decay power law t⁻ⁿ$t^{-n}$ go from 2 to 6, as evidenced by experimental results and recent analytical modeling in the surface layer.     

Homogeneous and unimolecular gas‐phase thermal decomposition kinetics of methyl benzoylformate: experimental and theoretical study

The kinetics of the gas‐phase thermal decomposition of the α‐ketoester methyl benzoylformate was carried out in a static system with reaction vessel deactivated with allyl bromide, and in the presence of the free radical inhibitor propene. The rate coefficients were determined over the temperature range of 440–481 °C and pressures from 32 to 80 Torr. The reaction was found to be homogenous, unimolecular and obey a first‐order rate law. The products are methyl benzoate and CO. The temperature dependence of the rate coefficient gives the following Arrhenius parameters: log₁₀ k (s^?1) = 13.56 ± 0.31 and E_a (kJ mol^?1) = 232.6 ± 4.4. Theoretical calculations of the kinetic and thermodynamic parameters are in good agreement with the experimental values using PBE1PBE/6‐311++g(d,p). A theoretical Arrhenius plot was constructed at this level of theory, and the good agreement with the experimental Arrhenius plot suggests that this model of transition state may describe reasonably the elimination process. These results suggest a concerted non‐synchronous semi‐polar three‐membered cyclic transition state type of mechanism. The most advanced coordinate is the bond breaking C^δ+‐‐‐^δ‐OCH₃ with an evolution of 66.7%, implying this as the limiting factor of the elimination process. Copyright © 2014 John Wiley & Sons, Ltd.