全文获取类型
收费全文 | 2829篇 |
免费 | 95篇 |
国内免费 | 33篇 |
专业分类
化学 | 1746篇 |
晶体学 | 25篇 |
力学 | 85篇 |
数学 | 601篇 |
物理学 | 500篇 |
出版年
2023年 | 28篇 |
2022年 | 62篇 |
2021年 | 69篇 |
2020年 | 55篇 |
2019年 | 46篇 |
2018年 | 63篇 |
2017年 | 44篇 |
2016年 | 99篇 |
2015年 | 97篇 |
2014年 | 106篇 |
2013年 | 167篇 |
2012年 | 164篇 |
2011年 | 172篇 |
2010年 | 116篇 |
2009年 | 107篇 |
2008年 | 165篇 |
2007年 | 146篇 |
2006年 | 141篇 |
2005年 | 133篇 |
2004年 | 109篇 |
2003年 | 72篇 |
2002年 | 96篇 |
2001年 | 35篇 |
2000年 | 35篇 |
1999年 | 31篇 |
1998年 | 28篇 |
1997年 | 27篇 |
1996年 | 24篇 |
1995年 | 18篇 |
1994年 | 15篇 |
1993年 | 29篇 |
1992年 | 23篇 |
1991年 | 31篇 |
1990年 | 16篇 |
1989年 | 8篇 |
1988年 | 14篇 |
1987年 | 21篇 |
1986年 | 9篇 |
1985年 | 33篇 |
1984年 | 25篇 |
1983年 | 14篇 |
1982年 | 21篇 |
1981年 | 24篇 |
1980年 | 12篇 |
1979年 | 23篇 |
1978年 | 25篇 |
1977年 | 24篇 |
1976年 | 13篇 |
1975年 | 14篇 |
1973年 | 8篇 |
排序方式: 共有2957条查询结果,搜索用时 15 毫秒
931.
932.
修正多重尺度法在圆薄板大挠度弯曲问题中的应用及其渐近性研究(Ⅰ) 总被引:1,自引:1,他引:0
本文应用修正多重尺度法研究圆板在铰链和简单支承条件下的大挠度弯曲。作出其级数解,分析其边界层效应和证明其渐近性。 相似文献
933.
934.
935.
Sorin Bucsa Alexandru Serban Mugur C. Balan Claudia Ionita Gabriel Nastase Catalina Dobre Alexandru Dobrovicescu 《Entropy (Basel, Switzerland)》2022,24(2)
This case study analyzes a cryogenic air separation unit (ASU) with a production of of gaseous oxygen with a concentration greater than 98.5%, operating in Romania on a steel plant platform. The goal of the paper is to provide an extensive model of exergetic analysis that could be used in an optimization procedure when decisional parameters are changed or structural design modifications are implemented. For each key part of the Air Separation Unit, an exergetic product and fuel were defined and, based on their definition, the coefficient of performance of each functional zone was calculated. The information about the magnitude of the exergetic losses offers solutions for their future recovery. The analysis of the exergy destructions suggests when it is worth making a larger investment. The exergetic analysis of the compression area of the ASU points out an exergy destruction and loss of 37% from the total plant’s electrical energy input. The exergy loss with the heat transferred to the cooling system of compressors can be recovered; for the exergy destruction portion, the challenge between investment and operating costs should be considered. The exergy destruction of the air separation columns found the High Pressure Column (HPC) to be more destructive than the Low Pressure Column. The share of the exergy destruction in the total plant’s electrical energy input is 8.3% for the HPC. The local COP of the HPC, calculated depending on the total exergy of the local product and fuel, is 62.66%. The calculus of the air separation column is performed with the ChemSep simulator. 相似文献
936.
Gabriel Iftime Jean-Claude Daran Eric Manoury Gilbert G. A. Balavoine 《Angewandte Chemie (International ed. in English)》1998,37(12):1698-1701
Exclusively planar chirality is exhibited by the ferrocenes obtained in a highly enantioselective synthesis in which a chiral aminoamide acts as a temporary protecting/directing group. This method was used to obtain an enantiomerically pure tetrasubstituted ferrocene, which was transformed into the first C2-symmetric disubstituted ferrocenophane [Eq. (1)]. 相似文献
937.
José R. Mora Edgar Márquez Jesus Lezama Tania Córdova Gabriel Chuchani 《International journal of quantum chemistry》2011,111(15):4011-4019
The kinetics and mechanisms of the gas‐phase elimination reactions of neopentyl chloride and neopentyl bromide have been studied by means of electronic structure calculations using density functional methods: B3LYP/6‐31G(d,p), B3LYP/ 6‐31++G(d,p), MPW1PW91/6‐31G(d,p), MPW1PW91/6‐31++G(d,p), PBEPBE/6‐31G(d,p), PBEPBE /6‐31++G(d,p). The reaction channels that account in products formation have a common first step involving a Wagner‐Meerwein rearrangement. The migration of the halide from the terminal carbon to the more substituted carbon is followed by beta‐elimination of HCl or HBr to give two olefins: the Sayzeff and Hoffmann products. Theoretical calculations demonstrated that these eliminations proceed through concerted asynchronous process. The transition state (TS) located for the rate‐determining step shows the halide detached and bridging between the terminal carbon and the quaternary carbon, while the methyl group is also migrating in a concerted fashion. The TS is described as an intimate ion‐pair with a large negative charge at the halide atom. The concerted migration of methyl group provides stabilization of the TS by delocalizing the electron density between the terminal carbon and the quaternary carbon. The B3LYP/6‐31++G(d,p) allows to obtain reasonable energies and enthalpies of activation. The nature of these reactions is examined in terms of geometrical parameters, electron distribution, and bond order analysis. © 2011 Wiley Periodicals, Inc. Int J Quantum Chem, 2011 相似文献
938.
The study of the kinetics and mechanism of dehydrochlorination reaction of 2‐methyl benzyl chloride in the gas phase was carried out by means of electronic structure calculations using ab initio Móller‐Plesset MP2/6‐31G(d,p), and Density Functional Theory (DFT) methods: B3LYP/6‐31G(d,p), B3LYP/6‐31++G(d,p), MPW1PW91/6‐31G(d,p), MPW1PW91/6‐31++G(d,p)], PBE/6‐31G(d,p), PBE/6‐31++G(d,p). Investigated reaction pathways comprise: Mechanism I, a concerted reaction through a six‐centered cyclic transition state (TS) geometry; Mechanism II, a 1,3‐chlorine shift followed by beta‐elimination and Mechanism III, a single‐step elimination with simultaneous HCl and benzocyclobutene formation through a bicyclic type of TS. Calculated parameters ruled out Mechanism III and suggest the elimination reaction may occur by either unimolecular Mechanism I or Mechanism II. However, the TS of the former is 20 kJ/mole more stable than the TS of the latter. Consequently, the Mechanism I seem to be more probable to occur. The rate‐determining process is the breaking of C‐Cl bond. The involvement of π‐electrons of the aromatic system was demonstrated by NBO charges and bond order calculations. The reaction is moderately polar in nature. © 2011 Wiley Periodicals, Inc. Int J Chem Kinet 43: 537–546, 2011 相似文献
939.
940.