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71.
72.
Jia‐Yuh Sheu Yeh‐Long Chen Cherng‐Chyi Tzeng Shu‐Lin Hsu Kuo‐Chang Fang Tai‐Chi Wang 《Helvetica chimica acta》2003,86(7):2481-2489
Certain 1‐ethyl‐ and 1‐aryl‐6‐fluoro‐1,4‐dihydroquinol‐4‐one derivatives were synthesized and evaluated for antimycobacterial and cytotoxic activities. Preliminary results indicated that, for 1‐aryl‐6‐fluoroquinolones, both 7‐(piperazin‐1‐yl)‐ and 7‐(4‐methylpiperazin‐1‐yl) derivatives, 9b and 11a , are able to completely inhibit the growth of M. tuberculosis at a concentration of 6.25 μg/ml, while the 7‐[4‐(2‐oxo‐2‐phenylethyl)piperazin‐1‐yl] derivative 13 exhibits only 31% growth inhibition at the same concentration. For 1‐ethyl‐6‐fluoroquinolones, both 7‐[4‐(2‐oxopropyl)piperazin‐1‐yl]‐ and 7‐[4‐(2‐oxo‐2‐phenylethyl)piperazin‐1‐yl]‐derivatives, 2a and 2b , respectively, show complete inhibition, while their 2‐iminoethyl and substituted phenyl counterparts 3a and 2c are less active. In addition, the 6,8‐difluoro derivative was a more‐favorable inhibitor than its 6‐fluoro counterpart ( 2b vs. 2d ). These results deserve full attention especially because 2a, 2b, 9b , and 11a are non‐cytotoxic at a concentration of 100 μM . Furthermore, compound 9b proved to be a potent anti‐TB agent with selective index (SI)>40 and an EC90 value of 5.75 μg/ml. 相似文献
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采用淋洗液发生器阴离子交换-抑制电导检测法,同时分离和检测阿思巴甜、甜蜜素、安赛蜜和糖精4种常见的甜味剂.由于采用了淋洗液发生器,使背景电导大大降低,可以实现甜味剂的高灵敏度检测和分离.该方法具有良好的重现性、线性关系和较低的检测限.阿思巴甜、甜蜜素、安赛蜜和糖精的检测限分别是:1.27、0.045、0.033、0.063 mg/L;样品测定的回收率分别为99.7%、102.8%、98.6%、103.5%. 相似文献
75.
Reported are fiber de-multiplexers based on side-polished fibers with a long interaction length and intra-core fiberBragg gratings. In conjunction with the silicon processing technologies, we demonstrate fiber filters and advantages ofour approaches are addressed. 相似文献
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STUDIES ON HYPERFINE STRUCTURE AND ISOTOPE SHIFT OF SOME EXCITED STATES IN Yb AND Tm ATOMS 下载免费PDF全文
The hyperfine structures and isotope shifts in some excited states of Yb and Tm have been measured using laser-atomic beam interaction, stepwise excitation and fluorescence detection techniques. From the experimental results, magnetic dipole hyperfine constants A and electric quadrupole hyperfine constants B have been derived. So for as we know, the A factor of [4f125d6s6p]9/2 level in Tm is given for the first time. 相似文献
79.
The electronic structure and magnetism of SmCo7-xZrx alloy are investigated using the spin-polarized MS-X. method. The results show that a few of electrons are transferred to the Sm(5d0) orbital due to orbital hybridization between Sm and Co atoms. The exchange interactions between 3d and 5d electrons are more important than the polarization effects of the conductive electrons, thus it is the main reason resulting in the long-range ferromagnetic order in SmCo7-xZrx. The Curie temperature of SmCo7-xZrx is generally lower than that of corresponding pure Co, which may be explained by the weaker average coupling strength between Co lattices due to some negative couplings mainly occurring of 2e site. The calculated results for the Sm5Co32Zr2 cluster may lead to a better understanding of why SmCo7-xZrx is stable phase. Since the spin-up DOS peak of d electrons at EF arises and the bonding of electrons at EF strengthens with increasing Zr concentration, which results in the internal energy of the system decrease, the stable ferromagnetic order forms in SmCo7-xZrx. 相似文献
80.
采用浮床黑麦草(Lolium multi florum)对畜禽养殖富营养水体氨氮的净化效应及动态过程进行了研究.结果表明:浮床黑麦草对富营养水体中的氨氮具有明显的净化效果.当覆盖率30%时,对氨氮的去除率最高可达到95.89%.对其去除水体氨氮的动态过程拟合表明符合三次方程曲线.该研究为冬季陆生植物修复富营养水体提供重要依据. 相似文献