全文获取类型
收费全文 | 15607篇 |
免费 | 2563篇 |
国内免费 | 3064篇 |
专业分类
化学 | 11544篇 |
晶体学 | 384篇 |
力学 | 1053篇 |
综合类 | 284篇 |
数学 | 1963篇 |
物理学 | 6006篇 |
出版年
2024年 | 33篇 |
2023年 | 194篇 |
2022年 | 456篇 |
2021年 | 501篇 |
2020年 | 508篇 |
2019年 | 577篇 |
2018年 | 513篇 |
2017年 | 575篇 |
2016年 | 714篇 |
2015年 | 809篇 |
2014年 | 903篇 |
2013年 | 1199篇 |
2012年 | 1341篇 |
2011年 | 1368篇 |
2010年 | 1055篇 |
2009年 | 1142篇 |
2008年 | 1220篇 |
2007年 | 1147篇 |
2006年 | 1112篇 |
2005年 | 877篇 |
2004年 | 782篇 |
2003年 | 639篇 |
2002年 | 753篇 |
2001年 | 663篇 |
2000年 | 477篇 |
1999年 | 371篇 |
1998年 | 249篇 |
1997年 | 167篇 |
1996年 | 146篇 |
1995年 | 123篇 |
1994年 | 95篇 |
1993年 | 106篇 |
1992年 | 68篇 |
1991年 | 62篇 |
1990年 | 50篇 |
1989年 | 49篇 |
1988年 | 35篇 |
1987年 | 40篇 |
1986年 | 24篇 |
1985年 | 24篇 |
1984年 | 14篇 |
1983年 | 11篇 |
1982年 | 6篇 |
1981年 | 10篇 |
1980年 | 8篇 |
1979年 | 7篇 |
1975年 | 1篇 |
1971年 | 1篇 |
1957年 | 1篇 |
1936年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
Qing Shi Dong Yang Yanlei Su Jian Li Zhongyi Jiang Yanjun Jiang Weikang Yuan 《Journal of nanoparticle research》2007,9(6):1205-1210
Lipase from Candida rugosa was covalently anchored onto acid-treated multi-walled carbon nanotubes (MWNTs) through a self-catalytic mechanism. A variety
of characterization techniques including FTIR, Raman spectroscopy, and XPS were employed to demonstrate the formation of the
ester linkage between lipase and MWNTs. The MWNTs-lipase biocomposites showed significantly increased solubility in some common-used
organic solvents, such as THF, DMF and chloroform. This study may offer a novel and facile route for covalent modification
of carbon nanotubes, and expand the potential utilization of both lipases and MWNTs in the fields of biocatalyst and biosensor. 相似文献
22.
This paper discusses a class of second-order derivative nonlinear Schrödinger equations which are used to describe the upper-hybrid oscillation propagation. By establishing a variational problem, applying the potential well argument and the concavity method, we prove that there exists a sharp condition for global existence and blow-up of the solutions to the nonlinear Schrödinger equation. In addition, we also answer the question: how small are the initial data, the global solutions exist? 相似文献
23.
Thin films of polystyrene (PS), poly(methyl methacrylate) (PMMA) and polystyrene-polyacrylonitrile copolymer (PS-AN), containing various embedded transition-metal complexes, have been studied by FTIR microscopy. The spatial distributions of the transition-metal carbonyl complexes throughout the thin organic polymer films have been determined by a two-dimensional IR mapping procedure. The spectral variations observed in the distribution of the metal carbonyls throughout the different polymer films are discussed. The IR data show that the technique used to prepare the organometallic-embedded thin films (viz. freeze-drying of solutions followed by hot mechanical pressing of the residues) does in general lead to homogeneous films which may eventually find industrial application, e.g. as membrane sensors for small molecules. 相似文献
24.
Guo Qing LI Zhong Jiao JIA 《中国化学快报》2003,14(1):62-65
Two new ionone derivatives,named rhododendrone and rhododendronside,were isolated from the alcohoilc extract of the aerial parts of Rhododendron przwalskii Maxim.Their structures were elucidated on the basis of spectroscopic analysis. 相似文献
25.
26.
This article focuses on discontinuous Galerkin method for the two‐ or three‐dimensional stationary incompressible Navier‐Stokes equations. The velocity field is approximated by discontinuous locally solenoidal finite element, and the pressure is approximated by the standard conforming finite element. Then, superconvergence of nonconforming finite element approximations is applied by using least‐squares surface fitting for the stationary Navier‐Stokes equations. The method ameliorates the two noticeable disadvantages about the given finite element pair. Finally, the superconvergence result is provided under some regular assumptions. © 2006 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 23: 421–436, 2007 相似文献
27.
We prove some basic properties of Donaldson’s flow of surfaces in a hyperkähler 4-manifold. When the initial submanifold is symplectic with respect to one Kähler form and Lagrangian with respect to another, we show that certain kinds of singularities cannot form, and we prove a convergence result under a condition related to one considered by M.-T. Wang for the mean curvature flow. 相似文献
28.
介绍一种二元阈值方法在股票指数上的应用 总被引:4,自引:0,他引:4
二元极值的阈值方法的一个发展是用来考虑两个变量的联合分布。这个方法是建立在二元极值的点过程表示法的基础上。本文用参数 (Logistic模型 )和非参数模型对 1992 1999年的上海、深圳日收盘指数对数收益进行分析并给出分析结果。 相似文献
29.
本文研究了两类重要微分不等式有界解的性质。引入了赋范线性空间(f,‖‖M),利用比较定理和黎卡提方程解的性质,给出了有界解的上界估计式,推广和改进了文[1,2]中的有关结果. 相似文献
30.
Wei‐Ling Wang Jian‐Wei Xu Yee‐Hing Lai 《Journal of polymer science. Part A, Polymer chemistry》2006,44(13):4154-4164
Bipyridinophane–fluorene conjugated copolymers have been synthesized via Suzuki and Heck coupling reactions from 5,8‐dibromo‐2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane and suitable fluorene precursors. Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P7 ) exhibits large absorption and emission redshifts of 20 and 34 nm, respectively, with respect to its planar reference polymer Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐1,4‐(2,5‐dimethylbenzene)] ( P11 ), which bears the same polymer backbone as P7 . These spectral shifts originate from intramolecular aromatic C? H/π interactions, which are evidenced by ultraviolet–visible and 1H NMR spectra as well as X‐ray single‐crystal structural analysis. However, the effect of the intramolecular aromatic C? H/π interactions on the spectral shift in poly[9,9‐dihexylfluorene‐2,7‐yleneethynylene‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P10 ) is much weaker. Most interestingly, the quenching behaviors of these two conjugated polymers are largely dependent on the polymer backbone. For example, the fluorescence of P7 is efficiently quenched by Cu2+, Co2+, Ni2+, Zn2+, Mn2+, and Ag+ ions. In contrast, only Cu2+, Co2+, and Ni2+ ions can partially quench the fluorescence of P10 , but much less efficiently than the fluorescence of P7 . The static Stern–Volmer quenching constants of Cu2+, Co2+, and Ni2+ ions toward P7 are of the order of 106 M?1, being 1300, 2500, and 37,300 times larger than those of P10 , respectively. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4154–4164, 2006 相似文献