光纤化学传感技术研究近况

光纤化学传感器作为传感器的一个重要分支,结合了化学和光学的相关技术,将化学制膜、光纤技术以及化学分析中的分光光度法、拉曼光谱、荧光光谱、折射率检测等方法相融合,以其微型化,抗电磁干扰,传输信息量大,拥有自身参比等特点不断向前发展。简要综述了光纤化学传感技术研究近况和未来的发展趋势。重点对光纤pH化学传感器、光纤离子化学传感器和光纤气体化学传感器进行了介绍。简要分析了常见的敏感膜制备方法如化学键合法和溶胶凝胶(sol-gel)等方法。新型光纤——微结构光纤的出现为光纤化学传感器开辟了新的发展方向。由于其具有大的内表面积,结构设计灵活多样,光纤内部提供感应场所等特点,快速度成为光纤化学传感器的重要发展方向和研究热点。对微结构光纤衍生而来的新型光纤化学传感器进行了详细评述, 最后对光纤化学传感器的未来进行展望。     

球磨法对不同基质上转换发光的影响

分别利用高温固相法和高能球磨法,在反应温度为1 100 ℃、反应时间为2 h的条件下合成了以Y₂O₃、La₂O₃、LiTaO₃为基质的双掺和三掺Tm³⁺、Er³⁺、Yb³⁺发光粉。XRD测试结果表明,高能球磨法制备的Y₂O₃、La₂O₃、LiTaO₃材料的相纯度高于高温固相法。用980 nm红外激光分别对两种合成方法制得的样品粉末进行发光性质的检测,结果表明高能球磨法制得样品的发光强度高于高温固相法样品。不同基质样品的上转换发光性质表现为：Tm³⁺、Yb³⁺掺杂呈蓝光;Er³⁺、Yb³⁺掺杂呈黄光;Tm³⁺、Er³⁺、Yb³⁺三掺样品的发光减弱,颜色可调。     

阴极荧光光谱有效收集效率的计算与测量（I）

从点光源均匀发光模型出发,重点导出了回转半椭球面镜的阴极荧光(Cathodoluminescence,简称CL)光谱有效收集效率η_λ~(eff)的计算公式,分析讨论了收集效率η_λ~(eff)与椭球参数e、收集角、Δφ出射角Δ(?)以及出射光束方位角θ_N的关系,给出了相应的理论计算和模拟实验结果.研究表明,理论计算与实验结果一致.     

Ce:KNSBN晶体中ps激光脉冲二波耦合的直接观察与记录

重复频率为82MHz的ps激光脉冲可在慢响应的光折变晶体Ce:KNSBN中实现二波耦合。本文报道用条纹照相机直接记录的实验结果并给出解释。 关键词：     

Linear analysis of degree correlations in complex networks

Many real-world networks such as the protein–protein interaction networks and metabolic networks often display nontrivial correlations between degrees of vertices connected by edges. Here, we analyse the statistical methods used usually to describe the degree correlation in the networks, and analytically give linear relation in the degree correlation. It provides a simple and interesting perspective on the analysis of the degree correlation in networks, which is usefully complementary to the existing methods for degree correlation in networks. Especially, the slope in the linear relation corresponds exactly to the degree correlation coefficient in networks, meaning that it can not only characterize the level of degree correlation in networks, but also reflects the speed that the average nearest neighbours’ degree varies with the vertex degree. Finally, we applied our results to several real-world networks, validating the conclusions of the linear analysis of degree correlation. We hope that the work in this paper can be helpful for further understanding the degree correlation in complex networks.     

射频等离子硫钝化GaAs(100)的表面特性

采用射频等离子方法,对Ga As(100)衬底片表面进行干法硫等离子体钝化,旨在得到性能稳定含硫钝化层。样品经过360℃温度条件下的快速热退火,光致发光(PL)测试表明,钝化后的样品PL强度上升了71%。同时,钝化样品的稳定性测试结果表明,样品放置在实验室空气中30 d,其PL强度未出现明显变化,说明Ga As的等离子体干法硫钝化具有较好的性能稳定性。     

Effect of Laser Cooling on Frequency Standard of Single Ca^＋ Ion Trapped in a Radio-Frequency Paul Trap

The source of systematic frequency shift of single-ion optical frequency standard of^40 Ca^＋ ion trapped in endcap trap and laser-cooled to a few of mK is analysed and calculated. Second-order Doppler shift, Stark shift due to micromotion and thermal motion, blackbody Stark shift and ac Stark shift are calculated for the ground state and excited 3d ^2D5/2 state. The Hertz-level measurement of the optical clock frequency in a single ^40Ca^＋ ion can be performed.     

自组装有机分子薄膜的可逆超高密度信息存储

信息技术的迅速发展对信息存储密度提出了越来越高的要求.采用自组装方法研究了有机分子4′-氰基-2, 6-二甲基-4-羟基偶氮苯 (4′-cyano-2,6-dimethyl-4-hydroxy azobenzene) 的成膜特性.通过在扫描隧道显微镜的针尖和基底之间加脉冲电压在薄膜上进行信息点的写入,得到了直径为1.8 nm的信息点,并分析了信息点形成的机理.     

Volume Effect of Bound States in Quark-Gluon Plasma

Bound states, such as qq and q(q), may exist in quark-gluon plasma. As the system is at high density,the volume of the bound states may evoke a reduction in the phase space. We introduce an extended bag model to investigate qualitatively the volume effect on the properties of the system. We find a limit temperature where the bound states start to be completely melted.     

基于OSLO的无限远像距消色差显微物镜的设计

共焦激光扫描显微镜对物镜有高分辨率、易于实现纵向扫描的要求,为此设计了高分辨率6片式无限远像距显微物镜.它的前置物镜与辅助物镜之间具有一段平行光路,因此容易实现轴向扫描.根据使用要求总体计算该物镜的外形尺寸,以像差理论为基础选择6片式的消色差物镜初始结构,用专业光学设计软件OSLO对物镜和辅助物镜进行设计和像质分析.设计结果显示,独特的6片式结构的20×物镜分辨率达到了800 lp/mm,符合共焦显微镜的使用要求.