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21.
Three-, two-, and one-dimensional disordered systems with randomly distributed, purely repulsive scattering centers, known as Lorentz models, are studied in the low energy limit [1]. Using a functional integral representation and a version of the “replica trick”, we have found in the D-dimensional system the density of electronic levels of the form and the constants b0, b1,…, bD, and γ have been determined. 相似文献
22.
The sorption and desorption isotherms of untreated calcareous soil and three treated soils to remove CaCO3, organic matter (OM) and both CaCO3 and OM were determined and analyzed with the Freundlich equation at pH 7.8, moderate concentrations of NpO2
+ (~10-5mol/l), in the presence of 0.01 mol/l CaCl2 and under ambient aerobic conditions. The relative contribution of CaCO3 and OM to the neptunium(V) sorption on calcareous soil and the sorption/desorption hysteresis is discussed. The effects of adding fulvic acid (FA) and carbonate in to the solution on the sorption of neptunium(V) on the soils were also studied. The sorption and desorption characteristics of NpO2
+, Zn2+, Sr2+ and Cs+ on the soils are compared. 相似文献
23.
Zhixian Zhou Yuzhong Wang Jingchao Tao Yaoting Fan Yangjie Wu 《Journal of inclusion phenomena and macrocyclic chemistry》1998,32(1):69-80
A novel anion-selective electrode has been prepared by usingtetraazaporphyrinogen as the electroactive component and o-nitrophenyloctylether as the plasticizer. The electrode exhibits almost Nernstian responsecharacteristics for Pic-, ReO
4
-
,SCN-, ClO
4
-
and TPB-. The linearresponse ranges towards the above-mentioned anions are 10-6 10-2, 10-5 10-2,10-5 10-2, 10-5 10-1, and 10-5 10-2mol/Land the corresponding slopes are -56.8, -57.1, -56.3, -56.1, and -59.9mV/decade with correlation coefficients of -0.99978, -0.99987, -0.99999,-0.99998, and -0.99998, respectively. The electrode shows an anti-Hofmeisterselectivity sequence: Pic- > SCN- >ReO
4
-
> ClO
4
-
> I- >Br- > BF
4
-
> Sal->NO
3
-
> Cl-. The unusual responsemechanism of the novel anion-selective electrode was investigated byexperimental observations and calculation with the MNDO method. Theelectrode was used as a TPB- and a Pic-sensitiveelectrode, respectively, and applied to the assay of levamisolehydrochloride tablets by potentiometric titration and Gran's methods. Theresults obtained are in excellent agreement with that determined by thestandard pharmacopoeia method based on nonaqueous titration. 相似文献
24.
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27.
We study the inhomogeneous deformation of a wedge of an incompressible generalized power-law Neo-Hookean material. We find solutions which have a boundary layer structure, in the sense that adjacent to the boundary the solution is inhomogeneous, while in the core region the solution is homogeneous. It is found that such solutions have an associated pressure field that is bounded. Inhomogeneous solutions are also possible when the pressure varies logarithmically with the radial coordinate. We also establish explicit exact solutions for specific values of the parameter. The results reduce to the Neo-Hookean solution when the power law exponent is set to unity. 相似文献
28.
Synthesis, Structure and Conductivity of the New Charge-transfer Salt (ET)_2(CH_2=CH-CH_2-SO_3)·H_2O
Zhi LIU Qi FANG* Wen Tao YU Min Hua JIANG De Qing ZHANG Dao Ben ZHU State Key Laboratory of Crystal Materials Shandong University Jinan Institute of Chemistry The Chinese Academy of Sciences Beijing 《中国化学快报》2003,14(4)
ET is one of the most famous electron-donor molecules, which forms charge-transfer complexes (abbr. CT-complexes) with various types of counterions. These complexes have received intense attention because a wide range of physical properties such as conductivity and superconductivity1, ferromagnetism2-4 and nonlinear optical properties5 was found in these materials. Although the majority of the ET-based CT-complexes were prepared by combining with inorganic counterions, CT-complexes with o… 相似文献
29.
30.
Tao Yu Xiaojie Jiang Xiaobo Xu Congyi Jiang Rui Kang Xiaobing Jiang 《Molecules (Basel, Switzerland)》2022,27(10)
Listeria monocytogenes is a major foodborne pathogen that can cause listeriosis in humans and animals. Andrographolide is known as a natural antibiotic and exhibits good antibacterial activity. We aimed to investigate the effect of andrographolide on two quorum-sensing (QS) systems, LuxS/AI-2 and Agr/AIP of L. monocytogenes, as well as QS-controlled phenotypes in this study. Our results showed that neither luxS expression nor AI-2 production was affected by andrographolide. Nevertheless, andrographolide significantly reduced the expression levels of the agr genes and the activity of the agr promoter P2. Results from the crystal violet staining method, confocal laser scanning microscopy (CLSM), and field emission scanning electron microscopy (FE-SEM) demonstrated that andrographolide remarkably inhibited the biofilm-forming ability of L. monocytogenes 10403S. The preformed biofilms were eradicated when exposed to andrographolide, and reduced surviving cells were also observed in treated biofilms. L. monocytogenes treated with andrographolide exhibited decreased ability to secrete LLO and adhere to and invade Caco-2 cells. Therefore, andrographolide is a potential QS inhibitor by targeting the Agr QS system to reduce biofilm formation and virulence of L. monocytogenes. 相似文献