全文获取类型
收费全文 | 90476篇 |
免费 | 26106篇 |
国内免费 | 23592篇 |
专业分类
化学 | 57837篇 |
晶体学 | 1850篇 |
力学 | 6234篇 |
综合类 | 979篇 |
数学 | 12235篇 |
物理学 | 61039篇 |
出版年
2024年 | 493篇 |
2023年 | 808篇 |
2022年 | 1286篇 |
2021年 | 1149篇 |
2020年 | 1345篇 |
2019年 | 1892篇 |
2018年 | 1845篇 |
2017年 | 2773篇 |
2016年 | 2573篇 |
2015年 | 3077篇 |
2014年 | 3154篇 |
2013年 | 5090篇 |
2012年 | 5469篇 |
2011年 | 7171篇 |
2010年 | 10615篇 |
2009年 | 11095篇 |
2008年 | 5101篇 |
2007年 | 4383篇 |
2006年 | 3990篇 |
2005年 | 4136篇 |
2004年 | 4730篇 |
2003年 | 3699篇 |
2002年 | 3592篇 |
2001年 | 3878篇 |
2000年 | 3206篇 |
1999年 | 3029篇 |
1998年 | 2371篇 |
1997年 | 2088篇 |
1996年 | 2392篇 |
1995年 | 2856篇 |
1994年 | 2910篇 |
1993年 | 2989篇 |
1992年 | 2563篇 |
1991年 | 2162篇 |
1990年 | 1834篇 |
1989年 | 1938篇 |
1988年 | 1928篇 |
1987年 | 1191篇 |
1986年 | 1235篇 |
1985年 | 885篇 |
1984年 | 1013篇 |
1982年 | 918篇 |
1981年 | 756篇 |
1980年 | 779篇 |
1979年 | 547篇 |
1978年 | 539篇 |
1977年 | 637篇 |
1976年 | 1044篇 |
1972年 | 532篇 |
1971年 | 436篇 |
排序方式: 共有10000条查询结果,搜索用时 46 毫秒
931.
IR spectra of propylene and acrolein adsorbed at different temperatures on CoMoO4 supported on MgO were recorded. Four different surface species were found: a -complex, an oxygen bonded carbonyl complex, acrylic acid and a carboxylate type complex. The mechanism of their transoformation is discussed.
- CoMoO4 MgO. , 4 : -, , , . .相似文献
932.
The catalytic activity of BeO for the double bond shift of 1-pentene has been investigated. The maximum activity was exhibited by samples calcined at 1173 K. The effect of pyridine, CO2 and CCl4 on the activity was also studied. Lewis acid-base site pairs appear to be active for the isomerization.
BeO 1- . , 1173 . , CO2 CCl4 . - .相似文献
933.
环氧丙烯酸酯的紫外光固化 总被引:8,自引:0,他引:8
制备了适于配制紫外光固化涂料的环氧丙烯酸酯,研究了反应温度、阻聚剂、催化剂等因素对环氧树脂与丙烯酸反应的影响;讨论了反应机理和动力学;并利用红外光谱观察了产物的紫外光固化行为。季铵盐能有效地催化环氧树脂和丙烯酸的反应,当其用量为0.6%~1.2%时,在90~110℃反应4.5~8小时后,环氧基转化率大于97%。由此配制的光固化涂料经紫外光辐照能快速固化。 相似文献
934.
C. Caro Gamez P. Valiente González M. Jiménez Arrabal V. López-Arza Moreno A. Sanchéz Misiego 《Fresenius' Journal of Analytical Chemistry》1991,340(3):169-172
Summary A spectrophotometric study has been carried out of the violet complex 3-indole-acetohydroxamic acid-vanadium extracted into a solution of trioctylmethyl-ammonium chloride in toluene [max 525 nm; =5381 l mol–1 cm–1; stoichiometry 1:3 (metal:reagent)]. A new method for the extract-spectrophotometric determination of V5+ in the range of 2–7 g/g is proposed and interferences by foreign ions were investigated. The method has been satisfactorily applied to the determination of vanadium(V) in fuel oil. The relative error is ±2.9%. 相似文献
935.
M. A. Agzamova M. I. Isaev M. B. Gorovits N. K. Abubakirov 《Chemistry of Natural Compounds》1988,23(6):696-700
A bisdesmosidic glycoside — cycloorbicoside G — has been isolated from the epigeal parts of the plantAstragalus orbiculatus Ledeb. (Leguminosae), and on the basis of chemical transformations and spectral characteristics its structure has been established as (23R,24S)-16,23;16,24-diepoxycycloartane-3,7,25-triol 25-O--D-glucopyranoside 3-O--D-xylopyranoside.Institute of the Chemistry of Plant Substances, Uzbek SSR Academy of Sciences, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 837–842, November–December, 1987. 相似文献
936.
937.
938.
The hydrothermal reaction of VOSO4, As2O3, CoC2O4·2H2O and 2,2-bipy yields a novel arsenic-vanadate [CoII(2,2-bpy)2]2[AsIII8VIV 14O42(H2O)]·H2O (1), which is characterized by IR, elemental analysis, TGA, magnetic susceptibility and single crystal X-ray diffraction analysis. X-ray diffraction shows that compound 1 is the first example of tubular arsenic–vanadium cluster containing infinite {[Co(2,2-bpy)2]2[As8V14O42(H2O)]} chain constructed from [As8V14O42(H2O)] clusters interconnected through [Co(2,2-bpy)]2+ units. Crystal data: 1, orthorhombic, P 212121, a=12.1401(2) Å, b=15.8722(1) Å, c=39.9533(5) Å, Z=4.Graphical Abstract: A novel polyoxoarsenicvanadate, [CoII(2,2-bipy)2]2 [AsIII8VIV 14O42(H2O)]·H2O, is depicted along with a tubular hybrid solid with a rhombic tube formed within the chain. 相似文献
939.
HUANG Ru-dan ** LI Juan ZHANG Jing . Department of Chemistry School of Science Beijing Institute of Technology Beijing P. R. China . Key Laboratory of Rare Earth Chemistry Physics Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchun P. R. China . Department of Chemistry Normal College Beihua University Jilin P. R. China 《高等学校化学研究》2005,(1)
IntroductionChirality is ubiquitous in the nature.Chiralcompounds have many applications in the areas ofmedicine,catalysis and materials,etc. Polyox-ometallates are inorganic polymers,which have at-tracted much interest since they have electri-cal[1_ 3 ] ,magnetic[4] ,optical properties[5_ 7] ,andsome characters as liquid crystals[8,9] .In this workwe report theα- Keggin structural polyoxometallatenanoparticles with optical activities.The opticalactivities of the samples are [α]13 D =+ 1 7… 相似文献
940.
In the process of ion-induced CO adsorption (Ar+, 4 keV, 4 A/cm2) on polycrystalline Ni at room temperature and P=(1–40)×10–6 Pa the emission of Ni+, NiCO+, CO+, NiO+ and C+ ions is observed. The emission of the last three ions is due to the ion-stimulated dissociation of weakly bound CO state and NiO formation. The weakly bound state is formed owing to surface defects produced by ion bombardment. The cross sections of the ion-induced desorption are 1.8 and 0.8×10–14 cm2, respectively, for weakly bound and strongly bound states. 相似文献