2H NMR spectra of 2-(p-heptylbenzoyloxy)-5-(p-heptylbenzenazo)tropone. A new sigmatropic liquid crystal

Liquid crystals incorporating in their molecular framework a seven-membered ring are still relatively rare [1]. Recently the synthesis and thermal behaviour of a series of liquid crystal materials having a tropone moiety in their mesogenic core have been reported [2-4]. These mesogens, based on a 2-(acyloxy)tropone core structure, show intramolecular migration of the acyl substituents between the two oxygen atoms at C-1 and C-2, an effect already known for simple 2-(acyloxy)tropones in their isotropic solutions [5]. This migration involves a concerted [1, 9]-sigmatropic rearrangement [2]. This rearrangement could play a major role in determining the properties of the mesophases: it has been suggested in fact that, because of this rearrangement, the mesogenic molecules acquire a mean rod-like shape which can sustain the mesophase formation [2].     

Numerical solution of the electron distribution function for ECRheating in magnetic mirror

The Fokker-Planck equation is solved with electron cyclotron resonance heating in a magnetic mirror with a fixed electrostatic potential on a loss-cone boundary and ECR heating. A self-consistent calculation of the plasma concentration justifies the fact that the degree of ionization of the ECR plasma is about 10%. The high values of the total electron energy (15-30 eV) are achieved. The electron concentration and the EVDF anisotropy degree are the nonmonotonic functions of the applied MW electric field. The basis for such dependencies is discussed. A linear perturbation analysis of the Vlasov equation together with with Maxwell's equations is briefly reviewed. The criteria for the start of unstable whistler oscillation growth are proposed. Using the simulated distribution function, the regimes where the unstable oscillations should to be taken into account are considered     

Measurement of the spin and temperature dependence of ddµ molecule formation rate in solid and liquid deuterium

The ddµ molecule formation rate is experimentally measured for the two hyperfine states of the dµ-atom in the temperature range of 5–30 K. Results are consistent with a preliminary measurement by the TRIUMF group and contradict theoretical predictions. The work has been performed on the JINR phasotron (Dubna).     

On the solvability of physically nonlinear problems of Thermoelasticity

We study the problem of existence and uniqueness of generalized solutions of nonlinear vector boundary-value problems arising in the physically nonlinear theory of thermoelasticity. We prove the convergence of iteration processes in the space W ¹ ₂.     

Ions and atoms in superfluid helium (4He)

We review the previous conclusion [J.Y. Ryu, Y.C. Chung and S.D. Choi, Phys. Rev. B 32, 7769 (1984)] that the trace property Tr(ABC) = Tr(CAB) leads to two different cyclotron transition absorption formulae in the electron-phonon systems in the lowest order approximation. The pictorial expression and the calculated linewidths in Ge and Si show that the socalled EWC scheme is more seeming than the socalled MWC scheme. The difference is expected to disappear if we take into account all the higher order perturbation terms or start with the many body formalism in the complete scheme.     

Modeling of heat transfer in a melt in growing single crystals by the stockbarger method using the accelerated crucible rotation technique (ACRT)

In model experiments, the layer of melt bounded by the crystallization front and the heater for heating the diaphragm in a growing furnace is shown to determine crystal growth by the Stockbarger method under conditions of induced convection and also to control the crystallization process. The free volume of the melt exerts no effect on its hydrodynamic and thermal structures. Optimum values of the exposure time are estimated for constant maximum and minimum velocities of modulated rotation of the growing ampoule. Institute of Mineralogy and Petrography, Siberian Division, Russian Academy of Sciences, Novosibirsk 630090. Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 39, No. 1, pp. 98–104, January–February, 1998.     

Phenomenological model of creep under variable loads

Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, No. 4, pp. 123–127, July–August, 1993.