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181.
O. V. Koryakova V. V. Sattarova D. V. Sevenard O. G. Khomutov K. I. Pashkevich 《Russian Journal of General Chemistry》2003,73(1):141-144
The tautomeric equilibrium in substituted 5,6,7,8-tetrahydroquinazolines was studied by IR spectroscopy. The effect of various substitutents in the pyrimidine ring and the solvent on the state of the tautomeric equilibrium was evaluated. 相似文献
182.
G. C. Psarras 《Journal of Polymer Science.Polymer Physics》2007,45(18):2535-2545
The charge transport properties of polymer matrix–carbon black composites are investigated in this study. Direct current conductivity is examined with varying parameters: the temperature and the conductive filler content. Conductivity data are analyzed by means of percolation theory, and both percolation threshold and critical exponent are determined at each of the examined temperatures. The temperature dependence of conductivity and the agreement of experimental results with the variable range hopping model reveal hopping conduction as the predominant transport mechanism, below and in the vicinity of the critical concentration of carbon black particles. At higher concentrations, the contribution of hopping transport to the overall conductivity is reduced and a balance between hopping and conduction via geometrical contact occurs. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2535–2545, 2007 相似文献
183.
C. Czeranowsky V. M. Baev G. Huber P. A. Khandokhin Ya. I. Khanin I. V. Koryukin E. Yu. Shirokov 《Radiophysics and Quantum Electronics》2004,47(10-11):723-728
Experimental study of low-frequency dynamics of an intracavity frequency-doubled Nd:YAG laser demonstrates the influence of the interaction of orthogonally polarized modes, participating in frequency doubling (type II phase matching), on the stability of the laser output. At a sufficiently low pump rate and low conversion efficiency, the laser shows stable operation with a low noise level at the frequencies of relaxation oscillations. At a high pump power and/or a high conversion efficiency, the laser emission becomes unstable as a result of Hopf bifurcation at the frequencies of relaxation oscillations that are responsible for the anti-phase polarization dynamics of the laser. 相似文献
184.
A brief account of applications of polarized inelastic neutron scattering in condensed matter research is given. We show that
full polarization analysis is the only tool allowing to discriminate unambiguously between different magnetic modes in various
magnetic materials. We show by means of recent results in the Heisenberg ferromagnet EuS that the effects of dipolar interactions
can be studied on a microscopic scale. Moreover, we have found for the first time indications for the divergence of the longitudinal
fluctuations belowT
c. In the itinerant antiferromagnet chromium we demonstrate that the dynamics of the longitudinal and transverse excitations
are very different, resolving a long standing puzzle concerning the slope of their dispersion. Finally, we show that a measurement
of the polarization-dependent part of the cross section of non-centrosymmetric MnSi proves directly that the chirality of
the magnetic fluctuations is left-handed. 相似文献
185.
Porous silicon (PS) exhibits several photoluminescence (PL) bands, whose spectral position and intensity depend strongly on the actual conditions of preparation of PS, its treatment, and subsequent use. The PS PL band peaking at about 1.8 eV and usually assigned to the intrinsic emission of silicon nanocrystals was studied. It was shown that the temperature-induced variation of the PL kinetics in the 80 to 300-K interval follows a complex pattern and depends noticeably on the actual point on the band profile. The temperature behavior of PL decay in the 1.8-eV band is determined by the electron-hole recombination rate within a nanocrystal and the cascade carrier transitions from small to large nanocrystals, with an attendant decrease in energy. 相似文献
186.
Vinod Kumar Pragya Das R.P. Singh S. Muralithar R.K. Bhowmik 《The European Physical Journal A - Hadrons and Nuclei》2003,17(2):153-157
The fusion evaporation reaction 122Sn(14N, 4n)132La was used to populate the high-spin states of 132La at the beam energy of 60 MeV. A new band consisting of mostly E2 transitions has been discovered. This band has the interesting links to the ground state 2- and the isomeric state 6-. A new transition of energy 351 keV connecting the low-spin states of the positive-parity band based on the πh
11/2 ⊗ νh
11/2 particle configuration, has been found. This has played a very important role in resolving the existing ambiguities and inconsistencies
in the spin assignment of the band head.
Received: 12 August 2002 / Accepted: 18 March 2003 / Published online: 7 May 2003 相似文献
187.
M. D. Srinivas 《Pramana》2003,60(6):1137-1152
We derive an optimal bound on the sum of entropic uncertainties of two or more observables when they are sequentially measured
on the same ensemble of systems. This optimal bound is shown to be greater than or equal to the bounds derived in the literature
on the sum of entropie uncertainties of two observables which are measured on distinct but identically prepared ensembles
of systems. In the case of a two-dimensional Hilbert space, the optimum bound for successive measurements of two-spin components,
is seen to be strictly greater than the optimal bound for the case when they are measured on distinct ensembles, except when
the spin components are mutually parallel or perpendicular 相似文献
188.
For the decay of two identical particles with close momenta, the angular correlations between the directions of emission of decay products are considered on the basis of the model of independent single-particle sources emitting unstable unpolarized particles of nonzero spin. These correlations reflect spin correlations that are caused by quantum-statistics and final-state-interaction effects. A general theory of angular correlations in the decays of two arbitrarily polarized particles (resonances) is constructed. 相似文献
189.
190.
Nickel complexes 1–4 ligated with 2,9-disubstituted-1,10-phenanthroline were synthesized and characterized by FT-IR spectra and elemental analysis.
The molecular structure of complex 2 was confirmed by X-ray crystal diffraction analysis. Activated with methylaluminoxane (MAO), those complexes showed moderate
activities for ethylene oligomerization.
Published in Kinetika i Kataliz, 2007, Vol. 48, No. 5, pp. 710–714.
This article was submitted by the authors in English. 相似文献