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961.
The synthesis of a specific isotopomer, C6D4H(ortho)-H(ortho)D4C6 of biphenyl is reported. The intramolecular dipolar coupling of the protons leads to a well-resolved single-crystal proton
nuclear magnetic resonance (NMR) spectrum and allows one to study the dynamics of the phenyl rings in a unique way. At room
temperature and above, the most conspicuous dynamical mode consists of 180° ring flips. The present data together with previous
measurements of the total flip rate allow us to conclude that the rings flip almost exclusively independently of each other.
Between the incommensurate (IC) phase transition of biphenyl at 38 K andT=250 K, the prominent namical mode consists of oscillatory twists ϕ(t) of the two rings. The data allow us to infer the mean square, (φ2), of these twists. (φ2) is found to grow linearly withT for 50<T<200 K. From the slope of (φ2) vs.T the frequency (the wave number[(v)\tilde]\tilde v) is derived. The result is[(v)\tilde] = 20\tilde v = 20 cm−1. ForT<38 K, the spectra give direct evidence of the IC phase transition and its nature (stripelike rather than quiltlike). The
temperature dependence of the magnitude of the order parameter of the IC phase is obtained. 相似文献
962.
Positron-lifetime experiments have been carried out on two undoped n-type liquid encapsulated Czochralski (LEC)-grown InP samples with different stoichiometric compositions in the temperature range 10-300 K. For temperatures below 120 K for P-rich InP and 100 K for In-rich InP, the positron average lifetime began to increase rapidly and then leveled off, which was associated with the charge state change of hydrogen indium vacancy complexes from (VInH4)+ to (VInH4)0. This phenomenon was more obvious in P-rich samples that have a higher concentration of VInH4. The transformation temperature of approximately 120 K suggests that the complex VInH4 is a donor defect and that the ionization energy is about 0.01 eV. The ionization of neutral VInH4 accounted for the decrease of the positron average lifetime when the sample was illuminated with a photon energy of 1.32 eV at 70 K. These results provide evidence for hydrogen complex defects in undoped LEC InP. 相似文献
963.
The study of the angular distribution of slow particles during high energy hadron-nucleus interaction indicates that emission of slow particles takes place from a thermally non-equilibrated system. This evidence has come out from the presence of intermittency - a phenomenon that reveals a fractal structure and represents a self-similarity in the particle production process. Hence, this study highlights inadequacy of cascade-evaporation model and advocates the need of its refinement. 相似文献
964.
Harper equations are derived for a px, py electronic system. Analysis is carried out for extreme points of the quasi-continuous spectrum in the cases when the number of magnetic flux quanta through a unit cell is a rational number and calculations are made for square and triangular lattices as well as for a honeycomb lattice with two nonequivalent atoms. The possibility of application of the results for explaining the fractional Hall effect is considered. 相似文献
965.
O. Wibbelhoff C. Meier A. Lorke P. Schafmeister A. D. Wieck 《Physica E: Low-dimensional Systems and Nanostructures》2004,21(2-4):516
We use frequency-dependent capacitance–voltage spectroscopy to study the dynamic charging of self-assembled InAs quantum dots. With increasing frequency, the AC charging becomes suppressed, beginning with the low-energy states. By applying an in-plane magnetic field, we generate an additional magnetic confinement that alters the tunneling barrier and hence the charging dynamics. In traveling through the potential barrier, the electrons acquire an additional momentum k0, proportional to the magnetic field B. As the tunneling is enhanced, when k0 matches the maximum of the electronic wave function Ψ (in momentum representation), we are able to map out the shape of Ψ by varying B. 相似文献
966.
967.
Maria G. Semenova Larisa E. Belyakova Anna S. Antipova Yu. N. Polikarpov Lida Klouda Anna Markovic Michael M. Il'in 《Colloids and surfaces. B, Biointerfaces》2003,31(1-4):47-54
We report on the effect of commercially important polysaccharides (maltodextrins with variable dextrose equivalent (Paselli SA-2, MD-6 and MD-10) on the surface activity at the air–water interface of small-molecule surfactants (sms), possessing different hydrophobic–lipophilic balance ((SSL (Na+), the main component is a sodium salt of stearol–lactoyl lactic acid, and PGE (080), polyglycerol ester of C18 fatty acid), and widely used in food products. A marked change of the surface activity of sms was found in the presence of maltodextrins by tensiometry. The combined data of laser multiangle light scattering and mixing calorimetry have suggested that this result is governed by specific complex formation between maltodextrins and sms in aqueous medium. Measurements have been made of the molar mass, the second virial coefficient and the enthalpy of intermolecular interactions in aqueous solutions. The implication of a degree of polymerization of maltodextrins in this phenomenon was shown. The interrelation between the molecular parameters of the formed complexes and their surface activity at the air–water interface has been revealed and discussed. 相似文献
968.
V. P. Shilov 《Journal of Experimental and Theoretical Physics》2003,96(4):719-729
The supercritical Marangoni convection has been studied in a plane-parallel liquid layer, bounded by a free deformable gas-liquid interface from above and by a low-heat-conductivity wall from below, occurring under conditions of inhomogeneous heating in the horizontal plane. In a longwave approximation with a small inhomogeneity of heat flux, the process is described by a system of two-dimensional nonlinear equations for the temperature perturbations, vorticity, and free surface deformation. The concept of quasiequilibrium, implying stability of long-range flows, is introduced, which allows the inhomogeneous heat flux to be modeled by a step function. The linear stability is analyzed in the cases of planar and axisymmetric heat fluxes. The boundaries of stability of the convection regimes are determined on the plane of parameters characterizing the degree of supercriticity inside a heated spot and the depth of damping outside the spot. For an axisymmetric spot, the domains of stability with respect to perturbations for various azimuthal numbers are established. 相似文献
969.
D. Chithrani R. L. Williams J. Lefebvre P. J. Poole G. C. Aers 《Physica E: Low-dimensional Systems and Nanostructures》2004,21(2-4):290
We discuss the preparation and spectroscopic characterisation of a single InAs/InP quantum dot suitable for long-distance quantum key distribution applications around λ=1.55 μm. The dot is prepared using a site-selective growth technique which allows a single dot to be deposited in isolation at a controlled spatial location. Micro-photoluminescence measurements as a function of exciton occupation are used to determine the electronic structure of the dot. Biexciton emission, shell filling and many-body re-normalization effects are observed for the first time in single InAs/InP quantum dots. 相似文献
970.