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961.
The fluorescence dynamics parameters of the fluorescent transient flavin-luciferase species from the typesVibrio fischeri andPhotobacterium leiognathi are presented. The fluorescence anisotropy decay is a single exponential function for both types. The correlation time is 70 ns for theP. leiognathi fluorescent transient intermediate (2°C, aqueous buffer, pH 7.0), consistent with the rotational correlation time of the luciferase macromolecule (77 kD) to which the flavin fluorophore is rigidly attached. In contrast, for theV. fischeri species the observed correlation time for the anisotropy decay function is 133 ns. This suggests that protein self-association occurs in theV. fischeri case and this is confirmed by filtration, where the fluorescent transient fromV. fischeri does not pass through a 100,000 molecular weight cutoff membrane, whereas theP. leiognathi species does. The filtration method also demonstrates self-association in the luciferase peroxyflavin and photoflavin fromV. fischeri. A monomer-dimer equilibrium also explains the previously reported high correlation times for theV. harveyi luciferase-flavin species. It is proposed that the self-association competes with the lumazine protein interaction in the bioluminescence reaction. 相似文献
962.
A two-dimensional self consistent model of the Beam-Plasma-Discharge (BPD) has been developed to calculate the discharge ignition of a bandlike electron beam in a discharge chamber. The discharge was considered in Argon with an initial concentration of 1014 cm?3. The model allows calculation of the time evolution of perpendicular profiles of electron density, temperature and the potential. 相似文献
963.
V. Formisano G. Bellucci A. Grigoriev A. Coradini J. P. Bibring 《Il Nuovo Cimento C》1992,15(6):1113-1119
Summary Multispectral imaging of planets opens a new class of studies of atmospheric and surface signatures. With ISM experiment on
board Phobos, the first IR multispectral imaging of Mars from space was achieved. In viem of the Future Omega experiment on
board Mars 94, we present here a sample of data and results (and problems) which can be achieved by studying spectral reflectance.
Paper presented at the V Cosmic Physics National Conference, S. Miniato, November 27–30, 1990. 相似文献
964.
Risk analysis tools have been used to help manage various projects. This paper describes a case study in which an extension to the stochastic project network model was developed for a risk analysis of an oil platform installation, quantifying the possible impact of the weather on the project's schedule. Examination of the weather data suggested the use of a Markov weather model combined with a separate residence time distribution for key states. The weather model was incorporated into the stochastic project network allowing the interactions of the various project uncertainties to be examined. While the weather introduced a significant additional risk to the project, analysis of management's options indicated that much of the risk might be avoided. In particular, the analysis quantified the benefits of scheduling the project start to take advantage of the seasonal variations and hiring heavy duty equipment to operate in more arduous conditions. 相似文献
965.
S. G. Charati A. Y. Houde S. S. Kulkarni M. G. Kulkarni 《Journal of Polymer Science.Polymer Physics》1991,29(8):921-931
Polymer packing density can be conveniently measured by either density-based measurements (direct or estimated free volume) or wide-angle X-ray diffraction (WAXD) spectra. Previously reported diffusivity and permeability values for various polyarylates and polyimides are examined on the basis of the packing density measured by these different techniques. It is shown that in these rigid glassy polymers, the mean intersegmental distance, the d-spacing, obtained from WAXD provides a better measure of the effect of polymer packing on diffusivity than either direct density measurements or estimated free volumes. It has been possible to correlate previously reported diffusivity and sorption data for various polyarylates and polycarbonate on the basis of the WAXD investigation, using the d-spacing and the amorphous peak width, respectively. The effect of polyarylate structure on d-spacing has been studied. A series of polyarylates have been synthesized with different substituents on the bridge carbon. In this series the d-spacing remains constant while the carbonyl group density and the glass transition temperatures are varied. However, small substituents on the aromatic ring cause significant changes in the d-spacing. These results can be used to tailor polyarylates with desired intersegmental distances and chain flexibility. 相似文献
966.
Donald G. Truhlar 《Journal of computational chemistry》1991,12(2):266-270
A simple formula is presented for calculating the approximate partition function of a hindered internal rotational mode of a polyatomic molecule. The formula gives useful accuracy over the whole range from harmonic oscillator to hindered rotator to free rotator. 相似文献
967.
A. Ross M. Czisch G.C. King 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1997,124(2):355-365
A theoretical approach to calculate the time evolution of magnetization during a CPMG pulse sequence of arbitrary parameter settings is developed and verified by experiment. The analysis reveals that off-resonance effects can cause systematic reductions in measured peak amplitudes that commonly lie in the range 5–25%, reaching 50% in unfavorable circumstances. These errors, which are finely dependent upon frequency offset and CPMG parameter settings, are subsequently transferred into erroneousT2values obtained by curve fitting, where they are reduced or amplified depending upon the magnitude of the relaxation time. Subsequent transfer to Lipari–Szabo model analysis can produce significant errors in derived motional parameters, with τeinternal correlation times being affected somewhat more thanS2order parameters. A hazard of this off-resonance phenomenon is its oscillatory nature, so that strongly affected and unaffected signals can be found at various frequencies within a CPMG spectrum. Methods for the reduction of the systematic error are discussed. Relaxation studies on biomolecules, especially at high field strengths, should take account of potential off-resonance contributions. 相似文献
968.
An acoustic pulse propagating on a two-mode fiber can act as a beam splitter in a scanning interferometer. When this device
is employed in white-light interferometry, the effects of distributed coupling and dispersive interferometer arms need to
be considered. A theory suitable for treating acousto-optic interaction of partially coherent light in a moving interaction
region was developed. It was found that differential optical dispersion should be negligible and the acoustic pulse length
short. Also the coherence time should be short but long compared to the intermodal group delay difference over a pulse length.
Experiments with long acoustic pulses were performed, and fairly good agreement with theory was obtained. 相似文献
969.
A new formalism is presented for the theory of scanning LLL x-ray interferometry, which takes account also of the amount of x-ray absorption and of crystal yawing. It is based on the Takagi approach to the dynamical theory of x-ray diffraction and uses, to a great extent, the formalism of quantum mechanics, in order to reduce the algebraic complexity of the Ewald-von Laue approach. The formalism presented here is an easy-to-handle tool for the study of x-ray propagation in multicrystal systems and for the investigation into deviations of the travelling-fringe period from the spacing of diffracting planes, as it explains how interference features change when moving in paramater space. 相似文献
970.
Two extensions of the univariate Gini index are considered:RD, based on expected distance between two independent vectors from the same distribution with finite meanμ
d; andRV, related to the expected volume of the simplex formed fromd+1 independent such vectors. A new characterization ofRDas proportional to a univariate Gini index for a particular linear combination of attributes relates it to the Lorenz zonoid. TheLorenz zonoidwas suggested as a multivariate generalization of the Lorenz curve.RVis, up to scaling, the volume of the Lorenz zonoid plus a unit cube of full dimension. Whend=1, bothRDandRVequal twice the area between the usual Lorenz curve and the line of zero disparity. Whend>1, they are different, but inherit properties of the univariate Gini index and are related via the Lorenz zonoid:RDis proportional to the average of the areas of some two-dimensioned projections of the lift zonoid, whileRVis the average of the volumes of projections of the Lorenz zonoid over all coordinate subspaces. 相似文献