全文获取类型
收费全文 | 307848篇 |
免费 | 3724篇 |
国内免费 | 646篇 |
专业分类
化学 | 166370篇 |
晶体学 | 4381篇 |
力学 | 12588篇 |
综合类 | 10篇 |
数学 | 37653篇 |
物理学 | 91216篇 |
出版年
2020年 | 2672篇 |
2019年 | 2844篇 |
2018年 | 3953篇 |
2017年 | 3885篇 |
2016年 | 5982篇 |
2015年 | 3898篇 |
2014年 | 5469篇 |
2013年 | 13373篇 |
2012年 | 10529篇 |
2011年 | 12199篇 |
2010年 | 8641篇 |
2009年 | 8192篇 |
2008年 | 11377篇 |
2007年 | 11345篇 |
2006年 | 10521篇 |
2005年 | 9746篇 |
2004年 | 8878篇 |
2003年 | 7916篇 |
2002年 | 7716篇 |
2001年 | 8073篇 |
2000年 | 6447篇 |
1999年 | 4926篇 |
1998年 | 4313篇 |
1997年 | 4215篇 |
1996年 | 4104篇 |
1995年 | 3690篇 |
1994年 | 3933篇 |
1993年 | 3606篇 |
1992年 | 4084篇 |
1991年 | 4032篇 |
1990年 | 3995篇 |
1989年 | 3784篇 |
1988年 | 3889篇 |
1987年 | 3759篇 |
1986年 | 3581篇 |
1985年 | 4757篇 |
1984年 | 4970篇 |
1983年 | 4158篇 |
1982年 | 4295篇 |
1981年 | 4228篇 |
1980年 | 4166篇 |
1979年 | 4132篇 |
1978年 | 4429篇 |
1977年 | 4334篇 |
1976年 | 4414篇 |
1975年 | 4062篇 |
1974年 | 4113篇 |
1973年 | 4286篇 |
1972年 | 2989篇 |
1971年 | 2488篇 |
排序方式: 共有10000条查询结果,搜索用时 203 毫秒
991.
Athanassios G. Bratsos 《Numerical Algorithms》2007,46(1):45-58
A predictor–corrector (P-C) scheme is applied successfully to a nonlinear method arising from the use of rational approximants
to the matrix-exponential term in a three-time level recurrence relation. The resulting nonlinear finite-difference scheme,
which is analyzed for local truncation error and stability, is solved using a P-C scheme, in which the predictor and the corrector
are explicit schemes of order 2. This scheme is accelerated by using a modification (MPC) in which the already evaluated values
are used for the corrector. The behaviour of the P-C/MPC schemes is tested numerically on the Boussinesq equation already
known from the bibliography free of boundary conditions. The numerical results are derived for both the bad and the good Boussinesq
equation and conclusions from the relevant known results are derived.
相似文献
992.
Bernhard G. Bodmann Vern I. Paulsen Soha A. Abdulbaki 《Journal of Fourier Analysis and Applications》2007,13(3):285-307
We study the performance of finite frames for the encoding of vectors by applying standard higher-order sigma-delta quantization
to the frame coefficients. Our results are valid for any quantizer with accuracy ε > 0 operating in the no-overload regime.
The frames under consideration are obtained from regular sampling of a path in a Hilbert space. In order to achieve error
bounds that are comparable to results on higher-order sigma-delta for the quantization of oversampled bandlimited functions,
we construct frame paths that terminate smoothly in the zero vector, that is, with an appropriate number of vanishing derivatives
at the endpoint. 相似文献
993.
In this paper we consider a class of nonlinear delay partial difference equations and a class of linear delay partial difference equations with variable coefficients, which may change sign. We obtain oscillation criteria for these equations. There are no results for the oscillation of these equations up to now. 相似文献
994.
A. V. Govorkov A. Ya. Polyakov T. G. Yugova N. B. Smirnov E. A. Petrova M. V. Mezhennyi A. V. Markov I. -H. Lee S. J. Pearton 《Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques》2007,1(4):380-385
The relation between the density of etch pits revealed in GaN by etching in a KOH/NaOH eutectic and the density of dislocations determined by transmission electron microscopy (TEM) is studied along with the relation between the density of dislocations and the density of dark spot defects observed in GaN by microcathodoluminescence (MCL) and electron-beam-induced current (EBIC). It is demonstrated that selective etching is a reliable rapid method for the determination of the type and density of dislocations in GaN in the range 106–108 cm?2, while MCL and EBIC can be used for the rapid nondestructive determination of the density of dislocations in the range 106–108 cm?2. It is also found that some deep electron and hole traps are related to dislocations. 相似文献
995.
A. S. Parshin G. A. Aleksandrova S. N. Varnakov S. A. Kushchenkov S. G. Ovchinnikov 《Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques》2007,1(4):462-465
The results of studying Fe/Si and Si/Fe layered structures with different thicknesses of the top layer by reflected electron energy loss spectroscopy are presented. A new method is proposed for the estimation of volume fractions of components in binary systems within the framework of the effective dielectric medium model. 相似文献
996.
P. V. Ivannikov N. S. Chekalin P. A. Miroshnikov G. V. Saparin A. A. Altukhov A. V. Shustrov 《Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques》2007,1(4):386-393
Surfaces of natural type-IIa diamond plates used in ionizing-radiation detectors are studied in a scanning electron microscope using techniques of electron-beam-induced conductivity at different bias voltages and real-color cathodoluminescence. 相似文献
997.
998.
E. Beinrohr M. Németh P. Tsch?pel G. T?lg 《Fresenius' Journal of Analytical Chemistry》1992,344(3):93-99
Summary Flow-through electrochemical cells with porous working electrodes made of crushed reticulated vitreous carbon and plated with mercury were used for absolute analysis of trace amounts of lead by anodic stripping coulometry with collection (ASCWC) in a flow system. The role of mercury coating, flow rate and pH were investigated. The coulombic content of the collection peak corresponded to the theoretical values calculated by Faraday's law in a concentration range from about 10–9 to 10–6 mol/l. The relative error and the relative standard deviation was +0.15% and 0.8%, respectively for 2×10–6 mol/l analyte concentration. The absolute detection limit (3 s) was 0.1 ng of Pb, the linear response range 7×104.
One leave from: Department of Analytical Chemistry, Slovak Technical University, CS-812 37 Bratislava, Czechoslovakia 相似文献
999.
G M Beijersbergen van Henegouwen 《Journal of photochemistry and photobiology. B, Biology》1991,10(3):183-210
Xenobiotics extensively used in drugs, cosmetics, food and agricultural chemicals can produce adverse biological effects. These toxic effects are separated into classes, e.g. hepatotoxicity, genotoxicity and neurotoxicity. Skin allergy, part of immunotoxicity, is also a subdivision of toxicology. When light is an essential condition for toxicity, the xenobiotic is called phototoxic. Thus it fits into the logic of toxicology that photoallergic compounds are a subdivision of phototoxic compounds. Phototoxicons as a group do not differ from the group of phototherapeutics with regard to their eventual biological effects. The primary photoreactions, secondary molecular processes, biomolecules involved and cellular and tissue damage are similar. The difference between the two groups is in the appreciation of the photobiological effects: adverse vs. desired. The aim of research is to determine the part of the molecular structure which makes a given compound phototoxic. With that knowledge the structure of the phototoxicon can be changed. This can result in a derivative which still has the desired properties of the parent compound, but is no longer phototoxic. This aim can be reached by combining data from both in vitro and in vivo research. The variety and number of phototoxic compounds is large. This, together with the limited research effort devoted to this subject so far, means that for most phototoxic xenobiotics a relationship between structure and in vivo photoreactivity is not available. In this review, emphasis is placed on xenobiotics whose in vitro and in vivo photochemistry have been studied. Furthermore, possible phototoxic effects which do not concern the skin but involve inner organs (systemic effects) are considered. References in this review mostly concern investigations over the last 10 years. For older literature or for additional information, references to other reviews are given. Important groups of phototoxic xenobiotics not dealt with in this article were already sufficiently covered in the reviews referred to. 相似文献
1000.
While in the companion paper (Tonani, C. & Righetti, P. G., Electrophoresis 1991, 12, 1011-1021) we gave the general outline of our new computer program, immobilized pH gradients (IPG) simulator, able to simulate and optimize linear pH gradients for isoelectric focusing in immobilized pH gradients, in the present report we extend the application of such a program to: (i) convex exponential gradients, (ii) logarithmic and (iii) polynomial gradients. Such gradients are meant to give equal space to protein spots in complex protein mixtures (e.g., cell lysates, biological fluids) and follow the statistical distribution of protein pI values along the pH axis. They will prove of fundamental importance in two-dimensional maps, both because they optimize the spreading of spots in the two-dimensional plane and because of the excellent reproducibility of immobilized pH gradients. The following concave exponential recipes are given: pH 3-8, pH 3-9, pH 3-10, pH 3-11, pH 4-7, pH 4-8, pH 4-9, pH 4-10, pH 4-11, pH 5-8, pH 5-9, and pH 5-10, as well as the most extended pH 2.5-11 interval. Two interesting logarithmic gradients are described: pH 3-6 and pH 3-7 and one sigmoidal (derived with a polynomial of 5th degree): pH 3-11. 相似文献