全文获取类型
收费全文 | 247篇 |
免费 | 5篇 |
国内免费 | 2篇 |
专业分类
化学 | 166篇 |
晶体学 | 1篇 |
力学 | 3篇 |
数学 | 33篇 |
物理学 | 51篇 |
出版年
2020年 | 2篇 |
2019年 | 3篇 |
2018年 | 4篇 |
2017年 | 3篇 |
2016年 | 4篇 |
2015年 | 6篇 |
2014年 | 6篇 |
2013年 | 12篇 |
2012年 | 6篇 |
2011年 | 4篇 |
2010年 | 7篇 |
2009年 | 7篇 |
2008年 | 13篇 |
2007年 | 9篇 |
2006年 | 9篇 |
2005年 | 16篇 |
2004年 | 14篇 |
2003年 | 6篇 |
2002年 | 12篇 |
2001年 | 3篇 |
2000年 | 7篇 |
1999年 | 4篇 |
1996年 | 3篇 |
1995年 | 2篇 |
1994年 | 1篇 |
1991年 | 7篇 |
1990年 | 9篇 |
1989年 | 5篇 |
1988年 | 5篇 |
1987年 | 4篇 |
1986年 | 7篇 |
1985年 | 8篇 |
1984年 | 4篇 |
1983年 | 1篇 |
1982年 | 6篇 |
1981年 | 4篇 |
1980年 | 3篇 |
1979年 | 4篇 |
1978年 | 2篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1973年 | 2篇 |
1972年 | 1篇 |
1970年 | 1篇 |
1968年 | 2篇 |
1967年 | 1篇 |
1966年 | 2篇 |
1965年 | 1篇 |
排序方式: 共有254条查询结果,搜索用时 15 毫秒
81.
Takashi Furuya 《Journal of Molecular Spectroscopy》2003,220(1):122-131
The rotational spectrum of the monodeuterated PH2 radical was studied using a source-modulated submillimeter-wave spectrometer. The PHD radical was generated in a free space absorption cell by a dc-glow discharge in a gas mixture of PH3 and D2. Six a-type and 20 b-type rotational transitions were observed in the frequency region of 170-670 GHz. Hyperfine structure due to the deuterium nucleus was resolved only in the rotational transitions of 111-000 and 110-101 and in the low F2 components of N=2-1 transitions. A total of 219 spectral lines were measured of which 145 were analyzed by least-squares methods. These yielded 34 precise molecular constants including the hyperfine coupling constants of phosphorus, hydrogen, and deuterium. The principal axes and principal values of the magnetic dipole coupling tensors of hydrogen in PH2 and deuterium in PD2 were derived from the observed values of PHD, PH2 and PD2. The principal axis of the hydrogen magnetic dipole coupling tensor in PH2 makes an angle of 2.29° with the PH bond and its Tσ and T⊥ principal values are determined to be 12.93 and −18.39 MHz, respectively. 相似文献
82.
CoFe2O4-BaTiO3 composites were prepared using conventional ceramic double sintering process with various compositions. Presence of two phases
in the composites was confirmed using X-ray diffraction. The dc resistivity and thermoemf as a function of temperature in
the temperature range 300 K to 600 K were measured. Variation of dielectric constant (ɛ′) with frequency in the range 100 Hz to 1 MHz and also with temperature at a fixed frequency of 1 kHz was studied. The ac
conductivity was derived from dielectric constant (ɛ′) and loss tangent (tan δ). The nature of conduction is discussed on the basis of small polaron hopping model. The static value of magnetoelectric
conversion factor has been studied as a function of magnetic field. 相似文献
83.
Fumitoshi Toyokawa Hiroshi Abe Keiichi Furuya Tadashi Kikuchi 《Surface science》1983,133(1):L429-L431
The surface of multi-built-up layer of cobalt(II) stearate on copper substrate has been studied by means of low energy SIMS. The sampling surfaces were impacted with 700 eV, 8 × 10?7 Å/cm2, Ar+ ions. In each group (odd-numbered accumulated and even-numbered accumulated samples), the 58Co+ intensities at the initial bombardment responded to the number of the accumulation, respectively. The 58Co+ ion intensities from even-numbered accumulated samples were observed more than the expected values from a proportionality between the accumulation number and 58Co+ intensities. 相似文献
84.
A Gurtu P K Malhotra I S Mittra P M Sood SC Gupta VK Gupta GL Kaul LK Mangotra Y Prakash NK Rao ML Sharma 《Pramana》1974,3(5):311-322
This is a continuation of our earlier investigation (Gurtuet al 1974Phys. Lett. 50 B 391) on multiparticle production in proton-nucleus collisions based on an exposure of emulsion stack to 200 GeV/c beam at the NAL. It is found that the ratioR em = 〈n s〉/〈n ch〉, where 〈n ch〉 is the charged particle multiplicity in pp-collisions, increases slowly from about 1 at 10 GeV/c to 1·6 at 68 GeV/c and attains a constant value of 1·71 ± 0·04 in the region 200 to 8000 GeV/c. Furthermore,R em = 1·71 implies an effectiveA-dependence ofR A =A 0.18,i.e., a very weak dependence. Predictions ofR em on various models are discussed and compared with the emulsion data. Data seem to favour models of hadron-nucleon collisions in which production of particles takes place through adouble step mechanism,e.g., diffractive excitation, hydrodynamical and energy flux cascade as opposed to models which envisage instantaneous production. 相似文献
85.
86.
Takebayashi Y Mashimo Y Koike D Yoda S Furuya T Sagisaka M Otake K Sakai H Abe M 《The journal of physical chemistry. B》2008,112(30):8943-8949
Fourier transform infrared (FT-IR) spectrum of water-in-supercritical CO(2) microemulsion was measured at 60 degrees C and 30.0 MPa over a wide range of water/CO(2) ratio from 0.0 to 1.2 wt % to study the distribution of water into CO(2), interfacial area around surfactant headgroup, and core water pool. The microemulsion was stabilized by sodium bis(1H,1H,2H, 2H-heptadecafluorodecyl)-2-sulfosuccinate [8FS(EO)(2)] equimolarly mixed with sodium 1-oxo-1-[4-(tridecafluorohexyl)phenyl]-2-hexanesulfonate [FC6HC4] or with poly(ethylene glycol) 2,6,8-trimethyl-4-nonyl ether [TMN-6]. The signal area of the O-H stretching band of water suggested that the number of water molecules in the microemulsion increases linearly with the water/CO(2) ratio, except for a slow initial increase below 0.4 wt % due to a part of water dissolved in CO(2). The amount of water in CO(2) was evaluated by decomposing the bending band of water into two components, one at lower frequency ascribed to water in CO(2) and the other at higher frequency to water in the microemulsion. The decomposition confirmed that CO(2) is saturated with water at the water content of 0.4 wt %. It was also revealed, from the symmetric SO stretching frequency of the surfactant, that the sulfonate headgroup is completely hydrated at the water/CO(2) ratio of 0.4-0.5 wt %. The results demonstrated that water is introduced preferentially into CO(2) and the interfacial area at small water content, and then is loaded into the micelle core after the saturation of CO(2) with water and the full hydration of the surfactant headgroup. 相似文献
87.
A cycle C in a graph G is dominating if every edge of G is incident with at least one vertex of C. For a set \(\mathcal {H}\) of connected graphs, a graph G is said to be \(\mathcal {H}\)-free if G does not contain any member of \(\mathcal {H}\) as an induced subgraph. When \(|\mathcal {H}| = 2, \mathcal {H}\) is called a forbidden pair. In this paper, we investigate the characterization of the class of the forbidden pairs guaranteeing the existence of a dominating cycle and show the following two results: (i) Every 2-connected \(\{P_{5}, K_{4}^{-}\}\)-free graph contains a longest cycle which is a dominating cycle. (ii) Every 2-connected \(\{P_{5}, W^{*}\}\)-free graph contains a longest cycle which is a dominating cycle. Here \(P_{5}\) is the path of order \(5, K_{4}^{-}\) is the graph obtained from the complete graph of order 4 by removing one edge, and \(W^{*}\) is the graph obtained from two triangles and an edge by identifying one vertex in each. 相似文献
88.
Daiki Tanaka Satsuki Kajiya Seito Shijo Dong Hyun Yoon Masahiro Furuya Yoshito Nozaki Hiroyuki Fujita Tetsushi Sekiguchi Shuichi Shoji 《Molecules (Basel, Switzerland)》2021,26(12)
In recent years, research on the application of microdroplets in the fields of biotechnology and chemistry has made remarkable progress, but the technology for the stable generation of single-micrometer-scale microdroplets has not yet been established. In this paper, we developed an efficient and stable single-micrometer-scale droplet generation device based on the fragmentation of droplet tails, called “tail thread mode”, that appears under moderate flow conditions. This method can efficiently encapsulate microbeads that mimic cells and chemical products in passively generated single-micrometer-scale microdroplets. The device has a simple 2D structure; a T-junction is used for droplet generation; and in the downstream, multi-branch channels are designed for droplet deformation into the tail. Several 1–2 µm droplets were successfully produced by the tail’s fragmentation; this continuous splitting was induced by the branch channels. We examined a wide range of experimental conditions and found the optimal flow rate condition can be reduced to one-tenth compared to the conventional tip-streaming method. A mold was fabricated by simple soft lithography, and a polydimethylsiloxane (PDMS) device was fabricated using the mold. Based on the 15 patterns of experimental conditions and the results, the key factors for the generation of microdroplets in this device were examined. In the most efficient condition, 61.1% of the total droplets generated were smaller than 2 μm. 相似文献
89.
Two new monoterpene diglycosides, suffruyabiosides A and B, and seven known compounds 3-9 were isolated from Moutan Cortex (root cortex of Paeonia suffruticosa Andrews). The structures were elucidated on the basis of 2D NMR spectral data. Suffruyabiosides A and B are rare monoterpene diglycosides, including a cellobiose in the molecules. Salicylpaeoniflorin (4) had a antiproliferation effect similar to paeoniflorin (3) on human lung adenocarcinoma epitherial A549 cells. Galloylpaeoniflorin (8) and salicylpaeoniflorin (4) revealed a more pronounced radical scavenging effect than a-tocopherol (positive control). An increase in the number of phenolic hydroxyl groups produced a more effective radical scavenging effect [8 > mudanpioside E (6) > oxypaeoniflorin (5)]. Comparison of the effects of 4 and 5 showed that o-substitution with a phenolic hydroxyl group was more effective than p-substitution. The results suggest that salicylpaeoniflorin (4) may be useful as a cytotoxic and a radical scavenging agent. 相似文献
90.
Yoshihiko Noguchi Tomoyasu Hirose Yujiro Furuya Aki Ishiyama Kazuhiko Otoguro Satoshi Ōmura Toshiaki Sunazuka 《Tetrahedron letters》2012,53(14):1802-1807
We report the first total synthesis and reassignment of the relative stereochemistry of naturally occurring 16-hydroxy-16,22-dihydroapparicine. Our novel route proceeds by a cascade reaction to efficiently construct a 1-azabicyclo[4.2.2]decane core, along with two stereocenters (C-15 and C-16). The C-16 quaternary carbon was constructed through stereospecific 1,2-addition using an indole nucleophile to an aldehyde or a methylketone. The stereospecific synthesis of two diastereomers of the target product has revealed the true relative stereochemistry of the natural compound. 相似文献