π-Extended Thiadiazoles Fused with Thienopyrrole or Indole Moieties: Synthesis, Structures, and Properties

We report the syntheses, structures, photophysical properties, and redox characteristics of donor-acceptor-fused π-systems, namely π-extended thiadiazoles 1-5 fused with thienopyrrole or indole moieties. They were synthesized by the Stille coupling reactions followed by the PPh(3)-mediated reductive cyclizations as key steps. X-Ray crystallographic studies showed that isomeric 1b and 2b form significantly different packing from each other, and 1a and 4a afford supramolecular networks via multiple hydrogen bonding with water molecules. Thienopyrrole-fused compounds 1b and 2b displayed bathochromically shifted intramolecular charge-transfer (CT) bands and low oxidation potentials as compared to indole-fused analog 3b and showed moderate to good fluorescence quantum yields (Φ(f)) up to 0.73. In 3b-5b, the introduction of electron-donating substituents in the indole moieties substantially shifts the intramolecular CT absorption maxima bathochromically and leads to the elevation of the HOMO levels. The Φ(f) values of 3-5 (0.04-0.50) were found to be significantly dependent on the substituents in the indole moieties. The OFET properties with 1b and 2b as an active layer were also disclosed.     

Forbidden Triples Containing a Complete Graph and a Complete Bipartite Graph of Small Order

For a graph G and a set \({\mathcal{F}}\) of connected graphs, G is said be \({\mathcal{F}}\) -free if G does not contain any member of \({\mathcal{F}}\) as an induced subgraph. We let \({\mathcal{G} _{3}(\mathcal{F})}\) denote the set of all 3-connected \({\mathcal{F}}\) -free graphs. This paper is concerned with sets \({\mathcal{F}}\) of connected graphs such that \({\mathcal{F}}\) contains no star, \({|\mathcal{F}|=3}\) and \({\mathcal{G}_{3}(\mathcal{F})}\) is finite. Among other results, we show that for a connected graph T( ≠ K ₁) which is not a star, \({\mathcal{G}_{3}(\{K_{4},K_{2,2},T\})}\) is finite if and only if T is a path of order at most 6.     

Control of multi-joint arm movements for the manipulation of touch in keystroke by expert pianists

Background  

Production of a variety of finger-key touches in the piano is essential for expressive musical performance. However, it remains unknown how expert pianists control multi-joint finger and arm movements for manipulating the touch. The present study investigated differences in kinematics and kinetics of the upper-limb movements while expert pianists were depressing a key with two different touches: pressed and struck. The former starts key-depression with the finger-tip contacting the key, whereas the latter involves preparatory arm-lift before striking the key. To determine the effect of individual muscular torque (MUS) as well as non-muscular torques on joint acceleration, we performed a series of inverse and forward dynamics computations.     

Working group report: Heavy-ion physics and quark-gluon plasma

This is the report of Heavy Ion Physics and Quark-Gluon Plasma at WHEPP-09 which was part of Working Group-4. Discussion and work on some aspects of quark-gluon plasma believed to have created in heavy-ion collisions and in early Universe are reported.     

Fabrication of self-standing nanowires, nanodendrites, and nanofractal-like trees on insulator substrates with an electron-beam-induced deposition

Self-standing tungsten nanowires, nanodendrites, and nanofractal-like trees were fabricated on insulator (Al₂O₃) substrates with a process of electron-beam-induced decomposition in a transmission electron microscope. The conditions for fabricating different morphologies are described. The fabricated structures are characterized with high-resolution transmission electron microscopy and X-ray energy-dispersive spectroscopy. A high concentration of tungsten and a high crystallinity of the structure are confirmed. The growth process is discussed, involving charges produced on the surface of the substrate and the behavior of precursor molecules under electron-beam irradiation. The formation of these structures is considered to relate to nanoscaled unevenness of the charge distribution on the surface of the substrate, movement of charges to the convex surface of the substrate, and accumulation of charges at the tips of the grown structures. PACS 81.07.-b; 07.78.+s; 81.15.Gh; 81.16.-c     

Support Varieties for Modules Over Stacked Monomial Algebras

Let Λ be a finite-dimensional (D, A)-stacked monomial algebra. In this article, we give necessary and sufficient conditions for the variety of a simple Λ-module to be nontrivial. This is then used to give structural information on the algebra Λ, as it is shown that if the variety of every simple module is nontrivial, then Λ is a D-Koszul monomial algebra. We also provide examples of (D, A)-stacked monomial algebras which are not self-injective but nevertheless satisfy the finite generation conditions (Fg1) and (Fg2) of [4 Erdmann , K. , Holloway , M. , Snashall , N. , Solberg , Ø. , Taillefer , R. ( 2004 ). Support varieties for selfinjective algebras . K-Theory 33 : 67 – 87 .[Crossref] , [Google Scholar]], from which we can characterize all modules with trivial variety.     

Bending and springback theory of metal-polymer sandwich laminates

In this report an analysis is made of the behavior of sandwich beams in which the core polymer is laminated on both sides with surface metal sheets, each of which has a different thickness and mechanical properties when they are loaded with a uniform bending moment which is then released resulting in springback of the bent sandwich beam. It is assumed that the polymer behaves elastically because the bending strain in the core is small and its elastic limit is much larger than that of metals. Sandwich beams have various elastoplstic stess distributions when bent depending on the mutual relationships between their dimensions, the mechanical moduli, and the applied bending moment. Further, residual curvatures, shifting position of neutral axis, and residual stress distributions in sandwich beams variously elastoplastically stressed initially on the decrease of applied bending moment are analyzed.