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11.
Summary HPLC determination of pheophytinatonicke(II) (Pheo-Ni) prepared by the replacement of magnesium(II) in chlorophyll with nicke(II)
is described. The good separation of PheoNi was obtained by using chemically bonded C18 as the stationary phase and acetone-methanol (50∶50, vol/vol) as the mobile phase. Conventional spectrophotometric method
was also used for the determination of PheoNi. For the synthetic samples prepared by mixing (pheophytinato a) nicke(II) [(Pheo-a)
Ni] and (pheophytinato b) nicke(II) [(Pheo-b) Ni], analytical values obtained by the spectrophotometric method were very high
compared to those obtained by HPLC. In the proposed HPLC method, (Pheo-a) Ni and (Pheo-b). Ni could be determined in the concentration
range of 0.028–30μg/ml and 0.038–30μg/ml with relative standard deviations (n=10) of 3.1% and 0.8%, respectively. 相似文献
12.
The number of iridium sites and that of rhodium sites occupied by a foreign atom was determined with the aid of the pulse technique. In the case of iridium the foreign atoms included are Cu, Ag, Cd, Hg, In, Tl, Pb, Se, Te, As and Bi. The approximate value is 1 for the first two, 2 for the next five and 2.5–2.7 for the others. In the case of rhodium substrate, the foreign atoms included are Cu, Ag, Cd, Hg, In, Tl, Ge, Pb, As, Sb, Se, Te, and Bi. The approximate value is 1 for the first two, 2 for the next six, 2.4–2.6 for the next four and 3.0 for the last one. Silver and copper ad-atoms are closely packed both on the iridium and rhodium surface, but the ad-atoms of the other elements are arranged on the surfaces leaving empty sites for geometrical reasons, even when the monolayer is apparently complete. 相似文献
13.
O. Takahashi Y. Masuda A. Muroya T. Furuya 《SAR and QSAR in environmental research》2013,24(5-6):547-558
In general, the docking scoring tends to have a size dependence related to the ranking of compounds. In this paper, we describe a novel method of parameter optimization for docking scores which reduce the size dependence and can efficiently discriminate active compounds from chemical databases. This method is based on a simplified theoretical model of docking scores which enables us to utilize large amounts of data of known active and inactive compounds for a particular target without requiring large computational resources or a complicated procedure. This method is useful for making scoring functions for the identification of novel scaffolds using the knowledge of active compounds for a particular target or a customized scoring function for an interesting family of drug targets. 相似文献
14.
A nonlinear optical crystal YCa(4)O(BO(3))(3) (YCOB) is phase matchable for third-harmonic generation (THG) of a Nd:YAG laser by type I mixing between 1.064 and 0.532mum . By partial substitution of Gd for Y in YCOB, a solid solution Gd(x)Y(1-x)Ca(4)O(BO(3))(3) gradually changes the phase-matching angles of THG to (theta, ?)=(90( degrees ), 90 ( degrees )) . We present the properties of noncritically phase-matched THG in Gd(x) Y(1-x)Ca(4)O(BO(3))(3) (x=0.28) . 相似文献
15.
G.Q.?XieEmail author M.?Song K.?Mitsuishi K.?Furuya 《Applied Physics A: Materials Science & Processing》2004,79(8):1843-1846
The selective deposition of a metal (tungsten) into ordered nanohole arrays of an anodic porous alumina membrane was performed using an electron-beam-induced deposition process. After deposition, the membrane was observed and analyzed using electron microscopy and energy-dispersive X-ray spectroscopy. It is shown that the deposition was preferentially conducted in the holes in the irradiated area of the electron beam. A calculation of the electron-beam intensity explains the reason for the preferential deposition in the holes. PACS 81.07.-b; 81.16.Rf; 61.46.+w 相似文献
16.
Mamoru Furuya Hiroshi Niitsuma 《Proceedings of the American Mathematical Society》2004,132(11):3189-3193
We introduce the concept of -adic -basis as an extension of the concept of -basis. Let be a regular local ring of prime characteristic and a ring such that . Then we prove that is a regular local ring if and only if there exists an -adic -basis of and is Noetherian.
17.
N. Hori A. Furuya M. Tsuruta F. Misaizu K. Ohno 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,43(1-3):41-44
Photoinduced dissociation in the ultraviolet region has been investigated for Ag nF n-1
+ cluster ions. Photodissociation spectrum of
Ag2F+
in the energy of 3.8–5.6 eV exhibits several sharp bands corresponding to the transition to electronically excited states.
In this dissociation, only the Ag2
+ ion was observed as a fragment ion. Theoretical calculation indicates that the parent Ag2F+ ion has a linear Ag-F-Ag equilibrium geometries in the ground and excited states. Since conformational changes by excitation
of bending vibration are necessary for the fragmentation of an F atom, this indicates that production of Ag2
+ from Ag2F+ is a result of internal conversion and following conformational changes. 相似文献
18.
19.
Experiments have been conducted to investigate an effect of inlet restriction on the thermal-hydraulic stability. A Test
facility used in this study was designed and constructed to have non-dimensional values that are nearly equal to those of
natural circulation BWR. Experimental results showed that driving force of the natural circulation at the stability boundary
was described as a function of heat flux and inlet subcooling independent of inlet restriction. In order to extend experimental
database regarding thermal-hydraulic stability to different inlet restriction, numerical analysis was carried out based on
the homogeneous flow model. Stability maps in reference to the core inlet subcooling and heat flux were presented for various
inlet restrictions using the above-mentioned function. Instability region during the inlet subcooling shifted to the higher
inlet subcooling with increasing inlet restriction and became larger with increasing heat flux.
Received on 17 January 2000 相似文献
20.
Minghui Song Kazutaka Mitsuishi Kazuo Furuya 《Physica E: Low-dimensional Systems and Nanostructures》2005,29(3-4):575
Nanometer-sized W-dendrites are fabricated on Al2O3 substrates with an electron-beam-induced deposition process. Dependence of growth of nanodendrite on surface topography is investigated with transmission electron microscopy. It is confirmed that the nanodendrite grows on convex surfaces but not around a hole on a substrate. These are attributed to different distribution of charges on surfaces with different topographies during electron beam irradiation when charges are produced on the surface due to emission of second electrons. The charges accumulate on convex surface and do not distribute around a hole. Therefore, the nanodendrite grows on the former and not on the latter. 相似文献