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Jean Kossanyi J. P. Morizur Bernard Furth Joseph Wiemann A. M. Duffield Carl Djerassi 《Journal of mass spectrometry : JMS》1968,1(6):777-789
The mass spectra of nineteen aliphatic 1,2-glycols containing a variety of substituents have been recorded and mechanistic rationalizations are presented for the more important degradation processes observed. Fragmentation of the hydroxylated carbon-carbon bond in these compounds occurred to an appreciable degree often accompanied by the transfer of a hydroxylic hydrogen atom. 相似文献
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Löbbus M Sonnfeld J van Leeuwen HP Vogelsberger W Lyklema J 《Journal of colloid and interface science》2000,229(1):174-183
The surface electric properties of the commercially available silica, Monospher 1000 (Fa. Merck), have been studied by conductivity and ESA (electrokinetic sonic amplitude) experiments. It could be shown that accounting for the contribution of the stagnant layer to surface conductivity is indispensable in the interpretation of electrokinetic data at low ionic strength. A general method has been put forward which allows to take into account the total, experimentally accessible surface conductivity in the evaluation of ESA data of moderately concentrated suspensions. This includes additional conductivity measurements which serve for the independent estimation of the total relative surface conductivity. The resulting zeta-potentials are clearly higher than those obtained after neglecting the contribution of the stagnant layer to surface conductivity. In addition, the ionic mobilities of potassium and magnesium in the hydrodynamically stagnant layer have been investigated in some detail. It has been found that the ionic mobility of potassium is of the same order of magnitude as in the bulk solution while the mobility of magnesium is significantly reduced. Copyright 2000 Academic Press. 相似文献
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