Dichloro­oxo(quinoline‐8‐thiolato‐κ2N,S)(triphenyl­phosphine oxide‐κO)rhenium(V) acetone solvate

The complex mol­ecule in the title compound, [Re(C₉H₆NS)Cl₂O(C₁₈H₁₅OP)]·C₃H₆O, has distorted octa­hedral geometry. The Re=O bond occupies the position trans to the triphenyl­phosphine oxide O atom. The Re—Cl bond trans to the thiol­ate S atom is longer than that trans to the quinoline N atom, implying a stronger trans influence of the S atom. Intra‐ and inter­molecular π–π inter­actions are also observed between the π rings in the complex.     

Biooxidation of (+)-catechin and (-)-epicatechin into 3,4-dihydroxyflavan derivatives by the endophytic fungus Diaporthe sp. isolated from a tea plant

The microbial transformation of (+)-catechin (1) and (-)-epicatechin (2) by endophytic fungi isolated from a tea plant was investigated. It was found that the endophytic filamentous fungus Diaporthe sp. transformed them (1, 2) into the 3,4-cis-dihydroxyflavan derivatives, (+)-(2R,3S,4S)-3,4,5,7,3',4'-hexahydroxyflavan (3) and (-)-(2R,3R,4R)-3,4,5,7,3',4'-hexahydroxyflavan (7), respectively, whereas (-)-catechin (ent-1) and (+)-epicatechin (ent-2) with a 2S-phenyl group resisted the biooxidation.     

Polarity determination of wurtzite-type crystals using hard x-ray photoelectron diffraction

The surface structure of a single-crystal ZnO wafer was studied by angle-resolved x-ray photoelectron spectroscopy (ARXPS) using synchrotron radiation. As a result, well-defined x-ray photoelectron diffraction (XPD) patterns were obtained for the (0001) and (000$\overline{1}$) polar surfaces using the photoemission from the Zn 2p_3/2 and O 1s core levels. The XPD patterns were indexed assuming forward scattering of photoelectrons by neighboring ions. Further, the XPD patterns for the (0001) and (000$\overline{1}$) surfaces were different from each other, indicating the possibility for using the XPD technique for polarity determination.     

Spontaneous supersymmetry breaking in matrix models from the viewpoints of localization and Nicolai mapping

In the previous work, it was shown that, in supersymmetric (matrix) discretized quantum mechanics, inclusion of an external field twisting the boundary condition of fermions enables us to discuss spontaneous breaking of supersymmetry (SUSY) in the path-integral formalism in a well-defined way. In the present work, we continue investigating the same systems from the points of view of localization and Nicolai mapping. The localization is studied by changing of integration variables in the path integral, which is applicable whether or not SUSY is explicitly broken. We examine in detail how the integrand of the partition function with respect to the integral over the auxiliary field behaves as the auxiliary field vanishes, which clarifies a mechanism of the localization. In SUSY matrix models, we obtain a matrix-model generalization of the localization formula. In terms of eigenvalues of matrix variables, we observe that eigenvalues' dynamics is governed by balance of attractive force from the localization and repulsive force from the Vandermonde determinant. The approach of the Nicolai mapping works even in the presence of the external field. It enables us to compute the partition function of SUSY matrix models for finite N (N is the rank of matrices) with arbitrary superpotential at least in the leading nontrivial order of an expansion with respect to the small external field. We confirm the restoration of SUSY in the large-N limit of a SUSY matrix model with a double-well scalar potential observed in the previous work.     

Reduction of thermal fluctuations in a cryogenic laser interferometric gravitational wave detector

The thermal fluctuation of mirror surfaces is the fundamental limitation for interferometric gravitational wave (GW) detectors. Here, we experimentally demonstrate for the first time a reduction in a mirror's thermal fluctuation in a GW detector with sapphire mirrors from the Cryogenic Laser Interferometer Observatory at 17 and 18 K. The detector sensitivity, which was limited by the mirror's thermal fluctuation at room temperature, was improved in the frequency range of 90 to 240 Hz by cooling the mirrors. The improved sensitivity reached a maximum of 2.2×10(-19) m/√Hz at 165 Hz.