Cellulose acetate butyrate as multifunctional additive for poly(butylene succinate) by melt blending: Mechanical properties, biomass carbon ratio, and control of biodegradability

We have evaluated the plasticizing effect of poly(butylene succinate) (PBS) and cellulose acetate butyrate (CAB). PBS and CAB were mixed with a melt-kneading machine. The tensile strength and strain at break in the case of the blend with 10% CAB in the PBS matrix were 547% and 35 MPa. It showed that CAB acted as a plasticizer for PBS. The biomass carbon ratio of the blends measured by accelerator mass spectrometry based on ASTM D6866 showed that the biomass carbon derived from a part of the CAB corresponded to the theoretical value of the polymer blend. The biodegradation of PBS with the CAB melt blend powders was evaluated by a microbial oxidative degradation analyzer under controlled compost conditions based on ISO 14855-2. PBS with 10% CAB was not degraded within 60 days due to the addition of CAB that could control the biodegradability of the PBS.     

A facile method for generation of carbon oxide sulfide

Carbon oxide sulfide was easily generated upon heating of amine salts of carbamothioic acids at 85°C which were produced in situ from amines, carbon monoxide, and elemental sulfur in the presence of a catalytic amount of selenium under mild conditions.