全文获取类型
收费全文 | 371篇 |
免费 | 7篇 |
国内免费 | 1篇 |
专业分类
化学 | 260篇 |
晶体学 | 3篇 |
力学 | 1篇 |
数学 | 36篇 |
物理学 | 79篇 |
出版年
2022年 | 2篇 |
2021年 | 6篇 |
2020年 | 3篇 |
2019年 | 6篇 |
2018年 | 2篇 |
2017年 | 3篇 |
2016年 | 9篇 |
2015年 | 6篇 |
2014年 | 16篇 |
2013年 | 6篇 |
2012年 | 28篇 |
2011年 | 27篇 |
2010年 | 15篇 |
2009年 | 4篇 |
2008年 | 21篇 |
2007年 | 18篇 |
2006年 | 20篇 |
2005年 | 18篇 |
2004年 | 15篇 |
2003年 | 14篇 |
2002年 | 17篇 |
2001年 | 5篇 |
2000年 | 12篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1997年 | 4篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 8篇 |
1993年 | 4篇 |
1992年 | 5篇 |
1991年 | 3篇 |
1990年 | 6篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1987年 | 4篇 |
1986年 | 1篇 |
1985年 | 11篇 |
1984年 | 4篇 |
1983年 | 5篇 |
1982年 | 2篇 |
1981年 | 7篇 |
1980年 | 5篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1976年 | 7篇 |
1975年 | 4篇 |
1974年 | 3篇 |
1973年 | 3篇 |
1972年 | 3篇 |
排序方式: 共有379条查询结果,搜索用时 31 毫秒
81.
Revisiting the Bromination of CH Bonds with Molecular Bromine by Using a Photo‐Microflow System
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dr. Yoshiyuki Manabe Yuriko Kitawaki Masahiro Nagasaki Prof. Koichi Fukase Prof. Hiroshi Matsubara Yoshiko Hino Prof. Takahide Fukuyama Prof. Ilhyong Ryu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(40):12750-12753
The photobromination of C?H bonds by using molecular bromine was reinvestigated under microfluidic conditions. The continuous‐flow method suppressed the production of dibrominated compounds and effectively produced the desired monobrominated products with high selectivity. Rapid bromination of benzylic substrates containing a photoaffinity azide group was achieved without any decomposition. 相似文献
82.
83.
84.
85.
C. Funayama T. Furukawa T. Sato Y. Ichikawa Y. Ohtomo Y. Sakamoto S. Kojima T. Suzuki C. Hirao M. Chikamori E. Hikota M. Tsuchiya A. Yoshimi C. P. Bidinosti T. Ino H. Ueno Y. Matsuo T. Fukuyama K. Asahi 《Hyperfine Interactions》2015,232(1-3):59-66
We demonstrate spin-exchange optical pumping of 129Xe atoms with our newly made laser system. The new laser system was prepared to provide higher laser power required for the stable operation of spin maser oscillations in the 129Xe EDM experiment. We studied the optimum cell temperature and pumping laser power to improve the degree of 129Xe spin polarization. The best performance was achieved at the cell temperature of 100 °C with the presently available laser power of 1 W. The results show that a more intense laser is required for further improvement of the spin polarization at higher cell temperatures in our experiment. 相似文献
86.
Dr. Yoichi M. A. Yamada Toshihiro Watanabe Tomohiko Beppu Naoshi Fukuyama Kaoru Torii Prof. Dr. Yasuhiro Uozumi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(37):11311-11319
Instantaneous catalytic carbon–carbon bond‐forming reactions were achieved in catalytic membrane‐installed microchannel devices that have a polymeric palladium‐complex membrane. The catalytic membrane‐installed microchannel devices were provided inside the microchannels by means of coordinative and ionic molecular convolution at the interface between the organic and aqueous phases flowing laminarly, in which both non‐crosslinked linear polymer ligands and palladium species dissolved. The palladium‐catalyzed Suzuki–Miyaura reaction of aryl, heteroaryl, and alkenyl halides with arylboronic acids and sodium tetraarylborates was performed with the catalytic membrane‐installed microchannel devices to give quantitative yields of biaryls, heterobiaryls, and aryl alkenes within 5 s of residence time in the defined channel region. These microchannel devices were applied to the instantaneous allylic arylation reaction of allylic esters with arylboron reagents under microflow conditions to afford the corresponding coupling products within 1 s of residence time. 相似文献
87.
Harada Y Takeuchi T Kino H Fukushima A Takakura K Hieda K Nakao A Shin S Fukuyama H 《The journal of physical chemistry. A》2006,110(49):13227-13231
The electronic structures of a series of DNA nucleobases and their dinucleotides were investigated by N 1s X-ray absorption, X-ray photoemission, and resonant X-ray emission spectroscopy. Resonant X-ray emission spectra of the guanine base and its dinucleotide indicate that it has a weak structure at the lowest binding energy; at this energy, it isolates from the main valence band and forms the HOMO state. This indicates that the HOMO state is localized in the guanine base, as claimed by valence and core photoemissions and expected from theoretical predictions. In addition, the XAS and XES profiles of the guanine dinucleotide indicate that disruption of the aromatic character of the six-membered ring results in the localization of the pi state at the imine (-N=) site of the guanine base; this may favor charge transfer among stacked guanine bases and further influence the conductivity of DNA. 相似文献
88.
Furukawa T Matsuo Y Hatakeyama A Fukuyama Y Kobayashi T Izumi H Shimoda T 《Physical review letters》2006,96(9):095301
The longitudinal electronic spin relaxation time of Cs atoms optically polarized in superfluid helium (He II, 1.5 K) has been measured with special care to cope with a serious decrease in the number of Cs atoms in the observation region. This decrease, mainly caused by helium convection in introducing the atoms into He II by laser sputtering, was significantly reduced using a new atom implantation method. Combined with a careful correction for the number of atoms, we have determined the relaxation time to be 2.24(19) s or longer, roughly twice as long as that in solid He. 相似文献
89.
Katusi Fukuyama 《Acta Mathematica Hungarica》2010,129(4):303-313
This paper is mainly concerned with the limit distribution of \((\cos 2\pi n_{1}x+\cdots +\cos 2\pi n_{N}x)/\sqrt{N}\) on the unit interval when the increasing sequence {n k } has bounded gaps, i.e., 1≤n k+1?n k =O(1). By Bobkov–Götze [4], it was proved that the limiting variance must be less than 1/2 in this case. They proved that the centered Gaussian distribution with variance 1/4 together with mixtures of Gaussian distributions belonging to a huge class can be limit distributions. In this paper it is proved that any Gaussian distribution with variance less than 1/2 can be a limit distribution. 相似文献
90.
Ryu I Miyazato H Kuriyama H Matsu K Tojino M Fukuyama T Minakata S Komatsu M 《Journal of the American Chemical Society》2003,125(19):5632-5633
Free-radical mediated stannylcarbonylation of azaenynes provides a general [n + 1]-type annulation approach leading to alpha-stannylmethylene lactams. The cyclization is unusual in its breadth, covering 4-exo, 5-exo, 6-exo, 7-exo, and 8-exo modes. 相似文献