ErP_5O_(14)非晶中Er~(3+)离子的三光子荧光现象

全浓度ErP_5O_(14)非晶由于其独特的晶体结构,使其重要的荧光线即未浓度淬灭,又存在较强的能量传递现象。本文用调Q的Nd~(3+)∶YAG 1.06μm脉冲激光,研究了ErP_5O_(14)非晶中Er~(3+)离子的多光子吸收现象,证明Er~(3+)离子吸收1.06μm激光导致了~4I_(15/2)→~2H_(11/2)的直接双光子吸收,并且在激光功率密度较大时,还会导致明显的相继~4I_(9/2)→~4F_(5/2)吸收而产生的相继激发三光子过程。     

具非线性对流项扩散方程的源型解

研究主部为热传导算子的拟线性抛物型方程Cauchy问题:u_t=u_(xx) (u~n)_x,(x,t)∈S=R×(0,∞),u(x,0)=δ(x),x∈■在一维情形下源型解的存在性,唯一性,不存在性,解的渐近性和相似源型解等问题.在研究过程中,找到了一个n的临界值,即n_0=3.当0≤n相似文献   

三核铁甲酸簇合物[Fe_3(μ_3-O)(μ-O_2CH)_6(H_2O)_2(O_2CH)]·2H_2O在乙炔、水汽体系中的反应行为

本文研究了[Fe_3(μ_3-O)(μ-O_2CH)_6(H_2O)_2(O_2CH)]·2H_2O(简称)在乙炔、水汽体系中的反应行为。发现当温度高于220℃,脱落部分配体的具有活化乙炔进行加成反应的性能。采用原位红外光谱法和气相色谱法对此反应过程进行了跟踪探索,报道了产物的定性及半定量结果。     

聚合物纳米杂化材料的控制合成、自组装及功能化

聚合物纳米杂化材料的制备及功能化是当前国际前沿研究课题之一.特殊结构的聚合物可以通过分子间特殊相互作用,在纳米尺度上自发地组装成具有特殊结构和形态的集合体,这类材料在新材料、电子以及生物医学等领域具有广泛的应用前景.本文介绍国内外,特别是厦门大学在双亲性分子及嵌段共聚物的模板自组装、基于POSS单体纳米构筑单元以及POSS嵌段聚合物自组装的有机/无机纳米杂化材料、模板控制导电高分子材料纳米形态构筑等领域材料的可控合成和组装,与此同时对相关材料的性能及功能化应用进行了简要的讨论.     

THE INTERIOR LAYER SOLUTION TO NONLOCAL REACTION DIFFUSION EQUATIONS

An initial boundary value problem of semilinear nonlocal reaction diffusion equations is considered.Under some suitable conditions,using the asymptotic theory,the existence and asymptotic behavior of the interior layer solution to the initial boundary value problem are studied.     

Synthesis and structural characterization of Znb3Nb2 powder

Science China Physics, Mechanics & Astronomy - Zinc nitride (Znb3Nb2) powder has been synthesized through the nitridation reaction of Zn powder with NH3 gas (at the flow rate of 500 ml/min) at...     

Ab Initio and Density Functional Study on the First Hyperpolarizabilities of Squaric Acid Homologues

The first hyperpolarizabilities of four squaric acid homologues: squaric acid, 1,2-dithiosquaric acid,1,2-diselenosquaric acid and 1,2-ditellurosquaric acid have been calculated using ab initio and DFT methods. The effects of equilibrium geometries, basis set and electron correlation on the first hyperpolarizabilties of these molecules were investigated. The frequency dispersion effect and solvent effect, which are essential to get reliable outputs in comparison to the experimental results, have also been explored. On the basis of these investigations, it is worthy to point out that the heavy atom effect takes effect for these squaric acid homologues.     

关于拟圆性质的评注

设D是扩充复平面R-2中的单连通Jordan真子域,D*=R-2\D-是D的外部.本文肯定并证明 了K.Hag在1999年提出的如下两个悬而未决的问题:(1)D是Cigar域当且仅当D是OLC域; (2)D是Turning域当且仅当D*是Cigar域.     

An explicit formula for the Webster torsion of a pseudo-hermitian manifold and its application to torsion-free hypersurfaces Dedicated to Professor Sheng GONG on the occasion of his 75th birthday

This paper gives an explicit formula for calculating the Webster pseudo torsion for a strictly pseudoconvex pseudo-hermitian hypersurface. As applications, we are able to classify some pseudo torsion-free hypersurfaces, which include real ellipsoids.     

Detection system for singlet oxygen luminescence in photodynamic therapy

Singlet oxygen （^1O2） is widely considered to play a major role in photodynamic therapy （PDT）, and thus an increasing attention has been focused on the direct detection of ^1O2 near-infrared luminescence around 1270 nm for PDT dosimetry. A new sensitive detection system is developed to directly measure the temporal and spectral resolved ^1O2 luminescence spectra. The triplet state and ^1O2 lifetimes of Rose Bengal as a model photosensitizer in different solvents are determined, and the obtained results agree well with the published data. Our detection system has the potential application in ^1O2 luminescence-based PDT dosimetry.