Synthesis, Structural Characterization and Reactivity of Two New Triangular Molybdenum Cluster Compounds: Mo_3Te_7-[S_2CN(CH_2CH_2OH)_2]_3I and Mo_3Te_4Y_3[S_2P( ~iPrO)_2]_3I (Y_3=1.43Te+1.57S)

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关于一类拟线性退化抛物方程

对拟线性退化抛物方程θ_(xx)u uθ_yu-θ_tu=f(·,u)进行了研究,得到了在[O,T]×Ω上的初边值问题解的存在唯—性,这里要求T充分小．     

溶剂热法合成新型锑硒化合物[M~1(C_4H_(13)N_3)_2]_n[M~2Sb_2Se_5]_n(M~1=Mn、Co,M~2=Zn、Cd)及结构

以二乙烯三胺为模板剂,通过溶剂热法制备了一种新型有机无机杂化锑硒化合物:[M1(C4H13N3)2]n[M2Sb2Se5]n(M1=Mn、Co,M2=Zn、Cd).相比传统的有机无机杂化锑硒化合物,过渡金属Zn和Cd参与了这种化合物主框架的构建,使化合物的主框架由传统的SbSex单元转变为Zn(Cd)SbSe5的配位单元.据我们所知,这是第一次合成出Zn和Cd参与SbSex骨架配位的有机无机杂化锑硒化合物.同时,由于结构中CdSe4和ZnSe4单元的存在,使得该化合物表现出荧光性质.这种化合物的出现,使得我们有可能通过相同的途径合成出一系列具有该类型结构特征,在发光领域有潜在应用前景的新型锑硒化合物.     

Lentivirus-Mediated Knockdown of CUGBP1 Suppresses Gastric Cancer Cell Proliferation In Vitro

Gastric cancer is the second most common cause of cancer-related death worldwide. This study was designed to examine the role of CUGBP1 in cell growth via an RNA interference (RNAi) lentivirus system in gastric cancer cells in vitro. The expression of CUGBP1 was much stronger in gastric cancer tissues than that in adjacent normal tissues. The lentivirus-mediated knockdown of CUGBP1 resulted in a significant reduction of CUGBP1 expression in MGC-803 gastric cancer cells. The cell viability was remarkably decreased by 50 % after 5 days of infection, as determined by MTT assay. Moreover, the size and the number of colonies formed in MGC-803 cells were markedly reduced in the absence of CUGBP1. Furthermore, the silencing of CUGBP1 downregulated the expression levels of cyclin B1 and cyclin D1, which are involved in cell cycle control. These results clearly indicated that CUGBP1 is essential for the growth of gastric cancer cells. Therefore, silencing of CUGBP1 by RNAi could be developed as a promising therapeutic approach for gastric cancer.     

越过临界状态的奇异扩散方程

本文讨论越过临界状态的奇异扩散方程Cauchy问题和带非线性边界条件的第二边值问题的可解性与不可解性.主要结果是: (1)若||u0||L1(R)< ∞,则对任意的正数T,方程的Cauchy问题在带型区域QT=R×(0,T)中不存在关于变量x为L1(R)可积的正解; (2)当且仅当T≤T0,矩形区域GT=(0,1)×(0,T)中的一类非线性边值问题存在唯一的经典解,其中T0=u0=integral from n=0 to1(u0(x)dx).     

异核碱金属二聚物NaK的激光诱导荧光光谱

用Ar~+激光器488nm输出作为激发光源,获得NaK分子的荧光谱,对它的标志和分析可以了解该分子D~1Ⅱ激发态的能级结构以及在其中所进行的各种能量转移过程。     

无机-有机杂化非线性光学晶体材料LAP和d-LAP晶体红外吸收边计算

根据双原子谐振子模型近似,提出了估算分子晶体材料红外吸收边的理论方法,然后利用超分子量子化学从头算,计算了L-精氨酸一水磷酸盐(LAP)晶体和氘化L-精氨酸一水磷酸盐(d-LAP)晶体单元超分子的红外振动光谱,其中LAP晶体超分子计算值与晶体红外光谱实验值吻合,表明超分子计算能有效地模拟无机-有机杂化非线性光学晶体的红外振动光谱。在归属了超分子重要基频线后,分析其红外强度,并估算了泛频频率。根据我们提出的方法,估算了这两种晶体的红外吸收边,结果与实验值较吻合。表明我们建议的理论方法是合理的。此外,通过计算表明,如果非线性光学晶体材料的红外吸收边是由与活泼H有关的伸缩振动泛频频率决定,那么活泼H的氘化是一种改善红外吸收边的有效途径。     

双圆盘加权Dirichlet空间上Toeplitz算子的约化子空间

刻画了双圆盘加权Dirichlet空间D_α(D~2)上Toeplitz算子T_Z_1N(或T_z_2N)和T_z_1N_z_2N的约化子空间.结果表明Toeplitz算子T_z_1N(或T_z_2N)的约化子空间结构与权系数α无关,而Toeplitz算子T_2_1N_z_2N的约化子空间结构与权系数α有关.     

Optical and Electrochemical Probes for Monitoring Cytochrome c in Subcellular Compartments During Apoptosis

Cytochrome c (Cyt. c) is a key initiator of the caspases that activate cell apoptosis. The spatiotemporal evaluation of the contents of Cyt. c in cellular compartments and the detection of Cyt. c delivery between cellular compartments upon apoptosis is important for probing cell viabilities. We introduce an optical probe and an electrochemical probe for the quantitative assessment of Cyt. c in cellular compartments at the single cell level. The optical or electrochemical probes are functionalized with photoresponsive o-nitrobenzylphosphate ester-caged Cyt. c aptamer constituents. These are uncaged by light stimuli at single cell compartments, allowing the spatiotemporal detection of Cyt. c through the formation of Cyt. c/aptamer complexes at non-apoptotic or apoptotic conditions. The probes are applied to distinguish the contents of Cyt. c in cellular compartments of epithelial MCF-10A breast cells and malignant MCF-7 and MDA-MB-231 breast cells under apoptotic/non-apoptotic conditions.     

Unconventional quantum gate based on Rydberg blockade mechanism

We propose a scheme for realizing an unconventional three-qubit controlled-phase gate via the Rydberg blockade mechanism.The qubit is encoded by atomic ensembles that are trapped in optical traps and fixed on an atom chip.Because of the collective nature of the encoding and the Rydberg blockade mechanism,the scheme do not require separate addressing of individual atoms.The time needed for the gate operation is much shorter than that in a similar scheme.In addition,we show the gate can be used as a basic tool for effective generation of large-scale 2D cluster states.