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41.
Cycloaddition of 1,3-diphenyl-2-azaallyllithium to tolane, diphenylbutadiyne and 1,4-diphenylbutenyne E produces quantitatively 2,3,4,5-tetraphenylpyrrole, 3-phenylethynyl-2,4,5-triphenyl-3-pyrroline and 3-phenylethynyl-2,4,5-triphenylpyrrolidine, respectively. Treatment before hydrolysis with benzyl bromide or dimethl sulfide gives N-alkyl-substituted derivatives. The structure of 3-pyrrolines was established by spectral data and chemical correlations. Stereochemical courses of this new synthetic method for 3-pyrrolines are discussed. 相似文献
42.
43.
Efficiency and effectiveness for non-storable commodities represent two distinct dimensions and a joint measurement of both is necessary to fully capture the overall performance. This paper proposes two novel integrated data envelopment analysis (IDEA) approaches, the integrated Charnes, Cooper and Rhodes (ICCR) and integrated Banker, Charnes and Cooper (IBCC) models, to jointly analyze the overall performance of non-storable commodities under constant and variable returns to scale technologies. The core logic of the proposed models is simultaneously determining the virtual multipliers associated with inputs, outputs, and consumption by additive specifications for technical efficiency and service effectiveness terms with equal weights. We show that both ICCR and IBCC models possess the essential properties of rationality, uniqueness, and benchmarking power. A case analysis also demonstrates that the proposed novel IDEA approaches have higher benchmarking power than the conventional separate DEA approaches. More generalized specifications of IDEA models with unequal weights are also elaborated. 相似文献
44.
45.
46.
Shun-Chieh Chang William Chung-Kung Yen Yue-Li Wang Jia-Jie Liu 《Optimization Letters》2016,10(6):1191-1201
In this paper, we study a variant of the p-median problem on block graphs G in which the p-median is asked to be connected, and this problem is called the connected p-median problem. We first show that the connected p-median problem is NP-hard on block graphs with multiple edge weights. Then, we propose an O(n)-time algorithm for solving the problem on unit-edge-weighted block graphs, where n is the number of vertices in G. 相似文献
47.
48.
We consider the parametric programming problem (Q
p
) of minimizing the quadratic function f(x,p):=x
T
Ax+b
T
x subject to the constraint Cx≤d, where x∈ℝ
n
, A∈ℝ
n×n
, b∈ℝ
n
, C∈ℝ
m×n
, d∈ℝ
m
, and p:=(A,b,C,d) is the parameter. Here, the matrix A is not assumed to be positive semidefinite. The set of the global minimizers and the set of the local minimizers to (Q
p
) are denoted by M(p) and M
loc
(p), respectively. It is proved that if the point-to-set mapping M
loc
(·) is lower semicontinuous at p then M
loc
(p) is a nonempty set which consists of at most ?
m,n
points, where ?
m,n
= is the maximal cardinality of the antichains of distinct subsets of {1,2,...,m} which have at most n elements. It is proved also that the lower semicontinuity of M(·) at p implies that M(p) is a singleton. Under some regularity assumption, these necessary conditions become the sufficient ones.
Received: November 5, 1997 / Accepted: September 12, 2000?Published online November 17, 2000 相似文献
49.
Journal of Global Optimization - Improperly efficient solutions in the sense of Geoffrion in linear fractional vector optimization problems with unbounded constraint sets are studied systematically... 相似文献
50.
Sophisticated catchment runoff problems necessitate conjunctive modeling of overland flow and sub‐surface flow. In this paper, finite difference numerical methods are studied for simulation of catchment runoff of two‐dimensional surface flow interacting with three‐dimensional unsaturated and saturated sub‐surface flows. The equations representing the flows are mathematically classified as a type of heat diffusion equation. Therefore, two‐ and three‐dimensional numerical methods for heat diffusion equations were investigated for applications to the surface and sub‐surface flow sub‐models in terms of accuracy, stability, and calculation time. The methods are the purely explicit method, Saul'yev's methods, the alternating direction explicit (ADE) methods, and the alternating direction implicit (ADI) methods. The methods are first examined on surface and sub‐surface flows separately; subsequently, 12 selected combinations of methods were investigated for modeling the conjunctive flows. Saul'yev's downstream (S‐d) method was found to be the preferred method for two‐dimensional surface flow modeling, whereas the ADE method of Barakat and Clark is a less accurate, stable alternative. For the three‐dimensional sub‐surface flow model, the ADE method of Larkin (ADE‐L) and Brian's ADI method are unconditionally stable and more accurate than the other methods. The calculations of the conjunctive models utilizing the S‐d surface flow sub‐model give excellent results and confirm the expectation that the errors of the surface and sub‐surface sub‐models interact. The surface sub‐model dominates the accuracy and stability of the conjunctive model, whereas the sub‐surface sub‐model dominates the calculation time, suggesting the desirability of using a smaller time increment for the surface sub‐model. Copyright © 2000 John Wiley & Sons, Ltd. 相似文献