Die Reaktion10B(d,α)8Be im Energiebereich von 0,5 bis 2 MeV

The differential magnetic susceptibility X=X′-iX″ of HoCl₃, Ho(Y)Cl₃, and Ho(La)Cl₃ has been measured with a mutual inductance bridge with frequencies from 5.3 c/s to 5.12 kc/s at temperatures between 1.1 and 4.2 °K, and in constant magnetic fields up to 3 kOe. — In monoclinic HoCl₃ a magnetic transition has been observed atT=2.15 °K (maximum of X″). No transition occurs for 0.5 and 5% Ho³⁺ in isomorphic YCl₃. — The results for nominal concentrations of 1, 2, and 5% Ho³⁺ in hexagonal LaCl₃ indicate, that there is a considerable precipitation of monoclinic HoCl₃ during crystal growth. Relaxation measurements on Ho³⁺ in hexagonal sites are interpreted in terms of a phonon-bottleneck in the temperature region 1.1 °K≦T≦2.0⁰K with a hot-phonon equilibration time of about 0.2 μs.     

Eigenvalue inequalities for products of matrix exponentials

Motivated by models from stochastic population biology and statistical mechanics, we proved new inequalities of the form $\text{(1) ?(e}{}^{\mathrm{A}}\text{e}{}^{\mathrm{B}}\text{)??(e}{}^{\mathrm{A+B}}\text{)}$, where A and B are n × n complex matrices, 1<n<∞, and ? is a real-valued continuous function of the eigenvalues of its matrix argument. For example, if A is essentially nonnegative, B is diagonal real, and ? is the spectral radius, then (1) holds; if in addition A is irreducible and B has at least two different diagonal elements, then the inequality (1) is strict. The proof uses Kingman's theorem on the log-convexity of the spectral radius, Lie's product formula, and perturbation theory. We conclude with conjectures.     

Optical model and DWBA analysis of the7Li(d,d)- and7Li(d,p 0)-reactions in the energy region 1.0 to 2.6 MeV

Absolute differential cross sections for the elastic scattering of deuterons by⁷Li have been determined in the energy range of 1.0 to 2.6 MeV. Two excitation curves measured at laboratory angles of 90° and 160° vary smoothly with energy. At higher energies an extremely strong enhancement of the cross section relative to the Rutherford value was observed at large angles. It was, however, possible to find realistic optical potentials that describe these distributions fairly well over the whole energy region. For two of these potentials good fits could be obtained with DWBA calculations on the⁷Li (d, p ₀)-reaction, one of them yielding a spectroscopic factor in close agreement with shell model predictions.     

An improved sequential extraction method to determine element mobility in pyrite-bearing siliciclastic rocks

A sequential extraction method was developed for pyrite-bearing (FeS₂) siliciclastic rocks. The focus of this study was to enhance the procedure by an improved oxidation step to completely dissolve not only organic matter but also microcrystalline pyrite. In the first experiment, four oxidation procedures were compared for pure pyrite at extraction temperatures of 25°C and 85°C with hydrogen peroxide (H₂O₂) as the main oxidant. It was found that pyrite dissolution was most effective by using a mixture of H₂O₂, ammonium acetate (NH₄OAc) and nitric acid (HNO₃) at 25°C. This procedure dissolved >90% pyrite, and detected >75% using solute iron measurements. The difference between these two results was explained by reprecipitation of secondary iron minerals. The procedure worked best at 25°C, since solvent evaporation at 85°C amplified iron oversaturation and precipitation. For the pyrite-bearing siliciclastic rocks, two sequential extraction schemes were compared to optimise solid–solvent ratio, extraction step order and type of solvent. Eventually, the most effective step order identified for siliciclastic rocks containing pyrite and little organic matter was to first (1) remove the exchangeable fraction, followed by (2) dissolution with acid and afterwards (3) with a reducing agent. The (4) oxidation step was performed last.     

How lipid unsaturation, peroxyl radical partitioning, and chromanol lipophilic tail affect the antioxidant activity of α-tocopherol: direct visualization via high-throughput fluorescence studies conducted with fluorogenic α-tocopherol analogues

The preparation of two highly sensitive fluorogenic α-tocopherol (TOH) analogues which undergo >30-fold fluorescence intensity enhancement upon reaction with peroxyl radicals is reported. The probes consist of a chromanol moiety coupled to the meso position of a BODIPY fluorophore, where the use of a methylene linker (BODIPY-2,2,5,7,8-pentamethyl-6-hydroxy-chroman adduct, H(2)B-PMHC) vs an ester linker (meso-methanoyl BODIPY-6-hydroxy-2,5,7,8-tetramethylchromane-2-carboxylic acid, H(2)B-TOH) enables tuning their reactivity toward H-atom abstraction by peroxyl radicals. The development of a high-throughput fluorescence assay for monitoring kinetics of peroxyl radical reactions in liposomes is subsequently described where the evolution of the fluorescence intensity over time provides a rapid, facile method to conduct competitive kinetic studies in the presence of TOH and its analogues. A quantitative treatment is formulated for the temporal evolution of the intensity in terms of relative rate constants of H-atom abstraction (k(inh)) from the various tocopherol analogues. Combined, the new probes, the fluorescence assay, and the data analysis provide a new method to obtain, in a rapid, parallel format, relative antioxidant activities in phospholipid membranes. The method is exemplified with four chromanol-based antioxidant compounds differing in their aliphatic tails (TOH, PMHC, H(2)B-PMHC, and H(2)B-TOH). Studies were conducted in six different liposome solutions prepared from poly- and mono-unsaturated and saturated (fluid vs gel phase) lipids in the presence of either hydrophilic or lipophilic peroxyl radicals. A number of key insights into the chemistry of the TOH antioxidants in lipid membranes are provided: (1) The relative antioxidant activities of chromanols in homogeneous solution, arising from their inherent chemical reactivity, readily translate to the microheterogeneous environment at the water/lipid interface; thus similar values for k(inh)(H(2)B-PMHC)/k(inh)(H(2)B-TOH) in the range of 2-3 are recorded both in homogeneous solution and in liposome suspensions with hydrophilic or lipophilic peroxyl radicals. (2) The relative antioxidant activity between tocopherol analogues with the same inherent chemical reactivity but bearing short (PMHC) or long (TOH) aliphatic tails, k(inh)(PMHC)/k(inh)(TOH), is ~8 in the presence of hydrophilic peroxyl radicals, regardless of the nature of the lipid membrane into which they are embedded. (3) Antioxidants embedded in saturated lipids do not efficiently scavenge hydrophilic peroxyl radicals; under these conditions wastage reactions among peroxyl radicals become important, and this translates into larger times for antioxidant consumption. (4) Lipophilic peroxyl radicals show reduced discrimination between antioxidants bearing long and short aliphatic tails, with k(inh)(PMHC)/k(inh)(TOH) in the range of 3-4 for most lipid membranes. (5) Lipophilic peroxyl radicals are scavenged with the same efficiency by all four antioxidants studied, regardless of the nature of their aliphatic tail or the lipid membrane into which they are embedded. These data underpin the key role the lipid environment plays in modulating the rate of reaction of antioxidants characterized by similar inherent chemical reactivity (arising from a conserved chromanol moiety) but differing in their membrane mobility (structural differences in the lipophilic tail). Altogether, a novel, facile method of study, new insights, and a quantitative understanding on the critical role of lipid diversity in modulating antioxidant activity in the lipid milieu are reported.     

Spatial distribution of structural disorder in Co2FeSi films studied by anisotropic magnetoresistance

We studied the spatial distribution of the partially disordered B2 phase in Co₂FeSi films by anisotropic magnetoresistance measurements. The analysis of our experimental results allows not only for the discrimination between different models for the spatial distribution of structural disorder, but also enables us to estimate the volume fraction occupied by the partially disordered B2 phase within the Co₂FeSi films grown on GaAs. In particular, our findings are in accordance with a laterally inhomogeneous distribution of the structural disorder in the topmost part of Co₂FeSi films.